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Synthesis and Adhesion Properties of Aliphatic Polyurethane Adhesive

지방족 폴리우레탄 접착제의 합성과 접착 특성

  • Park, Chang-Moo (Department of Industrial Engineering Chemistry, College of Engineering, Chungbuk National University) ;
  • Choi, Seung-Ok (Dong Yang Oil & Fat Co., LTD.) ;
  • Jeong, Noh-Hee (Department of Industrial Engineering Chemistry, College of Engineering, Chungbuk National University)
  • 박창무 (충북대학교 공과대학 공업화학과) ;
  • 최성옥 ((주) 동양유지 연구소) ;
  • 정노희 (충북대학교 공과대학 공업화학과)
  • Received : 2010.10.01
  • Accepted : 2010.12.17
  • Published : 2010.12.31

Abstract

Polyurethane adhesive is used in various fields as flexible packaging materials including a food packaging field. Therefore, the purpose of this study is synthesis of polyurethane adhesive which uses aliphatic isocyanate, and compares with aromatic isocyanate. The isocyanates for this test are toluene-2,4-diisocyanate(TDI), hexamethylene diisocyanate(HDI), 4,4-dicyclohexyl ethane diisocyanate($H_{12}MDI$), and isophorone diisocyanate(IPDI). And, the effect of any other diisocyanate are evaluated by several methods as for curing rate test, accelerate weathering test, and peel strength test. The polyurethane adhesive using curing catalyst and HDI has adhesion strength of about 560 g/15 mm between aluminium foil and nylon, about 1,520 g/15 mm between nylon and CPP. Those parameters are similar to polyurethane adhesive with TDI. Also, in case of curing rate, those are similar to TDI type polyurethane adhesive. Moreover, data of ${\Delta}E$ as color variation by QUV tester is equal to 4.12, as 48% against those of TDI type.

Keywords

References

  1. M. C. Delpech and M. B. Coutinho, "Waterborne Aniconic Polyurethane and Poly(urethane-urea)s: Influenece of Chain Extender on Mechanical and Adhesives Properties", Polymer Testing, 19, 939 (2000). https://doi.org/10.1016/S0142-9418(99)00066-5
  2. I. Akira, I. Ryohei, F. Keishi, and N. Yasuki, U. S. Patent 7,071,280 (2006).
  3. S. Sasano and S. Igarashi, U. S. Patent 6,288,201(2001).
  4. G. A. Priola, F. Ferrero, A. Quaglia, M. Frigione, and C. Cafagna, Polyurethane Resine-Based Adhesives: Curing Reaction and Properties of Cured Systems, In. J. Adhesion & Adhesives, 25, 87 (2005). https://doi.org/10.1016/j.ijadhadh.2004.04.003
  5. A. V. Pocius, "Adhesion and Adhesives Technology", p. 33, Carl Hanser Verlag, New York (1994).
  6. M. W. Ranney, "Epoxy and Urethane Adhesives", p. 55, Noyes Data Corp., New Jersey (1971).
  7. C. Hepburn, "Polyurethane Handbook" , 2nd ed., p. 21, Elsvier Applied Science, New York (1992).
  8. S. Sasano, T. Hori and K. Yamazaki, U. S. Patent 05,478,897 (1995).
  9. NPCS Board of Consultants & Engineers, "Polymer Materials and Applications" , p. 255, Anshan Ltd., UK (2008).
  10. K. L. Mittal, "Adhesive Technology and Applications" , p. 136, Marcel Dekker Inc., New York (2003).
  11. S. M. Kim, N. S. Kwak, Y. K. Yang, B. G. Lim, B. Y. Park, and T. S. Hwang, Synthesis and Physical Properties of Polycaprolactone Based Polyurethanes Using Aliphatic or Aromatic Diisocyanates, Polymer, 29, 253 (2005).
  12. I. S. Cho, S. G. Gang, and S. B. Kim, "Effect of Polyester Polyol and NCO Index to the Physical Properties of Polyurethane Adhesives in Cryogenic and Room Temperature", J. Kor. Institute of Gas, 12, 38 (2008).