Ageing Behavior of Beeswax Coated Hanji(I) - Thermal Ageing Test of Beeswax Coated Hanji -

밀랍지의 열화 거동 (제1보) - 열에 의한 밀랍지의 열화 -

  • Kim, Kang-Jae (Dept. of Wood Science and Technology, College of Agriculture and Life Science, Kyungpook National University) ;
  • Eom, Tae-Jin (Dept. of Wood Science and Technology, College of Agriculture and Life Science, Kyungpook National University)
  • 김강재 (경북대학교 농업생명과학대학 임산공학과) ;
  • 엄태진 (경북대학교 농업생명과학대학 임산공학과)
  • Received : 2010.05.31
  • Accepted : 2010.06.16
  • Published : 2010.06.30

Abstract

The annals of Joseon Dynasty has been known as one of the UNESCO's Memory of the World Heritage. The annals of Joseon Dynasty composed with two kind of books, wax coated book and non coated book. Especially the waxed book have been severely damaged by various reason. For the safety preservation of the annals of Joseon Dynasty waxed book, the thermal ageing mechanism of beeswax coated Hanji paper has been evaluated. The weight loss of waxed Hanji were rapidly increased until 30 days in three temperatures(105, 120 & $150^{\circ}C$) and stabilized after 30 days. The acid value and relative intensity of carbonyl groups in beeswax were increased with strong conditions. This means that the deterioration of beeswax should be progressed with oxidizing reaction. The physical strength and the crystallinity of dewaxed Hanji were decreased with ageing time.

Keywords

References

  1. 김영기, 세종대왕-15세기 한국의 빛-, 신구문화사 (1998).
  2. 송기중, 신병주, 박지선, 이인성, 조선왕조실록 보존을 위한 기초 조사연구(1), 서울대학교출판부 (2005).
  3. S.H. Jeong, S.Y. Jeong, J.H. Seo, H.Y. Lee, The study of restoration technique of wax-treated volume for the annals of the Joseon Dynasty(1) -Evaluation of degradation behavior of reproduced waxy paper-, KTAPPI, 39(1):56-63 (2007).
  4. 박지선 외, 조선왕조실록 보존에 관한 연구, 규장각증축 준공기념 국제학술회의, 23-37 (2005).
  5. 후세가와 켄죠 저, 최태규 외 옮김, 왁스의 성질과 응용, 동화기술 (2008).
  6. Anne-Laurence Dupont, Study of the degradation of gelatin in paper upon aging using aqueous size-exclusion chromatography, J. Chromatography A, 950:113-124 (2002). https://doi.org/10.1016/S0021-9673(02)00010-9
  7. T. J. Eom, K. J. Kim, J. H. Cho, Characterization of artificially aged beeswax and beeswax of waxed volume in Joseon Dynasty annals, Proceedings of the 2008 international symposium on conservation science for cultural heritage, 181-183(2008).
  8. M. Ali, A.M. Emsley, H. Herman, R.J. Heywood, Spectroscopic studies of the ageing of cellulosic paper, Polymer, 42, 2893-2900(2001). https://doi.org/10.1016/S0032-3861(00)00691-1
  9. S. Tasker, J.P.S. Badyal, S.C.E. Backson, R.W. Richards, Hydroxyl accessibility in cellulose, Polymer, 4717-4721(1994).
  10. J. Lojewska, P. Miskowiec, T. Lojewski, L. M. Promiewicz, Cellulose oxidative and hydrolytic degradation: In situ FTIR approach, Polymer Degradation and Stability, 88, 512-520(2005). https://doi.org/10.1016/j.polymdegradstab.2004.12.012
  11. M. Regert, S. Colninart, L. Degrand, O. Decavallas, Chemical alteration and use of beeswax through time: accelerated ageing tests and analysis of archaeological samples from various environmental contexts, Archaeometry, 43(4), 549-569(2001). https://doi.org/10.1111/1475-4754.00036