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Influence of Surface Treatment of Multi-walled Carbon Nanotubes on Interfacial Interaction of Nanocomposites

  • Received : 2010.05.02
  • Accepted : 2010.06.11
  • Published : 2010.06.30

Abstract

In this work, the effect of aminized multi-walled carbon nanotubes (NH-MWNTs) on the mechanical interfacial properties of epoxy nanocomposites was investigated by means of fracture toughness, critical stress intensity factor ($K_{IC}$), and impact strength testing, and their morphology was examined by scanning electron microscope (SEM). It was found that the incorporation of amine groups onto MWNTs was confirmed by the FT-IR and Raman spectra. The mechanical interfacial properties of the epoxy nanocomposites were remarkably improved with increasing the NH-MWNT content. It was probably attributed to the strong physical interaction between amine groups of NH-MWNTs and epoxide groups of epoxy resins. The SEM micrographs showed that NH-MWNTs were uniformly embed and bonded with epoxy resins, resulted in the prevention of the deformation and crack propagation in the NH-MWNTs/epoxy nanocomposites.

Keywords

References

  1. Iijima, S. Nature 1991, 56, 354.
  2. Bikiaris, D.; Vassiliou, A.; Chrissafis, K.; Paraskevopoulos, K. M.; Jannakoudakis, A.; Docoslis, A. Polym. Degrad. Stab. 2008, 93, 952. https://doi.org/10.1016/j.polymdegradstab.2008.01.033
  3. Lee, Y. S.; Im, J. S.; Yun, S. M.; Nho, Y. C., Kang, P. H.; Jin, H. Carbon Lett. 2009, 10, 314. https://doi.org/10.5714/CL.2009.10.4.314
  4. Farzi, G.; Akbar, S.; Beyou, E.; Cassagnau, P.; Melis, F. Polymer 2009, 50, 5901. https://doi.org/10.1016/j.polymer.2009.10.020
  5. Tang W.; Santare, M. H.; Advani, S. G. Carbon 2003, 41, 2779. https://doi.org/10.1016/S0008-6223(03)00387-7
  6. Kim, K. S.; Park, S. J. Synthetic Metals 2010, 160, 123. https://doi.org/10.1016/j.synthmet.2009.10.018
  7. Zhu, B. K.; Xie, S. H.; Xu, Z. K.; Xu, Y. Y. Compos. Sci. Technol. 2006, 66, 548. https://doi.org/10.1016/j.compscitech.2005.05.038
  8. Yuan, J.; Liew, K. M. Carbon 2009, 47, 713. https://doi.org/10.1016/j.carbon.2008.11.002
  9. Manchado, M. A. L.; Valentini, L.; Biagiotti, J.; Kenny, J. M. Carbon 2005, 43, 1499. https://doi.org/10.1016/j.carbon.2005.01.031
  10. Basiuk, E. V.; Gromovoy, T. Y.; Datsyuk, A.; Palyanytsya, B. B.; Pokrovskiy, V. A.; Basiuk, V. A. J. Nanosci. Nanotechnol. 2005, 5, 984. https://doi.org/10.1166/jnn.2005.131
  11. Star, A.; Liu, Y.; Grant, K.; Ridvan, L.; Stoddart, J. F.; Steuerman, D. W., Diehl, M. R.; Boukai, A.; Heath, J. R. Macromolecules 2003, 36, 553. https://doi.org/10.1021/ma021417n
  12. Park, S .J.; Cho, M. S.; Lim, S. T.; Choi, H. J.; Jhon, M. S. Macromol. Rapid. Commum. 2003, 24, 1070. https://doi.org/10.1002/marc.200300089
  13. Sobkowicz, M. J.; Dorgan, J. R.; Gneshin, K. W. Herring, A. M.; McKinnon, J. T. Carbon 2009, 47, 622. https://doi.org/10.1016/j.carbon.2008.10.051
  14. Ramanathan, T.; Liu, H.; Brinson, L. C. J. Polym. Sci. B:Polym. Phys. 2005, 43, 2269. https://doi.org/10.1002/polb.20510
  15. Steven, J. L.; Huang, A. Y.; Peng, H. Q.; Chang, I. W.; Khabashesku, V. N.; Margrave, J. L. Nano Lett. 2003, 3, 331. https://doi.org/10.1021/nl025944w
  16. Shen, J.; Huang, W.; Wu, L.; Hu, Y.; Ye, M. Compos. Sci. Technol. 2007, 67, 3041. https://doi.org/10.1016/j.compscitech.2007.04.025
  17. Velasco-Santos, C.; Martinez-Hernandez, A. L.; Lozada- Cassou, M.; Alvarez-Castillo, A.; Castano, V. M. Nanotechnology 2002, 13, 495. https://doi.org/10.1088/0957-4484/13/4/311
  18. Jin, F.L.; Park, S. J. J. Polym. Sci. Part B: Polym. Phys. 2006, 44, 3348. https://doi.org/10.1002/polb.20990
  19. Park, S. J.; Kim, H. C. J. Polym. Sci.: Part B: Polym. Phys. 2001, 139, 121.
  20. Thongruang, W.; Spontak,R. J.; Balik,C. M. Polymer, 2002, 43, 2279. https://doi.org/10.1016/S0032-3861(02)00043-5
  21. Park, S. J.; Jin, F. L.; Lee, C.; Mater. Sci. Eng. A 2004, 402, 335.

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