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Seasonal Variation of Atmospheric Polycyclic Aromatic Hydrocarbons (PAHs) on Anmyeon Island

안면도에서 대기 중 가스상 PAHs의 계절적 변동

  • An, Joon-Geon (South Sea Research Institute, KORDI) ;
  • Yim, Un-Hyuk (South Sea Research Institute, KORDI) ;
  • Shim, Won-Joon (South Sea Research Institute, KORDI) ;
  • Kim, Gi-Beum (Department of Marine Environmental Engineering Gyeongsang National University) ;
  • Kim, Seung-Kyu (School of Earth and Environmental Sciences Seoul National University) ;
  • Yi, Hi-Il (Marine Environment & Pollution Prevention Research Department, KORDI)
  • 안준건 (한국해양연구원 남해연구소) ;
  • 임운혁 (한국해양연구원 남해연구소) ;
  • 심원준 (한국해양연구원 남해연구소) ;
  • 김기범 (국립경상대학교 해양환경공학과, 해양산업연구소) ;
  • 김승규 (국립서울대학교 지구환경과학부) ;
  • 이희일 (한국해양연구원 해양환경.방제연구부)
  • Published : 2009.06.30

Abstract

Passive air samplers with polyurethane foam (PUF) disks were employed to determine seasonal gas phase variation of polycyclic aromatic hydrocarbons (PAHs) in ambient air on Anmyeon island from March 2007 to January 2008. Sum of 13 PAHs ranged between $3.5\;ng/m^3$ and $27.6\;ng/m^3$. Total PAHs during the heating season was 6.2 times higher than non-heating season. The dominant PAHs components during sampling periods were low and middle molecular weight PAHs including phenanthrene, fluoranthene, pyrene and chrysene. Gas exchange fluxes of PAHs across the air-water interface of the Yellow Sea were calculated using a modified two-film exchange model. PAHs fluxes ranged from $196\;ng/m^2/d$ net volatilization during summer to $3830\;ng/m^2/d$ net absorption during winter. Passive air sampler provides a convenient and cost-effective tool for measuring averaged gas phase PAHs, which was successfully used for calculation of gas exchange flux of PAHs in the Yellow Sea.

Keywords

References

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