Effect of PCB Surface Finishs on Intermetallic Compound Growth Kinetics of Sn-3.0Ag-0.5Cu Solder Bump

Sn-3.0Ag-0.5Cu 솔더범프의 금속간화합물 성장거동에 미치는 PCB 표면처리의 영향

  • Jeong, Myeong-Hyeok (School of Materials Science and Engineering, Andong National University) ;
  • Kim, Jae-Myeong (School of Materials Science and Engineering, Andong National University) ;
  • Yoo, Se-Hoon (Korea Institute of Industrial Technology, Micro-Joining Center) ;
  • Lee, Chang-Woo (Korea Institute of Industrial Technology, Micro-Joining Center) ;
  • Park, Young-Bae (School of Materials Science and Engineering, Andong National University)
  • 정명혁 (안동대학교 신소재공학부 청정소재기술연구센터) ;
  • 김재명 (안동대학교 신소재공학부 청정소재기술연구센터) ;
  • 유세훈 (한국생산기술연구원 마이크로조이닝 산학연사업단) ;
  • 이창우 (한국생산기술연구원 마이크로조이닝 산학연사업단) ;
  • 박영배 (안동대학교 신소재공학부 청정소재기술연구센터)
  • Received : 2010.02.23
  • Accepted : 2010.03.28
  • Published : 2010.03.30

Abstract

Thermal annealing and electromigration test were performed at $150^{\circ}C$ and $4{\times}10^3\;A/cm^2$ conditions in order to investigate the effect of PCB surface finishs on the growth kinetics of intermetallic compound (IMC) in Sn-3.0Ag-0.5Cu solder bump. The surface finishes of the electrodes of printed circuit board (PCB) were organic solderability preservation (OSP), immersion Sn, and electroless Ni/immersion gold (ENIG). During thermal annealing, the OSP and immersion Sn show similar IMC growth velocity, while ENIG surface finish had much slower IMC growth velocity. Applying electric current accelerated IMC growth velocity and showed polarity effect due to directional electron flow.

Sn-3.0Ag-0.5Cu 솔더범프의 금속간화합물 성장거동에 미치는 PCB 표면처리의 영향을 알아보기 위해서 PCB 패드 표면에 각각 OSP, immersion Sn, 그리고 ENIG를 처리하였고, 열처리는 $150^{\circ}C$ 조건에서 실험을 실시하였다. 또한, 전류인가시 Sn-3.0Ag-0.5Cu 솔더범프의 접합부 계면반응에 미치는 표면처리의 영향을 알아보기 위해서 $150^{\circ}C$, $4{\times}10^3\;A/cm^2$ 조건에서 electromigration특성을 비교 평가하였다. 열처리시 OSP와 immersion Sn의 금속간화합물 성장거동은 서로 비슷한 경향을 보인 반면, ENIG는 다른 표면처리에 비해 훨씬 느린 성장거동을 보였다. electromigration특성 평가결과 열처리에 비해 금속간화합물의 성장이 가속화되나 표면처리별 경향은 유사하였고, 전자 이동 방향에 따른 음극-양극에서 금속간화합물 형성의 차이를 보이는 극성효과(polarity effect)가 나타나는 것을 알 수 있었다.

