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A study on the electrical characteristics of CdZnS/CdTe heterojunction

CdZnS/CdTe 이종접합의 전기적 특성에 관한 연구

  • Received : 2010.03.09
  • Accepted : 2010.06.08
  • Published : 2010.07.30

Abstract

A CdS film has been used as a window layer in CdTe and Cu(In,Ga)$Se_2$ thin films solar cell. Partial substitution of Zn for Cd increases the photocurrent and the open-circuit voltage by providing a match in the electron affinities of the two materials and the higher band gap. In this paper, CdZnS/CdTe and CdS/CdTe heterojunctions were fabricated and the electrical characteristics were investigated. Current-voltage-temperature measurements showed that the current transport for CdS/CdTe heterojunction was controlled by both tunneling and interface recombination. However, CdZnS/CdTe heterojunction displayed different current transport mechanism with the operating temperature. For above room temperature, the current transport of device was generation/recombination in the depletion region and was the leakage current and/or tunneling in the range below room temperature.

CdTe 및 Cu(In,Ga)$Se_2$ 박막 태양전지의 창층으로 널리 이용되는 CdS에서 Cd의 일부를 Zn으로 치환하면 두 물질 사이의 전자 친화력의 정합이 향상되고 에너지 밴드 갭이 증가하여 개방전압 및 광전류를 증가시킬 수 있다. 본 연구에서는 태양전지와 같은 광전소자에 적용되는 CdZnS와 CdTe로 구성되는 이종접합 소자를 제작하고 접합에서의 전류 전도기구를 조사하기 위해 온도에 따른 전류-전압 특성을 분석하였다. CdS/CdTe 접합의 전류 흐름은 계면 재결합과 터널링의 조합에 의해 조절되지만 CdZnS/CdTe 접합의 경우 상온 이상의 온도에서는 공핍층에서의 생성/재결합, 상온 이하의 온도에서는 누설 전류나 터널링에 의해 전류 흐름이 제한됨을 알 수 있었다.

Keywords

References

  1. I.M. Dharmadasa, "Latest developments in CdTe, CuInGaSe2 and GaAs/AlGaAs thin film PV solar cells", Current Applied Physics, vol. 9 pp.e2-e6, 2009. https://doi.org/10.1016/j.cap.2008.12.021
  2. Repins, M.A. Contreras, B. Egaas, C. DeHart, J. Schart, C.L. Perkins, B. To and R. Noufi, "Accelerated Publication 19.9%-efficient ZnO/CdS/CuInGaSe2 solar cell with 81.2% fill factor", Prog. Photovolics, vol. 16, pp. 235-239, 2008. https://doi.org/10.1002/pip.822
  3. M. Celalettin Baykul, Nilgun Orhan, "Band alignment of Cd(1-x)ZnxS produced by spray pyrolysis method", Thin Solid Films, vol. 518, pp.1925-1928, 2010. https://doi.org/10.1016/j.tsf.2009.07.142
  4. S.D. Chavhan, S. Senthilarasu, Soo-Hyoung Lee, "Annealing effect on the structural and optical properties of a Cd1-xZnxS thin film for photovoltaic applications", Applied Surface Science, vol. 254 pp.4539-4545, 2008. https://doi.org/10.1016/j.apsusc.2008.01.054
  5. R. H. Bube, F. Buch, A. L. Fahrenbruch, Y. Y. Ma, and K. W. Mitchell, "Photovoltaic Energy Conversion with n-CdS-p-CdTe Heterojunctions and Other II-VI Junctions", IEEE Trans. Electron Devices, vol. ED-24, no. 4, pp.487-492, 1977.
  6. Jae-Hyeong Lee, Woo-Chang Song, Jun-Sin Yi, Kea-Joon Yang, Wun-Dong Han, Joon Hwang, "Growth and properties of the Cd1-xZnxS thin films for solar cell applications", Thin Solid Films, vol. 431-432, pp.349-353, 2003. https://doi.org/10.1016/S0040-6090(03)00526-1
  7. H. D. Kim, "Preparation and Photovoltaic Properties of Sintered CdS/CdTe Solar Cells with TCO Films", Ph. D. thesis, KAIST, 1995.
  8. S. K. Das, "Variation of Properties of Electrodeposited CdS/CdTe Solar Cells Deposited onto Different Transparent Conducting Oxide Substrates", Thin Solid Films, vol. 226, pp.259-264, 1993. https://doi.org/10.1016/0040-6090(93)90388-6
  9. S. A. Ringel, A. W. Smith, M. H. MacDougal, and A. Rohalgi, J. Appl. Phys., vol. 70, no. 2, pp.881-889, 1991. https://doi.org/10.1063/1.349652
  10. G. C. Morris and S. K. Das, "Influence of CdCl2 Treatment of CdS on the Properties of Electrodeposited CdS/CdTe Thin Film Solar Cells", Proc. 22nd IEEE Photovoltaic Specialists Conference, New York, pp.469-474, 1993.