Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지
DOI QR코드

DOI QR Code

Study on the Compatibility of Brominated Epoxy Resin with Nylon 6 and the Characterization of the Blends

브롬화 에폭시 수지와 나일론 6의 상용성 및 블렌드 수지의 물성에 관한 연구

  • Kim, Hwan-Chul (Department of Textile Material Engineering, Chonbuk National University)
  • 김환철 (전북대학교 섬유소재시스템공학과)
  • Received : 2010.01.19
  • Accepted : 2010.03.29
  • Published : 2010.06.27
Download PDF
⟨ Previous Next ⟩

Abstract

Nylon 6 was blended with a brominated epoxy resin, tetrabromobisphenol A diglycidyl ether (DGEBBA), to enhance flame retardant property. Thermal properties of the blends were analyzed by DSC. Melting point and crystallization temperature decreased as the amount of epoxy resin increased. Melt index and relative viscosity decreased as the amount of the epoxy resin increased. When the blended amount of the epoxy resin was below 5%, the melt index decreased while the relative viscosity slightly increased. The blend resin was successfully spun into fiber without swelling or drawing the resonance phenomena. However, both the tenacity and elongation of the fiber decreased by increasing the amount of the DGEBBA.

Keywords

References

  1. S. Kim, J. Kim, S. H. Lim, W. H. Jo, and C. R. Choe, Effects of Mixing Temperature on the Morphology and Toughness of Epoxy/Polyamide Blends, J. Appl. Polym. Sci., 72, 1055-1063(1999). https://doi.org/10.1002/(SICI)1097-4628(19990523)72:8<1055::AID-APP10>3.0.CO;2-8
  2. J. K. Kim, S. T. Kim, C. R. Choe, S. G. Rho, and M. C. Lee, Toughening of Epoxy by Inclusion of Thermoplastic Particles, Polymer (Korea), 19, 65-74(1995).
  3. Z. Zhong and Q. Guo, Miscibility and Cure Kinetics of Nylon/Epoxy Resin Reactive Blends, Polymer, 39, 3451-3458(1998). https://doi.org/10.1016/S0032-3861(97)10237-3
  4. Y. Huang, Y. Liu, and C. Zhao, Morphology and Properties of PET/PA-6/E-44 Blends, J. Appl. Polym. Sci., 69, 1505-1515(1998). https://doi.org/10.1002/(SICI)1097-4628(19980822)69:8<1505::AID-APP4>3.0.CO;2-G
  5. J. An, J. GE, and Y. Liu, Special Effect of Epoxy Resin E-44 on Compatibility and Mechanical Properties of Poly(butylene terephthalate)/Polyamide-6 Blends, J. Appl. Polym. Sci., 60, 1803-1810(1996). https://doi.org/10.1002/(SICI)1097-4628(19960613)60:11<1803::AID-APP3>3.0.CO;2-P
  6. C. Chiang and F. Chang, Polymer Blends of Polyamide-6 and Poly(phenylene ether) Compatibilized by a Multifunctional Epoxy Coupler, J. Appl. Polym. Sci., Part B: Polym. Physics, 36, 1805-1819(1998). https://doi.org/10.1002/(SICI)1099-0488(199808)36:11<1805::AID-POLB2>3.0.CO;2-P
  7. M. Y. Ju and F. C. Chang, Polymer Blends of PET-PS Compatibilized by SMA and Epoxy Dual Compatibilizers, J. Appl. Polym. Sci., 73, 2029-2040(1999). https://doi.org/10.1002/(SICI)1097-4628(19990906)73:10<2029::AID-APP21>3.0.CO;2-U
  8. S. V. Levchik and E. D. Weil, Combution and Fire Retardancy of Aliphatic Nylons, Polym. Int., 49, 1033-1073(2000). https://doi.org/10.1002/1097-0126(200010)49:10<1033::AID-PI518>3.0.CO;2-I
  9. E. D. Weil and S. Levchik, Current Practice and Recent Commercial Developments in Flame Retardancy of Polyamides, J. Fire Sci., 22, 251-264(2004). https://doi.org/10.1177/0734904104040546
  10. H. C. Chin and F. C. Chang, Reactive Compatibilization of PET/LCP Blends by a Multifunctional Epoxy Couplers, Polymer, 38, 2947-2953(1997). https://doi.org/10.1016/S0032-3861(96)00840-3
  11. H. C. Kim, D. H. Kim, J. K. Park, J. C. Lim, and Y. W. Park, Miscibility of Flame Retardant Epoxy Resin with Poly(ethyleneterephthalate) and the Characterization of the Blends, Fibers and Polymers, 10, 594-600 (2009). https://doi.org/10.1007/s12221-010-0594-7

Cited by

  1. A Study of Characteristics of Weft Used in Wig Manufacturing vol.24, pp.3, 2012, https://doi.org/10.5764/TCF.2012.24.3.204
  2. Synthesis of Polyurethane/Epoxy Hybrid Resin used for Damper of Loudspeaker vol.28, pp.1, 2016, https://doi.org/10.5764/TCF.2016.28.1.40