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Mössbauer Spectroscopic Study on Colorative Mechanism of Celadon Glaze

청자 유약 발색메카니즘에 대한 뫼스바우어 분광법에 의한 연구

  • Kim, Jong-Young (Icheon Branch, Korea Institute of Ceramic Engineering and Technology) ;
  • No, Hyung-Goo (Icheon Branch, Korea Institute of Ceramic Engineering and Technology) ;
  • Jeon, A-Young (Icheon Branch, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Ung-Soo (Icheon Branch, Korea Institute of Ceramic Engineering and Technology) ;
  • Cho, Woo-Seok (Icheon Branch, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Kyung-Ja (Icheon Branch, Korea Institute of Ceramic Engineering and Technology) ;
  • Kim, Chin-Mo (Department of Physics, Kookmin University) ;
  • Kim, Chul-Sung (Department of Physics, Kookmin University)
  • 김종영 (한국세라믹기술원 이천분원) ;
  • 노형구 (한국세라믹기술원 이천분원) ;
  • 전아영 (한국세라믹기술원 이천분원) ;
  • 김응수 (한국세라믹기술원 이천분원) ;
  • 조우석 (한국세라믹기술원 이천분원) ;
  • 김경자 (한국세라믹기술원 이천분원) ;
  • 김진모 (국민대학교 물리학과) ;
  • 김철성 (국민대학교 물리학과)
  • Received : 2010.10.15
  • Accepted : 2010.11.17
  • Published : 2011.01.31

Abstract

Systematic study on relationship between celadon coloring and glaze component was conducted by chromaticity analysis and M$\ddot{o}$ssbauer spectroscopic analysis. The chromaticity ($L^*$, $a^*$, $b^*$ values) and M$\ddot{o}$ssbauer analysis results were correlated to the amount of $Fe_2O_3$, $TiO_2$, MnO, and $P_2O_5$, which are the essential factors influencing celadon coloring. According to chromaticity analysis, celadon glaze color belongs to GY group when the addition of $TiO_2$ was 1.4%, whereas the color belongs to BG group when the addition of $TiO_2$ was 0.1%. For the GY group, the colors change from GY to YR with the decrease of brightness as the addition of $TiO_2$, MnO, and $P_2O_5$ increases. According to M$\ddot{o}$ssbauer analysis results, as the amount of divalent iron ion increases, the $a^*$ and $b^*$ values decrease, on the other hand, $L^*$ value increases. The ratio of divalent iron ion produced in reductive sintering process is found to be 80~95% in this study, which induces the increase of $L^*$ values in celadon glaze.

Keywords

References

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  1. Reaction Iron Oxide and Magnesium Oxide in Ceramics Body with Glaze vol.24, pp.7, 2014, https://doi.org/10.3740/MRSK.2014.24.7.363