Environmental Engineering Research

  • 제16권3호
  • /
  • Pages.131-136
  • /
  • 2011
  • /
  • 1226-1025(pISSN)
  • /
  • 2005-968X(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
권호 표지
DOI QR코드

DOI QR Code

Effects of Adding UV and H2O2 on the Degradation of Pharmaceuticals and Personal Care Products during O3 Treatment

  • Kim, Il-Ho (Water Resources & Environment Research Department, Korea Institute of Construction Technology, Department of Construction Environment Engineering, University of Science & Technology, Korea Institute of Construction Technology) ;
  • Kim, Seog-Ku (Water Resources & Environment Research Department, Korea Institute of Construction Technology, Department of Construction Environment Engineering, University of Science & Technology, Korea Institute of Construction Technology) ;
  • Lee, Hyun-Dong (Water Resources & Environment Research Department, Korea Institute of Construction Technology, Department of Construction Environment Engineering, University of Science & Technology, Korea Institute of Construction Technology) ;
  • Tanaka, Hiroaki (Research Center for Environmental Quality Management, Kyoto University)
  • 투고 : 2010.06.22
  • 심사 : 2011.07.14
  • 발행 : 2011.09.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

The degradation of 30 pharmaceuticals and personal care products (PPCPs) subjected to $O_3$, $O_3$/UV, and $O_3/H_2O_2$ treatments were investigated using semi-batch tests and evaluated by their pseudo-first-order rate constants. The additional application of UV or $H_2O_2$ during $O_3$ treatment significantly improved the degradation rate of most of the PPCPs. At the same $O_3$ feed rate, $O_3$/UV treatment exhibited much higher PPCP degradation efficiency than that of $O_3$ treatment. This was probably due to degradation of the PPCPs by $O_3$, direct UV photodegradation, and OH radicals that formed from the photodegradation of $O_3$ during $O_3$/UV treatment. PPCP degradation by $O_3$ was also promoted by adding $H_2O_2$ during the $O_3$ treatment. However, when the initial $H_2O_2$ concentration was high during $O_3$ treatment, OH radicals were likely to be scavenged by excess $H_2O_2$, leading to low PPCP degradation. Therefore, it is important to determine the appropriate $H_2O_2$ dosage during $O_3$ treatment to improve PPCP degradation when adding $H_2O_2$ during $O_3$ treatment.

키워드

참고문헌

  1. Staehelin J, Hoigne J. Decomposition of ozone in water in the presence of organic solutes acting as promoters and inhibitors of radical chain reactions. Environ. Sci. Technol. 1985;19:1206-1213. https://doi.org/10.1021/es00142a012
  2. Langlais B, Reckhow DA, Brink DR, American Water Works Association Research Foundation, Compagnie generale des eaux. Ozone in water treatment: application and engineering: cooperative research report. Chelsea: Lewis Publishers; 1991.
  3. Jorgensen SE, Halling-Sorensen B. Drugs in the environment. Chemosphere 2000;40:691-699. https://doi.org/10.1016/S0045-6535(99)00438-5
  4. Andreozzi R, Caprio V, Marotta R, Radovnikovic A. Ozonation and $H_2O_2/UV$ treatment of clofibric acid in water: a kinetic investigation. J. Hazard. Mater. 2003;103:233-246. https://doi.org/10.1016/j.jhazmat.2003.07.001
  5. Huber MM, Canonica S, Park GY, von Gunten U. Oxidation of pharmaceuticals during ozonation and advanced oxidation processes. Environ. Sci. Technol. 2003;37:1016-1024. https://doi.org/10.1021/es025896h
  6. Oh BS, Jang HY, Hwang TM, Kang JW. Role of ozone for reducing fouling due to pharmaceuticals in MF (microfiltration) process. J. Membr. Sci. 2007;289:178-186. https://doi.org/10.1016/j.memsci.2006.11.052
  7. Dantas RF, Canterino M, Marotta R, Sans C, Esplugas S, Andreozzi R. Bezafibrate removal by means of ozonation: primary intermediates, kinetics, and toxicity assessment. Water Res. 2007;41:2525-2532. https://doi.org/10.1016/j.watres.2007.03.011
  8. Nakada N, Komori K, Suzuki Y, Konishi C, Houwa I, Tanaka H. Occurrence of 70 pharmaceutical and personal care products in Tone River basin in Japan. Water Sci. Technol. 2007;56:133-140.
  9. Okuda T, Kobayashi Y, Nagao R, et al. Removal efficiency of 66 pharmaceuticals during wastewater treatment process in Japan. Water Sci. Technol. 2008;57:65-71. https://doi.org/10.2166/wst.2008.822
  10. Kim I, Tanaka H. Photodegradation characteristics of PPCPs in water with UV treatment. Environ. Int. 2009;35:793-802. https://doi.org/10.1016/j.envint.2009.01.003
  11. Hoigne J, Bader H. Rate constants of reactions of ozone with organic and inorganic compounds in water. I. Non-dissociating organic compounds. Water Res. 1983;17:173-183. https://doi.org/10.1016/0043-1354(83)90098-2
  12. Buffle MO. Mechanistic investigation of the initial phase of ozone decomposition in drinking water and wastewater: impact on the oxidation of emerging contaminants, disinfection and by-products formation [dissertation]. Zuerich: Eidgenoessische Technische Hochschule Zuerich; 2006.
  13. von Gunten U. Ozonation of drinking water. Part I. Oxidation kinetics and product formation. Water Res. 2003;37:1443-1467. https://doi.org/10.1016/S0043-1354(02)00457-8

피인용 문헌

  1. Studies on photodegradation process of psychotropic drugs: a review vol.24, pp.2, 2017, https://doi.org/10.1007/s11356-016-7727-5
  2. Fate of veterinary antibiotics in riverine soils: evaluation of applicability in riverbank filtration vol.57, pp.43, 2011, https://doi.org/10.1080/19443994.2015.1112979
  3. A simple and rapid algal assay kit to assess toxicity of heavy metal-contaminated water vol.269, pp.None, 2011, https://doi.org/10.1016/j.envpol.2020.116135