The Korean Journal of Pesticide Science (농약과학회지)

The Korean Society of Pesticide Science (한국농약과학회)
권호 표지

Behavior of Pesticides in Soil

토양 중 농약의 동태

  • Lee, Kyu-Seung (Department of Bioenvironmental chemistry, Chungnam National University)
  • 이규승 (충남대학교 농업생명과학대학 생물환경화학과)
  • Received : 2010.09.07
  • Accepted : 2010.09.17
  • Published : 2010.09.30
Download PDF
⟨ Previous Next ⟩

Abstract

The researches with pesticides in soil were divided several categories such as run off from soil surface, adsorption and desorption in soil, leaching through soil, degradation and decomposition studies, fates in soil, monitoring survey and development of analytical procedures and so on. In this paper it was reviewed that the research results published in Korean journals since 1996, in connection with the former review as 'Evaluation on the effects of pesticide residues to agroecosystem in Korea'.

총설은 1996년 "농업생태계에 대한 잔류농약의 영향평가"라는 총설 이후 국내에서 발표된 토양 중에서의 농약의 동태에 관한 연구 보문을 요약 정리한 것이다. 내용은 농약의 지표면 유출, 농약의 토양 중 흡착 및 탈착, 농약의 토양 중 용탈, 농약의 토양 종 분해는 미생물에 의한 분해와 비생물학적 분해로 나누어 검토하였고, 농약의 토양 종에서의 행적 및 토양 중 잔류와 잔류 분석법 등으로 구분하여 정리하였다.