Keywords

References

  1. Directive 2002/95/EC of the European Parliament and of the Council, Restriction of the Use of Certain Hazardous Substances in Electrical and Electronic Equipment (RoHS), EU (2003).
  2. European Union WEEE Directive, 3d Fraft (2000).
  3. J. Muller, H. Griese, and H. Reichl, "Environmental Aspects of PCB Microintegration" ICP works '99, Minneapolis (1999).
  4. D. Suh, D. W. Kim, P. Liu, H. Kim, J. A. Weninger, C. M. Kumar, A. Prasad, B. W. Grimsley and H. B. Tejada, "Effects of Ag Content on Fracture Resistance of Sn-Ag-Cu Lead-Free Solders under High-Strain Rate Conditions", Mater. Sci. Eng., A 460, 595 (2007).
  5. M. McCormack and S. Jin, "Progress in the Design of New Lead-Free Solder Alloys", JOM, 45(7), 36 (1993). https://doi.org/10.1007/BF03222379
  6. F. Carson, S. M. Lee and N. Vijayaragavan, "Controlling Top Package Warpage for PoP Applications", Proc. 57th Electronic Components and Technology Conference (ECTC), Nevada, pp.737-742, IEEE Components, Packaging and Manufacturing Technology (CPMT) (2007).
  7. J. M. Koo, C. Y. Lee and S. B. Jung, "Effect of Reflow Number on Mechanical and Electrical Properties of Ball Grid Array (BGA) Solder Joints", J. Microelectron. Packag. Soc., 14(4), 71 (2007).
  8. V. Denis and C. Gilles, "OSP Coatings: The Nitrogen Solution", Proc. 18th Electronic Manufacturing Technology Symposium, pp.101-104, IEEE/CMPT International (1995).
  9. D. Chang, F. Bai, Y. P. Wang and C.S. Hsiao, "The Study of OSP as Reliable Surface Finish of BGA Substrate", Proc. 6th Electronics Packaging Technology Conference (EPTC), Singapore, pp.149-153, IEEE (2004).
  10. H. K.Lee, S. H. Son, H. Y. Lee and J. M. Jeon, "A Study on the ENIG Surface Finish Process and its Properties", J. Kor. Inst. Surf. Eng., 40(1), 32 (2007). https://doi.org/10.5695/JKISE.2007.40.1.032
  11. K. Zeng, R. Stierman, T. C. Chiu, D. Edwards, K. Ano and K. N. Tu, "Kirkendall Void Formation in Eutectic Sn-Pb Solder Joint on Bare Cu and its Effect on Joint Reliability", J. Appl. Phys., 97, 024508 (2005). https://doi.org/10.1063/1.1839637
  12. M. Ding, G Wang, B. Chao, P. S. Ho, P. Su and T. Uehling, "Effect of Contact Metallization on Electromigration Reliability of Pb-free Solder Joints", J. Appl. Phys., 99, 094906 (2006). https://doi.org/10.1063/1.2193037
  13. S. K. Kang, W. K. Choi, D. Y. Shih, D. W. Henderson, T. Gosselin, A. Sarkhel, C. Goldsmith and K.J. Puttlitz, "$Ag_3Sn$ Plate Formation in the Solidification of Near-Ternary", JOM, 55(6), 61 (2003). https://doi.org/10.1007/s11837-003-0143-6
  14. G. T. Lim, J. H. Lee, B. J. Kim, K. W. Lee, M. J. Lee, Y. C. Joo and Y. B. Park, "Effect of Thermal Aging on the Intermetallic Compound Growth Kinetics in the Cu Pillar Bump", J. Microelectron. Packag. Soc., 14(4), 15 (2007).
  15. C. M. Tsai, W. C. Luo, C. W. Chang, Y. C. Shieh and C. R. Kao, "Cross-Interaction of Under-Bump Metallurgy and Surface Finish in Flip-Chip Solder Joints", J. Electron. Mater., 33(12), 1424 (2004). https://doi.org/10.1007/s11664-004-0082-1
  16. J. M. Koo, B. Q. Vu, Y. N. Kim, J. B. Lee, J. W. Kim, D. U. Kim, J. H. Moon and S. B. Jung, "Mechanical and Electrical Properties of Cu/Sn-3.5Ag/Cu Ball Grid Array (BGA) Solder Joints after Multiple Reflows", J. Electron. Mater., 37, 118 (2008). https://doi.org/10.1007/s11664-007-0301-7
  17. B. Chao, S. H. Chae, X. Zhang, K. H. Lu, J. Im and P. S. Ho, "Investigation of Diffusion and Electromigration Parameters for Cu-Sn Intermetallic Compounds in Pb-Free Solders using Simulated Annealing", Acta Materialia, 55(8), 2805 (2007). https://doi.org/10.1016/j.actamat.2006.12.019
  18. J. H. Choi, S. W. Jun, H. J. Won, B. Y. Jung and T. S. Oh, "Electromigration Behavior of the Flip-Chip Bonded Sn- 3.5Ag-0.5Cu Solder Bumps", J. Microelectron. Packag. Soc., 11(4), 43 (2004).
  19. J. S. Zhang, Y. C. Chan, Y. P. Wu, H. J. Xi and F. S. Wu, "Electromigration of Pb-Free Solder under a Low Level of Current Density", J. Alloys Compd., 458(1-2), 492 (2008). https://doi.org/10.1016/j.jallcom.2007.04.040
  20. L. Xu, J. H. L. Pang, F. Ren and K. N. Tu, "Electromigration Effect on Intermetallic Growth and Young's Modulus in SAC Solder Joint", J. Electron. Mater., 35(12), 2116 (2006). https://doi.org/10.1007/s11664-006-0321-8
  21. B. Y. Wu and Y. C. Chan, "Electric Current Effect on Microstructure of Ball Grid Array Solder Joint", J. Alloys Compd., 392(1-2), 237 (2005). https://doi.org/10.1016/j.jallcom.2004.09.044
  22. H, Gan and K. N. Tu, "Polarity Effect of Electromigration on Kinetics of Intermetallic Compound Formation in Pb-Free Solder V-Groove Samples", J. Appl. Phys., 97. 063514 (2005). https://doi.org/10.1063/1.1861151