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Operating Strategy Optimization of Metal Hydride based Hydrogen Supply System

수소저장합금을 이용하는 수소공급시스템의 운전 방법 최적화

  • Received : 2011.04.24
  • Accepted : 2011.10.21
  • Published : 2011.10.30

Abstract

Characteristics of a commercial metal hydride (MH) hydrogen supply system have been investigated and an operating strategy was developed based on the experimental data. As a prior step, charging/discharging capacity, thermal properties such as heat capacity, heat of reaction of MH system were experimentally measured. And then P-C-T data for various operating conditions were collected and a correlation between P, C and T predicting the behavior of MH was derived. Based on the basic experimental data, an operating strategy of MH system was developed, in which the hot water temperature supplied into the water jacket of MH was controlled depending on the pressure of MH, thereby the pressure of MH could be maintained at a suitable range. By adjusting the temperature of hot water from $40^{\circ}C$ to $60^{\circ}C$, the maximum discharging capacity of hydrogen could be increased by 4.7%, and consequently more stable hydrogen supply and longer operation time of fuel cell system could be achieved.

Keywords

References

  1. B. Gim, and J. Kim, "An Analysis of the Economy of Scale for Domestic On-site Hydrogen Fueling Stations", Journal of Energy Engineering, Vol. 16, No. 4, 2007, pp. 170-180.
  2. T. Pregger, D. Graf, W. Krewitt, C. Sattler, M. Roeb, and S. Moller, "Prospects of solar thermal hydrogen production processes", International Journal of Hydrogen Energy, Vol. 34, 2009, pp. 4256-4267. https://doi.org/10.1016/j.ijhydene.2009.03.025
  3. L. Reguera, J. Roque, J. Hernandez, and E. Reguera, "High density hydrogen storage in nanocavities: Role of the electrostatic interaction", International Journal of Hydrogen Energy, Vol. 35, 2010, pp. 12864-12869. https://doi.org/10.1016/j.ijhydene.2010.09.007
  4. Schlapbach. L., and Zuttel A, "Hydrogenstorage materials for mobile applications", Nature, Vol. 414, 2002, pp. 353-358.
  5. J. Larminie, and A. Dicks, Fuel Cell System Explained. 2nd ed., Wiley.
  6. F.L. Darkrim, P. Malbrunot, and G. P. Tartaglia, "Review of hydrogen storage by adsorption in carbon nanotubes", International Journal of Hydrogen Energy, Vol. 27, 2002, pp. 193-202. https://doi.org/10.1016/S0360-3199(01)00103-3
  7. J.B. Taylor, J.E.A. Alderson, K.M. Kalyanam, A.B. Lyle, and L.A. Phillips, "Tehcnical and economic assessment of methods for the storage of large quatities of hydrogen", International Journal of Hydrogen Energy, Vol. 11, 1986, pp. 5-22. https://doi.org/10.1016/0360-3199(86)90104-7
  8. H. Tanaka, K. Tokoyoda, M. Matsumoto, Y. Suzuki, T. Kiyobayashi, and N. Kuriyama, "Hazard assessment of complex hydrides as hydrogen storage materials", Vol. 34, 2009, pp. 3210-3218. https://doi.org/10.1016/j.ijhydene.2009.01.064
  9. S.H. Ho, and M. M. Rahman, "Three- dimensional analysis for liquid hydrogen in a cryogenic storage tank with heat pipe-pump system", Vol. 48, 2008, pp. 31-41. https://doi.org/10.1016/j.cryogenics.2007.09.005
  10. B. Sakintuna, F. Lamari-Darkrim, and M. Hirscher, "Metal hydride materials for solid hydrogen storage: A review", Vol. 32, 2007, pp. 1121-1140. https://doi.org/10.1016/j.ijhydene.2006.11.022
  11. J. Yang, A. Sudik, C. Wolverton, and D.J. Siegel, "High capacity hydrogen storage materials: Attributes for automotive applications and techniques for materials discovery", Chemical Society Reviews, Vol. 39, No. 2, 2010, pp. 656-675. https://doi.org/10.1039/b802882f
  12. S. Mellouli, F. Askri, H. Dhaou, A. Jemni and S. Ben Nasrallah, "Numerical simulation of heat and mass transfer in metal hydride hydrogen storage tanks for fuel cell vehicles", International Journal of Hydrogen Energy, Vol. 35, No. 4, 2010, pp. 1693-1705. https://doi.org/10.1016/j.ijhydene.2009.12.052
  13. T. Forde and Q. Ulleberg, "Thermal integration of a metal hydride storage unit and a PEM fuel cell stack", International Journal of Hydrogen Energy, 34, 2009, pp. 6730-6739. https://doi.org/10.1016/j.ijhydene.2009.05.146
  14. Z. Jiang, R.A. Dougal, S. Liu, S.A. Gadre, A.D. Ebner, and J.A. Ritter, "Simulation of a thermally coupled metal-hydride hydrogen storage and fuel cell system", Journal of Power Sources, Vol. 142, 2005, pp. 92-102. https://doi.org/10.1016/j.jpowsour.2004.09.029
  15. G.L. Guizzi, M. Manno, and M. Defalco, "Hybrid fuel cell-based energy system with metal hydride hydrogen for small mobile applications", International Journal of Hydrogen Energy, Vol. 34, 2009, pp. 3112-3124. https://doi.org/10.1016/j.ijhydene.2009.01.043
  16. http://www.hydrogencomponents.com.
  17. M. Visaria, I. Mudawar, and T. Pourpoint, "Enhanced heat exchanger design for hydrogen storage using high-pressure metal hydride - Part 2. Experimental results", International Journal of Heat and Mass Transfer, Vol. 54, 2011, pp. 424-432. https://doi.org/10.1016/j.ijheatmasstransfer.2010.09.028
  18. P. Muthukumar, and M. Groll, "Metal hydride based heating and cooling systems: A review", International Journal of Hydrogen Energy, 2010, pp. 8816-8829.
  19. T. Nishizaki, K. Miyamoto, and K. Yoshida, "Coefficient of performance of hydride heat pumps", Journal of the Less Common Metals, Vol. 89, 1983, pp. 559-566. https://doi.org/10.1016/0022-5088(83)90372-7