Keywords

References

  1. Ahn, K.C. and Lee, J.K. (2000). Accelerating effect of some photosensitizers on photodegradation of the herbicide quinclorac in aqueous solution and soil, Kor. J. Pesti. Sci. 4(4), 12-18.
  2. Ahn, K.C., Kyung, K.S. and Lee, J.K. (1998). Behaviour of the soil residues of the herbicide quinclorac in the micro - ecosystem (pot), Kor. J. Pesti. Sci. 2(3), 96-106.
  3. An, D.H., Kim, I.S. and Suh, Y.T. (1999). Degradation of $^{14}C$-propiconazole in soil from different depths, Kor. J. Pesti. Sci. 3(2), 8-18.
  4. An, X.H., An, W.H., Im, I.B., Lee, S.B. and Kang, J.G. (2006). Persistence of Fungicide Pencycuron in Soils, Kor. J. Pesti. Sci. 10(4), 296-305.
  5. Choi, G.I., Seong, K.Y. and Kim, J.G. (2005). Behaviors of the Fungicide Procymidone in soils, Kor. J. Environ. Agric. 24(2), 123-1321. https://doi.org/10.5338/KJEA.2005.24.2.123
  6. Choi, H., Kim, B.J., Bae, D.Y., Lee, Y.D. and Kang, S.C. (1998). Screening of Organo Phosphorus Insecticide Fenitrothion Degrading Microorganisms, Kor. J. Environ. Agric., 17(3), 279-285.
  7. Chun, J.C., Kim, S.E., Park, N.I. and Lim, S.J. (1998). Residue and Adsorptive Capacity of Paraquat in Orchard Soils, Kor. J. Pesti. Sci. 2(3), 90-95.
  8. Chun, M.Y. and Yeo, H.G. (2005). Characteristics of PCDD/Fs Deposited on Pine Needles and Soil, Kor. J. Environ. Agric. 24(3), 280-288. https://doi.org/10.5338/KJEA.2005.24.3.280
  9. Chung, K.Y., Woo, S.H., Kim, H.T., Sa, T.M., Kim, Y.K., Hong, S.D., Kim, J.J. and Lee, J.K. (2004). Degradation of the Fungicide Tolclofosmethyl in the Turfgrass Soil of Golf Course, Kor. J. Environ. Agric. 23(3), 178-184. https://doi.org/10.5338/KJEA.2004.23.3.178
  10. Gyeong, G.S., Lee, B.M., Im, Y.B., Lee, Y.D., Han, S.S., Choe, J.H., Kim, J.H., Lyu, G.H. and Lee, J.G. (2004). Adsorption and leaching characteristics of fungicide hexaconazole, Kor. J. Pesti. Sci. 8(1), 46-53.
  11. Gyeong, G.S., Oh, K.S., Ahn, K.C., Kwon, J.W. and Lee, J.K. (1998). Leaching behavior of the herbicide bentazon in soil column, Kor. J. Pesti. Sci. 2(1), 59-64.
  12. Han, S.G., Ahn, B.K. and Moon, Y.H. (1998). Adsorption and Movement of Fenoxaprop-P-ethyl in Soils, Kor. J. Weed. Sci. 18(4),325-332.
  13. Hong, M.K., Park, J.W. and Kim, J.E. (2001). Behaviors of Chloronicotinyl Insecticide Acetamiprid in Soil, Kor. J. Environ. Agric. 20(3), 162-168.
  14. Hwang, I.T., Hong, K.S., Lee, B.H., Kim, H.R., Jeon, D.J. and Cho, K.Y. (2004). Selectivity and behaviour of EK-5439 in the soil as a candidate for rice herbicide, Kor. J. Pesti. Sci. 8(3), 175-183.
  15. Ihm, Y.B., Kyung, K.S., Kim, C.S., Lee, H.D., Ryu, G.H. and Lee, J.K. (2006). Adsorption and Leaching Characteristics of the Insecticide Imidacloprid in Paddy Soils, Kor. J. Environ. Agric. 25(1), 58-63. https://doi.org/10.5338/KJEA.2006.25.1.058
  16. Im, Y.B., Gyeong, G.S., Kim, C.S., Choe, B.L., Hong, S.M. and Lee, J.G. (2004). Photolysis of the insecticide imidacloprid in water and water-paddy soil systems, Kor. J. Pesti. Sci. 8(1),38-45.
  17. Jeong, B.R., Lee, Y.D. and Song, S.D. (2000). Weed Control Efficacy and Soil Persistence of New Pendimethalin Formulations, Kor. J. Weed. Sci. 20(2), 121-126.
  18. Kim, C.S., Ihm, Y.B., Lee, H.D. and Oh, B.Y. (2005a). Leaching of Organophosphorus and Carbamate Pesticides in Soil Column and Prediction of Their Mobility Using the Convective Mobility Test Model in Soils, Kor. J. Environ. Agric. 24(4), 350-357. https://doi.org/10.5338/KJEA.2005.24.4.350
