Worker's exposure assessment of cyclonite in explosive compounds and bomb manufacturing companies

폭약 및 폭탄 제조시 발생하는 시클로나이트의 작업자 노출수준 평가

  • 정지연 (용인대학교 환경과학대학) ;
  • 이지현 (용인대학교 환경과학대학) ;
  • 김은영 (용인대학교 환경과학대학) ;
  • 이승훈 (용인대학교 환경과학대학)
  • Received : 2010.12.14
  • Accepted : 2011.03.19
  • Published : 2011.03.31

Abstract

Cyclonite is a white powder and is very explosive. It can cause seizures (a problem of the nervous system) in human and animals when large amounts are inhaled or eaten. Research papers for workers exposure assesment of the cyclonite are very a few in the world. A field study was conducted at explosive compounds and bomb manufacturing companies to evaluate workers exposure to cyclonite. The airborne average concentration of cyclonite in explosive compounds manufacturing company was $4.10{\mu}g/m^3$(range: ND - $59.92{\mu}g/m^3$), and that of cyclonite in bomb manufacturing company was $31.49{\mu}g/m^3$(range: ND - $291.41{\mu}g/m^3$). Package process and assembly process in both companies were considered the high potential of exposure to cyclonite. Even though all airborne concentrations of cyclonite were lower than occupational exposure standard (MOEL: $500{\mu}g/m^3$), exposure to cyclonite can also occur through dermal contact during manufacture, handling, and clean-up of cyclonite. So control measures for protecting skin absorption of cyclonite were needed for preventing adverse health effect by cyclonite exposure.

Keywords

References

  1. 고용노동부. 화학물질 및 물리적인자의 노출기준(고시 제2010-44호); 2010.
  2. 기술시험연구회. 화약류 관리/제조. 원화; 2006.
  3. 환경부. 전국화학물질 유통량 조사(2002) 결과. 환경부; 2004
  4. American Conference of Governmental Industrial Hygienists (ACGIH). Documentation of Thresholds limit values for chemical substances and physical agents and biological exposure indeces, 7th edition. Cincinnati: ACGIH; 2001.
  5. ACGIH. TLVs and BEIs based on the documentation fo the threshold limit values for chemical substances and physical agents & biological exposure indices. Cincinnati: ACGIH; 2010.
  6. Army. Database assessment of pollution control in the military explosives and propellants production industry. Aberdeen Proving Ground, MD: US. Army Toxic and Hazardous Material Agency. Report no. AMX-TH-TE-85037; 1986.
  7. Budavari S, O'Neil MJ, Smith A, et. al. The merk index: an encyclopedia of chemical, drugs, and biologicals. Eleventh edition. NJ: Merk&Co., Inc; 1989.
  8. Bingham E, Cohrssen B, Powell CH. Patty's toxicology, 5th ed. New York: John Wileyand Sons Inc.;2001.p.614
  9. Hathaway JA, Buck CR. Absence of health hazards associated with RDX manufacture and use. J Occup Med 1977;19:269-272 https://doi.org/10.1097/00043764-197704000-00008
  10. Kaplan AS, Bergought CF, Peczenik A. Human intoxication from RDX. Arch Environ Health 1965;10:877-883 https://doi.org/10.1080/00039896.1965.10664112
  11. Ketel WB, Hughes JR. Toxic encephalopathy with seizures secondary to ingestion of an explosive material composition C- 4: A clinical and electroencephalographic study. Neurology 1972;22:871-876
  12. Knepshield JH, Stone WJ. Toxic effects following ingestion of C-4 plastic explosive. In: Drug abuse: Current concepts and research. Springfield, IL: Charles C. Thomas; 1972.
  13. Hollander AI, Colbach EM. Composition C-4 induced seizures: A report of five cases. Military Medicine 1969;134:1529-1530.
  14. US National Library Medicine(NLM). Hazardous substance data bank.[cited 2011 March 11]. Available from: URL:http//www.http://toxnet.nlm.nih.gov/cgibin/ sis/htmlgen?HSDB
  15. Merrill SL. Ingestion of an explosive material, composition C-4: A report of two cases. U.S. ARV Med Bull 1968;35(1):1.
  16. National Institute of Occupational Safety and Health (NIOSH). Pocket guide to chemical hazards and other databases [DHHS(NIOSH) Pub. No 2005 -149]. Cincinnati, Ohio; NIOSH: 2005.
  17. OSHA. OSHA sampling and analytical method PV2135, Cyclonite(RDX).[cited 2010 December 11]. Available from http://www.osha.gov/dts/sltc /methods /partial /pv2135/ pv2135.html.
  18. Paik NW, Walcott RJ, Brogan PA. Worker exposure to asbestos during removal of sprayed material and renovation activity in building containing sprayed material. Am Ind Hyg Assoc J 1983;44(6):428-432. https://doi.org/10.1080/15298668391405085
  19. Stone WJ, Paletta TL, Heiman EM et al.. Toxic effects following ingestion of C-4 plastic explosive. Arch Intern Med 1969;124:726-730. https://doi.org/10.1001/archinte.1969.00300220078015
  20. West RR, Stafford DA. Occupational exposures and haematological abnormalities among ordance factory workers: a case control study. Leukemia Research 1997;21(7):675-680. https://doi.org/10.1016/S0145-2126(97)00042-8
  21. Wikipedia. Nippoo/Chemistry.[cited 2010 December 9]. Available from http://en.wikipedia.org/wiki/user: nippoo /chemistry.
  22. Woody RC, Keams GL, Brewster MA et al. The neurotoxicity of cyclotrimethylene -trinitramine (RDX) in a child: A clinical and pharmacokinetic evaluation. Clin Toxic 1986;24:305-319. https://doi.org/10.3109/15563658608992595