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Evaluations of lap shear and peel strength for epoxy and polyurethane adhesive bonded Triplex sheets at cryogenic temperatures

극저온에서 우레탄과 에폭시 접착제로 접착된 트리플엑스의 전단강도과 박리 강도 평가

  • Shon, Min-Young (Department of Industrial Chemistry, Pukyong National University)
  • Published : 2011.06.30

Abstract

Adhesive joints are widely used for structural joining applications in various fields and environmental conditions. Polyurethane (PU) and Epoxy adhesives are now being used for liquefied natural gas (LNG) carriers at cryogenic temperatures. This paper presents a comprehensive evaluation of epoxy and PU adhesive bonds between Triplex sheets at normal and cryogenic temperatures. The most significant result of this study is that for all adhesives tested, there is a significant decrease in peel strength at cryogenic temperatures. However, the reasons for the decrease in peel strength for epoxy and PU adhesives differ. Consequently, PU adhesives can be considered better suited for use in applications requiring high bonding performance at cryogenic conditions, such as in LNG carriers.

접착제에 의한 접합은 일반적으로 구조물의 접합에 널리 사용되고 있다. 폴리우레탄 접착제와 에폭시 접착제는 현재 극저온에서 운항되고 있는 LNG 선박의 화물창에 적용되고 있다. 본 연구에서는 화물창용 소재인 트리플엑스와 폴리우레탄 및 에폭시 접착제와의 상온과 극저온에서의 접착강도를 평가하였다. 연구결과 모든 접착시스템에서 극저온에서 박리강도의 감소가 있었으며 그 원인은 접착제마다 다르게 검토되었다. 결과적으로는 폴리우레탄 접착제와 트리플엑스가 극저온에서의 강도 값이 에폭시에 비해 우수하였으며 LNG 선과 같은 극저온 환경에 접합한 것으로 평가되었다.

Keywords

References

  1. J.F. Bonacci and M. Maalej, "Externally bonded FRP for service-life extension of RC infrastructure," J Infrastruct. Sys. ASCE 6, 2000, pp. 7-33.
  2. H.R. III Hamilton and C.W. Dolan, "Durability of FRP reinforcements for concrete," Prog. Struct. Eng. Mater. 2, 2000, pp. 45-139.
  3. V.M. Karbhari and F. Seible, "Fiber reinforced composites - advanced materials for the renewal of civil infrastructure," Appl. Compos. Mater. 7, 2000, pp. 95-124. https://doi.org/10.1023/A:1008915706226
  4. K.W. Neale, "FRPs for structural rehabilitation: a survey of recent progress," Prog. Struct. Eng. Mater. 2, 2000, pp. 8-133.
  5. M.A. Shaw and J.F. Drewett. "Case studies of carbon fibre bonding worldwide," In: L.C. Hollaway and M.B. Leeming (eds), Strengthening of Reinforced Concrete Structures Using Externally-Bonded FRP Composites in Structural and Civil engineering. Woodhead Publishing, Cambridge, UK, 1999.
  6. D.F. Atiken, "Engineer's Handbook of Adhesives," The Machinery Publishing Company, London, 1972.
  7. S.M. Kumar, N. Sharma and B.C. Ray, "Mechanical behavior of glass/epoxy composites at liquid nitrogen temperature," J Reinf. Plast. Compos. 27, 2008, pp. 937. https://doi.org/10.1177/0731684407085877
  8. K. Frisch and S.L. Reegen, "Advances in Polyurethane Science and Technology," Vols. 1-9. Echnomic, Westport 1984.
  9. Z. Wirpsza, "Polyurethanes-Chemistry, Technology and Applications," PTR Prentice Hall, London 1993.
  10. 손민영, 이재광, 홍정락, 한국복합재료학회지, 제22권 제4호, 2009, pp. 13-19.
  11. D .H. Kaelble, "Theory and analysis of peel adhesion: mechanisms and mechanics," Trans. Soc. Rheol. 3, 1959, pp. 161. https://doi.org/10.1122/1.548850
  12. D.H. Kaelble, "Theory and analysis of peel adhesion: bond stress and distributions," Trans. Soc. Rheol. 4, 1960, pp. 45. https://doi.org/10.1122/1.548868
  13. D.H. Kaelble, "Peel adhesion: micro-fracture mechanics of interfacial unbonding of polymers," Trans. Soc. Rheol. 9, 1965, pp. 135.
  14. D.H. Kaelble and C.L. Ho, "Biaxial bond stress analysis in peeling," Trans. Soc. Rheol. 18, 1974, pp. 219. https://doi.org/10.1122/1.549333
  15. J.J. Bikerman, "Theory of peeling through a Hookean solid," J. Appl. Phys. 28, 1957, pp. 1484. https://doi.org/10.1063/1.1722682
  16. J.L. Gardon, "Peel adhesion I: some phenomenological aspects of the test," J. Appl. Polym. Sci. 7, 1963, pp. 625. https://doi.org/10.1002/app.1963.070070219
  17. J.L. Gardon, "Peel adhesion II: a theoretical analysis," J. Appl. Polym. Sci. 7, 1963, pp. 643. https://doi.org/10.1002/app.1963.070070220
  18. G.J. Spies, "The peeling test on redux-bonded joints," Aircraft Eng, 30, 1953, pp. 2.
  19. J. Jouwersma, "On the theory of peeling," J. Appl. Polym. Sci. 45, 1960, pp. 253. https://doi.org/10.1002/pol.1960.1204514535
  20. A.J. Kinloch, C.C. Lau and J.G. Williams, "Small scale aluminium/epoxy peel test specimens and measurement of adhesive fracture energy," Int. J Fract. 66, 1994, pp. 45. https://doi.org/10.1007/BF00012635
  21. A.N. Gent and A.J. Kinloch, "Adhesion of viscoelastic materials to rigid substrates III: energy criterion for failure," J. Appl. Polym. Sci. 9, 1971, pp. 659.
  22. E.H. Andrews and A.J. Kinloch, "Mechanics of adhesive failure I," in: Proc. R. Soc. Lond. A 332, 1973, pp. 385. https://doi.org/10.1098/rspa.1973.0032
  23. E.H. Andrews and A.J. Kinloch, "Mechanics of adhesive failure II," in: Proc. R. Soc. Lond. A 332, 1973, pp. 401. https://doi.org/10.1098/rspa.1973.0033
  24. ISO 4578, Adhesives - Determination of peel resistance of high-strength adhesive bonds - Floating roller method.
  25. Stanley R. Sandler, Florence R. Berg, "Polyurethanes as cryogenic adhesives," Journal of Applied Polymer Science, Vol 9, 1965, pp. 3909-3916. https://doi.org/10.1002/app.1965.070091212
  26. Edward M. Petrie, "Handbook of adhesives and sealants," pp. 705.

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