  19. Kim, C.S., Lee, B.M., Ihm, Y.B. and Choi, J.H. (2002a). Leaching potential of butachlor, ethoprophos, iprobenfos, isoprathiolane and procymidone in soils as affected by adsorption characteristics, Kor. J. Pesti. Sci. 6(4), 309-319.
  20. Kim, C.S., Lee, H.D., Lhm, Y.B., and Lm, G.J. (2007). Runoff of Endosulfan by Rainfall Simulation and from Soybean-grown Field Lysimeter, Kor. J. Environ. Agric. 26(4). 343-350. https://doi.org/10.5338/KJEA.2007.26.4.343
  21. Kim, C.S., Lee, H.D., Oh, B.Y., and Lee, Y.D. (2006a). Runoff and Erosion of Alachlor, Ethalfluralin, Ethoprophos and Pendimethalin from Soybean Field Lysimeter, Kor. J. Environ. Agric. 25(4), 297-305. https://doi.org/10.5338/KJEA.2006.25.4.297
  22. Kim, C.S., Lhm, Y.B., Lee, Y.B., and Oh, B.Y. (2006b). Runoff and Erosion of Alachlor, Ethalfluralin, Ethoprophos and Pendimethalin by Rainfall Simulation, Kor. J. Environ. Agric. 25(4), 306-315. https://doi.org/10.5338/KJEA.2006.25.4.306
  23. Kim, C.S., Park, B.J., Ihm, Y.B. and Ryu, G.H. (2005b). Adsorption Characteristics of Organophosphorus and Carbamate Pesticides in Four Soils and the Evaluation for Their Leaching Potential Using Two Screening Models, Kor. J. Environ. Agric. 24(4), 341-349. https://doi.org/10.5338/KJEA.2005.24.4.341
  24. Kim, C.S., Park, K.H., Kim, J.B. and Choi, J.H. (2002b), Leaching and mobility prediction of butachlor, ethoprophos, iprobenfos, isoprothiolane and procymidone in soils, Kor. J. Pesti. Sci. 6(4), 300-308.
  25. Kim, H.K., Lee, Y.H. and Lee, K.S. (2002c). Adsorption and Degradation of Procymidone in Ginseng Cultivating Soils, Kor. J. Environ. Agric. 21(4), 286-290. https://doi.org/10.5338/KJEA.2002.21.4.286
  26. Kim, H.K., Park, I.J., Shim, J.H. and Shu, Y.T. (1996a). Soil Adsorption of Herbicide Quizalofop-Ethyl, Kor. J. Environ. Agric. 15(4), 442-447.
  27. Kim, H.K., Yun, B.K., Park, I.J. and Shu, Y.T. (1996b). Fate of the Herbicide Quizalofop - Ethyl in Soil, Kor. J. Environ. Agric. 15(4), 488-493.
  28. Kim, I.S. and Suh, Y.T. (1999). Behaviour of Fungicide 14C - Propiconazole in Rice Plant Grown - Lysimeter Soil, Kor. J. Environ. Agric. 18(3), 215-220.
  29. Kim, J.H. (1996c). Leaching of Trifluralin in the Commerce Clay Loam Soil, Kor. J. Environ. Agric. 15(4), 464-471.
  30. Kim, J.H. and Kim, S.K. (2000). Adsorption and residues of EPN in the soil of Cheju Island, Kor. J. Pesti. Sci. 4(1), 19-25.
  31. Kim, J.S. and Kim, J.E. (2009). Adsorption Pattern of the Herbicide, Bentazon and Its Metabolites on Soil, Kor. J. Environ. Agric. 28(3), 274-280. https://doi.org/10.5338/KJEA.2009.28.3.274
  32. Kim, K., Kim, Y.H., Kim, J.H., and Park, C.K. (1996d). Study on Pesticide Runoff from Soil Surface -I, Runoff of Captafol by Natural Rainfall in Field, J. Korean Soc. Agric. Chem. Biotechnol. 39(6), 488-493.
  33. Kim, K., Yeom, D.H., Kim, J.H., Led, S.K., Kim, Y.H., and Park, C.K. (1997a). Study on Pesticide Runoff from Soil surface-III Runoff of Pesticides by Simulated Rainfall in the Laboratory, J. Korean Soc. Agric. Chem. Biotechnol. 40(4), 334-341.
  34. Kim, K., Yeom, D.H., Kim, J.H., Lee, S.K., Kim, Y.H., and Park, C.K. (1997b). Study on Pesticide Runoff from Soil Surface-II Runoff of Phorate by Simulated Rainfall in Field, J. Korean Soc. Agric. Chem. Biotechnol. 40(4), 323-328.
  35. Kim, S.M., Jo, I.G., Gyeong G.S. and Lee, J.K. (2003a). Influence of soil organic matter and moisture on the persistence of the herbicide mefenacet in soils, Kor. J. Pesti. Sci. 7(3), 182-187.
