Journal of the Korea Safety Management & Science (대한안전경영과학회지)

Korea Safety Management & Science (대한안전경영과학회)
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Thermal Characteristics of Polyvinylchloride in Combustion Reaction Using TGA

TGA를 이용한 폴리염화비닐의 연소반응에서의 열적 특성 연구

  • Seo, Su-Eun (Department of Industrial Engineering, Myongji University) ;
  • Kang, Yun-Jin (Department of Industrial Engineering, Myongji University) ;
  • Min, Cho-Young (Department of Industrial Engineering, Myongji University) ;
  • Bae, Dong-Chul (Department of Safety and Health Engineering, Hoseo University) ;
  • Kang, Kyung-Sik (Safety Management Laboratory, Myongji University)
  • 서수은 (명지대학교 산업공학과) ;
  • 강윤진 (명지대학교 산업공학과) ;
  • 민영초 (명지대학교 산업공학과) ;
  • 배동철 (호서대학교 안전보건학과) ;
  • 강경식 (명지대학교 안전경영연구소)
  • Published : 2009.09.30
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Abstract

The combustion reaction of polyvinylchloride(PVC) was investigated using a thermogravimetric technique under an air atmosphere condition at several heating rates from 10 to $50^{\circ}C$/min. To obtain information on the kinetic parameters, the dynamic thermogravimetric analysis curve and its derivative were analyzed by a variety of analytical methods such as Kissinger, Friedman, Chatterjee-Conrad, Ozawa and Coats-Redfern methods. The combustion reaction of PVC proceeded in two steps; the first step was caused by the dehydrochlorination process in PVC, and the second step by the combustion of polyene. The comparative works for the kinetic results obtained from various methods should be performed to determine the kinetic parameters, because there are tremendous differences in the calculated kinetic parameters depending upon the mathematical method taken in the analysis.

Keywords

References

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