DOI QR코드

DOI QR Code

Electrochemistry Characterization of Nickel Using Ethanolamine Compound Additives

에탄올아민화합물 첨가에 대한 니켈의 전기화학적 특성

  • Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University)
  • 박근호 (창원대학교 화공시스템공학과)
  • Received : 2010.10.20
  • Accepted : 2010.12.06
  • Published : 2010.12.31

Abstract

The electrochemistry characterization of metal is important in many industrial applications. In this study, we investigated the C-V diagrams related to the electrochemistry characterization of nickel. We determined electrochemical measurement by using cyclic voltammetry with a three electrode system. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650mV and measured to the initial point. The scan rate were 100, 150, 200 and 200mV/s. As a result, the C-V characterization of nickel using ethanolamine and ethylethanolamine inhibitor appeared irreversible process caused by the oxidation current from the cyclic voltammogram. After adding ethanolamine compound additive, adsorption film constituted, and the passive phenomena happened. According to the results by cyclic voltammetry method, it was revealed that the effect of the electrochemistry characterization of nickel depends on ethanolamine structure interaction to adsorption complex.

Keywords

References

  1. J. E. Singley and D. W. Deberry, Corrosion Prevention and Control in Water Treatment and Supply Systems, Pollution Technology Review, 122, 8, (1985).
  2. D. Landolt, "Corrosion and surface Chemistry of metals", p.204, EPFL Press, Lausanne, Switzerland (2007).
  3. A. Igual Munoz, J. Garcia Ant'on, J. L. Gui'on, and V. P'erez Herranz, Comparison of inorganic inhibitors of copper, nickel and copper-nickels in aqueous lithium bromide solution, Electrochimica Acta, 50, 957 (2004). https://doi.org/10.1016/j.electacta.2004.07.048
  4. G. Gece and S. Bilgic, A theoretical study on the inhibition efficiencies of some amino acids as corrosion inhibitors of nickel, Corrosion Sci., 52, 3435 (2010). https://doi.org/10.1016/j.corsci.2010.06.015
  5. R. S. Goncalves, D. S. Azambuja, and A. M. S. Lucho, Electrochemical studies of propargyl alcohol as corrosion inhibitor for nickel, copper, and copper/nickel(55/45) allopy, Corrosion Sci., 44, 467 (2002). https://doi.org/10.1016/S0010-938X(01)00069-5
  6. Z. Hu, K. Chandran, D. Grasso, and B. F. Smets, Effect of Nickel and Cadmium Speciation on Nitrification Inhibition, Environ. Sci. Technol. 36, 3074 (2002). https://doi.org/10.1021/es015784a
  7. P. G. Cao, J. L. Yao, J. W. Zheng, R. A. Gu, and Z. Q. Tian, Comparative Study of Inhibition Effects of Benzotriazole for Metals in Neutral Solutions As Observed with Surface- Enhanced Raman Spectroscopy, Langmuir, 18, 100 (2002). https://doi.org/10.1021/la010575p
  8. K. H. Park, A Study on the Inhibition Effect of Metal Corrosion Using Organic Copmpound Containing an Amine Group, J. Kor. Oil Chem. Soc., 27(3), 361 (2010).
  9. K. H. Park and B. C. Min, A Study on the behaviors of electrochemical polarization according to the organic inhibitor involved amine groups for carbon steel, The Research Bulletin of Changwon National University, 14, 379, (1992).
  10. E. E. Stansbury and R. A. Buchman, "Fundamentals of electrochemical corrosion", P.63, ASM International, Ohio, U.S.A.(2004).
  11. S. H. Choi and T. C. Son, J. Y. Song, K. H. Park, Electrochemical Properties of Organic Ultra Thin Films of Fatty Acid and Phospholipid Mixture, J. Kor. Oil Chem. Soc., 23(2), 137 (2006).
  12. T. C. Son, C. H. Mim, and K. H. Park, Electrochemical Properties of Langmuir-Blodgett(LB) Films of Alkyl Bromides, J. Kor. Oil Chem. Soc., 26(4), 451 (2009).
  13. C. H. Mim, T. C. Son, and K. H. Park, Electrochemical Properties of Ultrathin Film Functional Polyimide by Langmuir-Blodgett Method, J. Kor. Oil Chem. Soc., 26(4), 400 (2009).
  14. D. S. Park, Study for Electrode Reaction Characteristics by Cyclic Voltammetry, Poly. Sci. Tec., 14, 356 (2003).
  15. T. C. Son, D. S. Kim, and K. H. Park, Electrochemical Properties of Langmuir-Blodgett (LB) Monolayer Films of Alkyl Bromides Mixture, J. Kor. Oil Chem. Soc., 27(2), 202 (2010).
  16. H. S. Kim Y. I. Yun, E. J. Cho, Y. H. Choi, and M. Y. Oh, Analysis of Electrocoagulation Process using Faraday's Law, J. Ind.. Tec., 21, 351 (2001).