  36. Kim, S.M., Kwon, J.U., Ahn, G.C., Jo, I.G., Gyeong, G.S. and Lee J.G. (2003b). Leaching behaviour of the herbicide mefenacet in the soil columns, Kor. J. Pesti. Sci. 7(3), 176-181.
  37. Kim, S.S., Kim, T.H., Lee, S.M., Park, D.S., Zhu, Yong-Zhe. and Hur, J.H. (2005c). Mobility of pesticides in different slopes and soil collected from Gangwon alpine sloped-land under simulated rainfall conditions, Kor. J. Pesti. Sci. 9(4), 316-329.
  38. Kim, S.S., Kim, T.H., Lee, S.M., Park, H.R., Park, D.S., Lim, C.K., and Hur, J.H. (2008). Mobility of Pesticides from Soil in Different Slope by Simulated Rainfall Under Field Conditions, Kor. J. Pesti. Sci. 12(1). 24-33.
  39. Kim, Y.S., Kim, Y.H. and Moon, Y.H. (1997c). Influence of Soil Pollutants and Fertilizers on Degradation Rate of Herbicide Alachlor in Soil, Kor. J. Weed Sci. 17(2), 214-219.
  40. Kim, Y.W. (1997d). Residue analysis of Quinclorac in soil by supercritical fluid extraction and fluorogenic derivation coupled with high performance liquid chromatography, J. Korean Soc. Agric. Chem. Biotechnol. 40(5), 442-446.
  41. Kwak, H.R., Lee, K.B., Kim, K.Y. Kim, Y.W. and Suh, Y.T. (2000). Degradation of 14C - bifenox in Soils under Anaerobic Conditions, Kor. J. Environ. Agric. 19(4), 300-308.
  42. Kwon, J.W. and Lee, J.K. (1997). Mineralization and Adsorption of $^{14}C$-Labelled Imazapyr in Soil, Kor. J. Environ. Agric. 16(4), 320-326.
  43. Kwon, J.W. and Lee, J.K. (1999a). Behaviour of the soil residues of the bipyridylium herbicide, [14C]paraquat in the micro - ecosystem, Kor. J. Pesti. Sci. 3(1), 66-77.
  44. Kwon, J.W. and Lee, J.K. (1999b). Leading characteristics of the bipyridylium herbicide paraquat in soil column, Kor. J. Pesti. Sci. 3(2), 29-36.
  45. Kwon, J.W., Kim, Y.S., Choi, J.W. and Lee, K.S. (1997). Extraction Method for Paraquat from Soil, Kor. J. Environ. Agric. 16(3), 239-244.
  46. Kyung, K.S., Lee, B.M. and Lee, J.K. (2004). Behavior of the soil residues of the fungicide hexaconazole in a rice plants-grown microecosystem (pot), Kor. J. Pesti. Sci. 8(3), 198-209.
  47. Lee, J.K. and Kwon, J.W. (1998a). Microbial degradation and other methods for accelerated degradation the Herbicide Imazapyr, Kor. J. Environ. Agric. 17(2), 5-10.
  48. Lee, J.K., Gyeong, G.S., Kwon, J.W., Ahn K.C. and Jung, I.S. (1998b). Leaching behaviour of the systemic insecticide carbofuran and the herbicide pretilachlor in soil columns, Kor. J. Pesti. Sci. 2(2), 59-67.
  49. Lee, J.K., Jung, I.S., Kwon, J.W. and Ahn, K.C. (1998c). Diminution of Pesticide Residues on Crops and Soil by Accelerated Photolysis, Kor. J. Environ. Agric. 17(2), 107-116.
  50. Lee, J.K., Kwon, J.W., Ahn, K.C., Park, J.H. and Lee, Y.P. (2004a). Fate of the herbicide bensulfuron-methyl in a soil/rice plant microecosystem, Kor. J. Pesti. Sci. 8(4), 299-308.
  51. Lee, K.S. (1997). Evaluation on the effects of pesticides to agroecosystm in korea, Kor. J. Environ. Agric. 16(1), 80-93.
  52. Lee, S.J., Kim, B.H. and Kim, J.E. (1998d). Characteristics of Adsorption-Desorption of Herbicide Paraquat in Soils, Kor. J. Pesti. Sci. 2(1), 70-78.
  53. Lee, S.M., Kim, S.S., Park, D.S. and Hur, J.H. (2005). Mobility of pesticides in different soil textures and gravel contents under soil column, Kor. J. Pesti. Sci. 9(4), 330-337.
  54. Lee, W.S. and Kim, J.E. (1998e). Effects of Soil Organic Matter and Oxidoreductase on Adsorption and Desorption of Herbicide Oxadiazon in Soils, Kor. J. Pesti. Sci. 2(3), 70-78.
