Environmental Engineering Research

  • 제14권2호
  • /
  • Pages.126-133
  • /
  • 2009
  • /
  • 1226-1025(pISSN)
  • /
  • 2005-968X(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
권호 표지
DOI QR코드

DOI QR Code

Development of Transport Parameters affecting on the Removal of Micro Organic Compounds such as Disinfection By-Products and Pharmaceutically Active Compounds by Low-Pressure Nanofiltration

  • Oh, Jeong-Ik (Housing & Urban Research Institute, Korea National Housing Corporation) ;
  • Yamamoto, Kazuo (Environmental Science Research Center, University of Tokyo)
  • 발행 : 2009.06.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

This study investigated the removal characteristics of various micro organic compounds by low-pressure nanofiltration membranes comprised of disinfection by products and pharmaceutically active compounds. The experimental removal of micro organic compounds by low-pressure nanofiltration membranes was compared with the transport model calculations, which consist of diffusion and convection terms including steric hindrance factor. The selected molecule from the disinfection byproducts and pharmaceutical active compounds showed a much lower removal than polysac-charides with a similar molecular size. However,the difference between model calculation and experimental removal of disinfection by-products and pharmaceutically active compounds could be corrected. The correlation of Ks with solute radius was further considered to clarity transport phenomena of micro organic solutes through nanofiltration membranes.

키워드

참고문헌

  1. Awadalla, F. T., Striez, C., and Lamb, K., "Removal of ammonium and nitrate ions from mine effluents by membrane technology," Sep. Sci. Technol., 29(4), 483-495 (1994) https://doi.org/10.1080/01496399408002157
  2. Bilstad, T., "Nitrogen separation from domestic wastewater by reverse osmosis," J. Membr. Sci., 102, 93-102 (1995) https://doi.org/10.1016/0376-7388(94)00279-8
  3. Braundhuber, P. and Amy, G., "Altemative methods formembrane filtration of arsenic from drinking water," Desatination, 117, 1-10 (1998) https://doi.org/10.1016/S0011-9164(98)00061-7
  4. Monthon, T., Oh, J. I., Yamamoto, K., and Urase, T., "Comparison between removal characteristics of natural organic matter and inorganic salts in ultra low pressure nanofiltration for drinking water production," Water Sci. Technol.: Water Supply, 1(5/6), 77-90 (2001)
  5. Oh, J. I., Yamamoto, K., Kitawaki, H., Nakao, S., Sugawara, T., Rahman, M. M., and Rahman, M. H., "Application of low-pressure nanofiltration coupled with a bicycle pump for the treatment of arsenic-contaminated groundwater," Desalination, 132, 307-314 (2000) https://doi.org/10.1016/S0011-9164(00)00165-X
  6. Soltanieh, M. and Mousavi, M., "Application of charged membranes in water softening: modeling and experiments in the presence of poly electrolyte," J. Membr. Sci., 154,53-60 (1999) https://doi.org/10.1016/S0376-7388(98)00285-3
  7. Urase, T., Oh, J. I., and Yamamoto, K., "Effect of pH on removal of different species of arsenic by nanofiltration," Desalination, 117, 11-18 (1998) https://doi.org/10.1016/S0011-9164(98)00062-9
  8. Chavalit, R., "Transport phenomena of anionic pollutants through nanofiltration membranes and their application to water treatment especially in very low pressure range of operation," Doctoral dissertation in Department of Urban Engineering, University of Tokyo (1996)
  9. Monthon, T., "Ultra low pressure nanofiltration of river water for drinking water treatment," Doctoral dissertation in department of urban engineering, University of Tokyo, (2002)
  10. Kimura, K.., Amy, G., Drewes, J. E., Hebere, T., Kim, T. U., and Watanabe, Y., "Removal of organic micro pollutants (disinfection by-products, endocrine disrupting compounds, and pharmaceutically active compounds) by NF/RO membranes," J. Membr. Sci., 227, 113-121 (2003) https://doi.org/10.1016/j.memsci.2003.09.005
  11. Kiso, Y., Li, H. D., and Kitao T., "Pesticides separation by nanofiltration membranes," J. Jpn Soc. Water Environ., 19(8), 648-659 (1996) (Japanese) https://doi.org/10.2965/jswe.19.648
  12. Webb, S., Ternes, T., Gibert, M., and Olejniczak, K., "Indirect human exposure to pharmaceuticals via drinking water," Toxicol. Lett., 142,157-167 (2003) https://doi.org/10.1016/S0378-4274(03)00071-7
  13. Weigel, S., Kallenborn, R., and H. Huhnerfuss, "Simultaneous solid-phase extraction of acidic, neutral and basic pharmaceuticals form aqueous samples at ambient (neutral) pH and their determination by gas chromatographymass spectrometry," J. Chromatogr. A, 1023, 183-195 (2004) https://doi.org/10.1016/j.chroma.2003.10.036
  14. Wang, X. L., Tsuru, T., Togho, M., Nakao, S., and Kimura, S.. Transport of orgarnic electrolytes with electrostatic and steric-hindrance effects through nanofiltration membranes, J. Chem. Eng. Jpn., 128(4), 372-380 (1995) https://doi.org/10.1252/jcej.28.372
  15. Deen, W. M. and Smith, F. G., "Hindered diffusion of synthetic polyelectrolytes in charged microporous membranes," J. Membr. Sci., 12, 217-237 (1982) https://doi.org/10.1016/S0376-7388(00)80184-2
  16. Samuel, P. K., Sano, K., Sudo, M., and Kensaka, M., "Water permselectivity in the pervaporation of acetic acid-water mixture using crosslinked poly(vinyl alcohol) membranes," Separation and Purification Technology, 18, 141-150 (2000) https://doi.org/10.1016/S1383-5866(99)00060-X
  17. Liu, G. W., Yao, K., "What causes the unfrozen water in polymers: hydrogen bonds between water and polymer chains?," Polymer, 42, 3943-3947 (2001) https://doi.org/10.1016/S0032-3861(00)00726-6

피인용 문헌

  1. 이온 몰 전도도가 나노여과막에 의한 폐수 중의 중금속 분리특성에 미치는 영향 vol.4, pp.1, 2009, https://doi.org/10.5804/lhij.2013.4.1.119