Journal of Electrochemical Science and Technology

  • 제1권1호
  • /
  • Pages.1-9
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  • 2010
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  • 2093-8551(pISSN)
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  • 2288-9221(eISSN)
한국전기화학회 (The Korean Electrochemical Society)
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Electrochemistry of Conductive Polymers 46. Polymer Films as Overcharge Inhibitors for Lithium-Ion Rechargeable Batteries

  • Choi, Shin-Jung (Department of Chemistry, Pohang University of Science and Technology) ;
  • Park, Su-Moon (Interdisciplinary School of Green Energy, Ulsan National Institute of Science & Technology)
  • 투고 : 2010.08.05
  • 심사 : 2010.08.16
  • 발행 : 2010.09.30
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초록

Conducting polymer films grown from various aromatic compounds have been evaluated as overcharge protecting additives for lithium ion rechargeable batteries. The polymer films were grown electrochemically under the conditions similar to those encountered during the overcharging processes of lithium batteries and subsequently characterized by potentiodynamic, electrochemical quartz crystal microbalance, electrochemical impedance spectroscopic, and scanning electron microscopic experiments. Results indicate that bicyclic and polycyclic aromatic hydrocarbons would be poor candidates for inhibitors, while biphenyl, terphenyl, and benzene derivatives displayed excellent performances. Mixed polymer films grown from o-terphenyl and p-xylene show the best performance among the candidates.

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참고문헌

  1. P. Arora and Z. Zhang, Chem. Rev., 104, 4419 (2004). https://doi.org/10.1021/cr020738u
  2. L. Xiao, X. Ai, Y. Cao, and H. Yang, Electrochim. Acta, 49, 4189 (2004). https://doi.org/10.1016/j.electacta.2004.04.013
  3. K. Shima, K. Shizuka, M. Ue, H. Ota, T. Hatozaki, and J.-I. Yamaki, J. Power Sources, 161, 1264 (2006). https://doi.org/10.1016/j.jpowsour.2006.05.029
  4. S. Tobishima, Y. Ogino, and Y. Watanawa, J. Appl. Electrochem., 33, 143 (2003). https://doi.org/10.1023/A:1024039302020
  5. X.M. Feng, X.P. Ai, and H.X. Yang, J. Appl. Electrochem., 34, 1199 (2004). https://doi.org/10.1007/s10800-004-0771-8
  6. K. Abe, Y. Ushigoe, H. Yoshitake, and M. Yoshio, J. Power Sources, 153, 328 (2006). https://doi.org/10.1016/j.jpowsour.2005.05.067
  7. H. Lee, J.H. Lee, S. Ahn, H.-J. Kim, and J.-J. Cho, Electrochem. Solid State Lett., 9, A307 (2006). https://doi.org/10.1149/1.2193072
  8. S.-J. Choi and S.-M. Park, J. Electrochem. Soc., 155, A783 (2008). https://doi.org/10.1149/1.2968229
  9. S.-M. Park in Handbook of Conductive Molecules and Polymers, H. S. Nalwa, Vol. 3, Wiley, Chichester, England, p 429 (1997).
  10. S.-M. Park and H.J. Lee, Bull. Korean Chem. Soc., 26, 697 (2005). https://doi.org/10.5012/bkcs.2005.26.5.697
  11. H.J. Lee, S.-y. Cui, and S.-M. Park, J. Electrochem. Soc., 148, D139 (2001). https://doi.org/10.1149/1.1401080
  12. H.S. Sharma and S.-M. Park, J. Electrochem. Soc., 148, E61 (2004).
  13. B.A. Boukamp, Equivalent Circuit User’s Manual, 2nd ed., University of Twente, Enschede, the Netherlands (1989).
  14. B.J. Johnson and S.-M. Park, J. Electrochem. Soc., 143, 1269 (1996). https://doi.org/10.1149/1.1836628
  15. J.-W. Kim and S.-M. Park, Electrochem. Solid State Lett. 3, 385 (2000). https://doi.org/10.1149/1.1391155
  16. C.-H. Pyun and S.-M. Park, Anal. Chem., 58, 251 (1986). https://doi.org/10.1021/ac00292a063
  17. C. Zhang and S.-M. Park, Anal. Chem., 60, 1639 (1988). https://doi.org/10.1021/ac00166a037
  18. C. Zhang and S.-M. Park, Bull. Korean Chem. Soc., 10, 302 (1989).
  19. H.J. Lee, J. Lee, and S.-M. Park, J. Phys. Chem. B, 114, 2660 (2010) https://doi.org/10.1021/jp9113859
  20. B. Fan, L. Qu, and G. Shi, J. Electroanal. Chem., 575, 287 (2005). https://doi.org/10.1016/j.jelechem.2004.10.002
  21. Z. Huang, L. Qu, G. Shi, F. Chen, and X. Hong, J. Electroanal. Chem., 556, 159 (2003). https://doi.org/10.1016/S0022-0728(03)00341-3
  22. C.K. Mann and K.K. Barnes, Electrochemical Reactions in Nonaqueous Systems, Dekker, New York, 1970, Chapter 3.