  55. Lee, Y.D and Kwon, C.H. (2004b). High-Performance Liquid Chromatographic Determination of Cyclosulfamuron Residues in Soil, Water, Rice Grain and Straw, Kor. J. Environ. Agric. 23(4), 251-257. https://doi.org/10.5338/KJEA.2004.23.4.251
  56. Lee, Y.D. and Kwon, C.H. (2004c). Determination of Monocrotophos Residues in Fruits and Soils Using High-Performance Liquid Chromatography, Kor. J. Environ. Agric. 23(4), 245-250. https://doi.org/10.5338/KJEA.2004.23.4.245
  57. Lee, Y.D. and Song, S.D. (2001). Dissipation of Cyclosulfamuron in Rice Paddies, Kor. J. Environ. Agric. 20(4), 269-276.
  58. Lee, Y.D., Kim, H.J., Chung, J.B., and Jeong, B.R. (2000). Loss of Pendimethalin in Runoff and Leaching from Turfgrass Land under Simulated Rainfall, J. Agric. Food Chem. 48, 5376-5382. https://doi.org/10.1021/jf0005869
  59. Moon, Y.H. and Kim, Y.S. (1998). Adsortion and Degradation of Herbicide Napropamide in Soils, Kor. J. Weed. Sci. 18(3), 257-261.
  60. Moon, Y.H. and Kim, Y.S. (2000). Dissipation in Surface Water and Adsorption in Soil on Butachlor, Oxadiazon, Pretilachlor and Thiobencarb, Kor. J. Weed. Sci. 20(1), 32-38.
  61. Oh, K.S., Lee, Y.G., Oh, B.Y., Lee, B.M. and Lee, J.K. (2000). Degradation of the herbicide dicamba by microorganisms isolated from the soil and phosphate extracts of turfgrass , Zoysia japonica S., Kor. J. Pesti. Sci. 4(3), 1-6.
  62. Oh, K.S., Oh, B.Y., Park, S.S., Ihm, Y.B., Kyung, K.S. and Lee, J.K. (1998). Degradation of the herbicide dicamba under sunlight and in soil, Kor, J. Pesti. Sci. 2(1), 53-58.
  63. Oh, S.S., Hyun, H.N. and Moon, D.K., Adsorption Coefficients of Eight Pesticides for Citrus Orchard Soils with Different Soil Organic Matter, Kor. J. Environ. Agric. 19(1), 6-12.
  64. Oh, S.S., Koh, Y.K., Hyun. H.N. and Chung, J.B. (2001). Effect of Activated Carbon, Orpar or Zeolite on Lea - Loss of Fenitrothion, Triadimefon and Diniconazole in Model Green of Golf Course, J. Korean Soc. Agric. Chemoc.iotechnoloc44(2), 97-102.
  65. Park, B.J., Kim, C.S., Park, K.H., Park, H.J., Im, G.J., Choi, J.H. Shim, J.H. and Ryu, G.H. (2006a). Residue and Safety ; Distribution and Mobility of Herbicide (14)C-Molinate in a Rice-Paddy-Soil Lysimeter, Kor. J. Pesti. Sci. 10(3), 172-182.
  66. Park, B.J., Park, H.J., Lee, B.M., Ihm, Y.B., Choi, J.H. and Ryu, G.H. (2005). Persistence and degradation of herbicide molinate in paddy-soil environment, Kor. J. Pesti. Sci. 9(1), 60-69.
  67. Park, D.S., Kim, T.H., Kim, S.S., Lee, S.M., Kim, S.M. and Hur, J.H. (2004a). Monitoring of pesticide residues at alpine and sloped-land in Gangwondo, Korea, Kor. J. Pesti. Sci. 8(3), 189-197.
  68. Park, H.J., Choi, J.H., Park, B.J., Kim, C.S., Ihm, Y.B. and Ryu, G.H. (2004b). Uptake of endosulfan and procymidone from arable soil by several vegetables 1 (green house study), Kor. J. Pesti. Sci. 8(4), 280-287.
  69. Park, K.H., Lee, Y.K., Lee, S.H., Park, B.J., Kim, C.S., Choi, J.H. and Uhm, J.Y. (2006b). Pesticide Degradation Activity of Several Isolates of Soil Bacteria and Their Identification, Kor. J, Pesti. Sci. 10(2), 138-148.
  70. Park, N.I., Lee, I.Y., Park, J.H., Lim, T.K., Chun, J.C., Kim, K.H. and Park, J.E. (2007). Residue Patterns of Butachlor and Pyrazosulfuron-ethyl in Soil, Water and Products of Transplanted Rice Paddy Field, Kor. J. Weed. Sci. 27(1), 49-55.
  71. Tu, O.J. (1998). A Study on Degradation Rate of Carbofuran in Sterilized Soil and Sulfate-added Paddy Soil, Kor. J. Environ. Agric. 17(1), 11-15.
  72. Yang, J.E., Cho, B.Y and You, K.Y. (1997). Leaching and Adsorption of Flupyrazofos(KH-502) in the Soil, Kor. J. Environ. Agric. 16(1),72-79.