Carbon letters

Korean Carbon Society (한국탄소학회)
권호 표지
DOI QR코드

DOI QR Code

Hydrogen Storage Behaviors of Carbon Nanotubes/Metal-organic Frameworks-5 Hybrid Composites

  • Received : 2009.02.09
  • Accepted : 2009.03.13
  • Published : 2009.03.30
Download PDF
⟨ Previous Next ⟩

Abstract

In this work, the hydrogen storage behaviors of carbon nanotubes (CNTs)/metal-organic frameworks-5 (MOF-5) hybrid composites (CNTs/MOF-5) were studied. Hydrothermal synthesis of MOF-5 was conducted by conventional convection heating using 1-methyl-2-pyrrolidone (NMP) as a solvent. Morphological characteristics and average size of the CNTs/MOF-5 were also obtained using a scanning electron microscopy (SEM). The pore structure and specific surface area of the CNTs/MOF-5 were analyzed by N2/77 K adsorption isotherms. The capacity of hydrogen storage of the CNTs/MOF-5 was investigated at 298 K/100 bar. As a result, the CNTs/MOF-5 had crystalline structures which were formed by hybrid synthesis process. It was noted that the CNTs/MOF-5 can be potentially encouraging materials for hydrogen adsorption and storage applications at room temperature.

Keywords

References

  1. Schlapbach, L.; Zuttel, A. Nature 2001, 414, 353. https://doi.org/10.1038/35104634
  2. Park, S.J.; Kim. B.J.; Lee, Y.S. Carbon Let. 2007, 8, 225. https://doi.org/10.5714/CL.2007.8.3.225
  3. Park, S.J.; Kim. B.J.; Lee, Y.S. Carbon Let. 2007, 8, 340. https://doi.org/10.5714/CL.2007.8.4.340
  4. Park, S.J.; Kim. B.J.; Lee, Y.S. Carbon Let. 2008, 9, 35. https://doi.org/10.5714/CL.2008.9.1.035
  5. Kim, B. J.; Park, S. J. J. Colloid Interface Sci. 2007, 311, 619. https://doi.org/10.1016/j.jcis.2007.03.049
  6. Kim, B. J.; Park, S. J. J. Colloid Interface Sci. 2007, 311, 311. https://doi.org/10.1016/j.jcis.2007.02.059
  7. Leuch, L. M. Le; Bandosz, T. J. Carbon 2007, 45, 568. https://doi.org/10.1016/j.carbon.2006.10.016
  8. Kim, B. J.; Lee, Y. S.; Park, S. J. Int. J. Hydrogen Energy 2008, 33, 2254. https://doi.org/10.1016/j.ijhydene.2008.02.019
  9. Benard, P.; Chahine, R. Scripta Mater. 2007, 56, 803. https://doi.org/10.1016/j.scriptamat.2007.01.008
  10. Rzepka, M.; Lamp, P. J. Phys. Chem. B 1998, 102, 10894. https://doi.org/10.1021/jp9829602
  11. Kitagawa, S.; Kitaura, R.; Noro, S. Angew. Chem. Int. Ed. 2004, 43, 2334. https://doi.org/10.1002/anie.200300610
  12. Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.; O'Keeffe, M.; Yaghi, O. M. Science 2003, 300, 1127. https://doi.org/10.1126/science.1083440
  13. Rowsell, J. L. C.; Millward, A. R.; Park, K. S.; Yaghi, O. M. J. Am. Chem. Soc. 2004, 126, 5666. https://doi.org/10.1021/ja049408c
  14. Tranchemontagne, D. J.; Hunt, J. R.; Yaghi, O. M. Tetrahedron 2008, 64, 8553. https://doi.org/10.1016/j.tet.2008.06.036
  15. Opelt, S.; Türk, S.; Dietzsch, E.; Henschel, A.; Kaskel, S.; Klemm, E. Catal. Comm. 2008, 9, 1286. https://doi.org/10.1016/j.catcom.2007.11.019
  16. Hafizovic, J.; Bjorgen, M.; Olsbye, U.; Dietzel, P.; Bordiga, S.; Prestipino, C.; Lamberti, C.; Lillerud K. P. J. Am. Chem. Soc. 2007, 129, 3612. https://doi.org/10.1021/ja0675447
  17. Li, J.; Cheng S.; Zhao, Q.; Long, P.; Dong, J. Int. J. Hydrogen Energy 2009, 34, 1377. https://doi.org/10.1016/j.ijhydene.2008.11.048
  18. Menon, M.; Andriotis, A. N.; Froudakis, G. E. Chem. Phys. Lett. 2000, 320, 425. https://doi.org/10.1016/S0009-2614(00)00224-4
  19. Brunauer, S.; Emmett, P. H.; Teller, E. J. Am. Chem. Soc. 1938, 60, 309. https://doi.org/10.1021/ja01269a023
  20. Kim, B. J.; Lee, Y. S.; Park, S. J. J. Colloid Interface Sci. 2008, 318, 530. https://doi.org/10.1016/j.jcis.2007.10.018

Cited by

  1. Preparation and Electroactivities of Carbon Nanotubes-supported Metal Catalyst Electrodes Prepared by a Potential Cycling vol.10, pp.3, 2009, https://doi.org/10.5714/CL.2009.10.3.213
  2. Adsorption of Amine Functionalized Activated Carbons vol.10, pp.3, 2009, https://doi.org/10.5714/CL.2009.10.3.221
  3. Influence of phosphoric acid treatment on hydrogen adsorption behaviors of activated carbons vol.12, pp.2, 2011, https://doi.org/10.5714/CL.2011.12.2.112
  4. Comprehensive review on synthesis and adsorption behaviors of graphene-based materials vol.13, pp.2, 2012, https://doi.org/10.5714/CL.2012.13.2.073
  5. Carbon nanotubes-properties and applications: a review vol.14, pp.3, 2013, https://doi.org/10.5714/CL.2013.14.3.131