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Preparation and Electrical Properties of TiO2 Films Prepared by Sputtering for a Pulse Power Capacitor

스퍼터링에 의한 펄스파워 캐패시터용 TiO2 박막의 제조 및 전기적특성

  • Park, Sang-Shik (School of Nano-Materials Engineering, Kyungpook National University)
  • 박상식 (경북대학교 나노소재공학부)
  • Received : 2012.07.06
  • Accepted : 2012.09.06
  • Published : 2012.11.30

Abstract

$TiO_2$ thin films for a pulse power capacitor were deposited by RF magnetron sputtering. The effects of the deposition gas ratio and thickness on the crystallization and electrical properties of the $TiO_2$ films were investigated. The crystal structure of $TiO_2$ films deposited on Si substrates at room temperature changed to the anatase from the rutile phase with an increase in the oxygen partial pressure. Also, the crystallinity of the $TiO_2$ films was enhanced with an increase in the thickness of the films. However, $TiO_2$ films deposited on a PET substrate showed an amorphous structure, unlike those deposited on a Si substrate. An X-ray photoelectron spectroscopy(XPS) analysis revealed the formation of chemically stable $TiO_2$ films. The dielectric constant of the $TiO_2$ films as a function of the frequency was significantly changed with the thickness of the films. The films showed a dielectric constant of 100~110 at 1 kHz. However, the dissipation factors of the films were relatively high. Films with a thickness of about 1000nm showed a breakdown strength that exceeded 1000 kV/cm.

Keywords

References

  1. R. Vazquez-Reina, S. Chao, V. Petrovsky, F. Dogan, and S. Greenbaum, "Electrical and Electron Paramagnetic Resonance Spectroscopy Characterization oF Mn-doped Nanostructured $Tio_2$ for Capacitor Applications," J. Power Sources, 210 21-5 (2012). https://doi.org/10.1016/j.jpowsour.2012.02.096
  2. K. R. Bray, R. L. C. Wu, S. Fries-Carr, and J. Weimer, "Aluminum Oxynitride Dielectrics for Multilayer Capacitors with Higher Energy Density and Wide Temperature Properties," Thin Solid Films, 518 366-71 (2009). https://doi.org/10.1016/j.tsf.2009.06.052
  3. A. Nishino, "Capacitors: Operating Principles, Current Market and Technical Trends," J. Power Sources, 60 137-47 (1996). https://doi.org/10.1016/S0378-7753(96)80003-6
  4. L. Lopez, W. A. Daoud, and D. Dutta, "Preparation of Large Scale Photocatalytic $TiO_2$ Films by the Sol-gel Process," Surf. Coat. Technol., 205 251-57 (2010). https://doi.org/10.1016/j.surfcoat.2010.06.028
  5. Z. Chen, Y. Tang, H. Yang, Y. Xia, F. Li, T. Yi, and C. Huang, "Nanocrystalline $TiO_2$ Film with Textural Channels: Exhibiting Enhanced Performance in Quasi-solid/solid-state Dye-sensitized Solar Cells," J. Power Sources, 171 990-98 (2007). https://doi.org/10.1016/j.jpowsour.2007.07.007
  6. Y. Leprince-Wang, D. Souche, K. Yu-Zhang, S. Fisson, G. Vuye, and J. Rivory, "Relations Between the Optical Properties and the Microstructure of $TiO_2$ Thin Films Prepared by Ionassisted Deposition," Thin Solid Films, 359 171-76 (2000). https://doi.org/10.1016/S0040-6090(99)00759-2
  7. M. Hiratani, M. Kadoshima, T. Hirano, Y. Shimamoto, Y. Matsui, T. Nabatame, K. Torii, and S. Kimura, "Ultra-thin titanium Oxide Film with a Rutile-type Structure," Appl. Surf. Sci., 207 13-19 (2003). https://doi.org/10.1016/S0169-4332(02)01228-X
  8. S. Chao and F. Dogan, "Processing and Dielectric Properties of $TiO_2$ Thick Films for High-Energy Density Capacitor Applications," Int. J. Appl. Ceram. Technol., 8 [6] 1363-67 (2011). https://doi.org/10.1111/j.1744-7402.2010.02592.x
  9. M. Takeuchi, T. Itoh, and H. Nagasaka, "Dielectric Properties of Sputtered $TiO_2$ Films," Thin Solid Films, 51 83-88 (1978). https://doi.org/10.1016/0040-6090(78)90215-8
  10. R. F. Bunshah, "Handbook of Deposition Technologies for Films and Coatings," pp.270, 2nd ed., Noyes Publication, USA, 1994.
  11. Y. Zhao, Y. Qian, W. Yu, and Z. Chen, "Surface Roughness of Alumina Films Deposited by Reactive R.f. Sputtering," Thin Solid Films, 286 45-48 (1996). https://doi.org/10.1016/S0040-6090(95)08514-9
  12. D. G. Syarif, A. Miyashita, T. Yamaki, T. Sumita, T. Choi, and H. Itoh, "Preparation of Anatase and Rutile Thin Films by Controlling Oxygen Partial Pressure," Appl. Surf. Sci., 193 287-92 (2002). https://doi.org/10.1016/S0169-4332(02)00532-9
  13. J. Sicha, J. Musil, M. Meissner, and R. Cerstvy, "Nanostructure of Photocatalytic $TiO_2$ Films Sputtered at Temperature Below 200," Appl. Surf. Sci., 254 3793-800 (2008). https://doi.org/10.1016/j.apsusc.2007.12.003
  14. M. Horprathum, P. Eiamchai, P. Chindaudom, A. Pokaipisit, and P. Limsuwan, "Oxygen Partial Pressure Dependence of the Properties of $TiO_2$ Thin Films Deposited by DC Reactive Magnetron Sputtering," Procedia Eng., 32 676-82 (2012). https://doi.org/10.1016/j.proeng.2012.01.1326
  15. K. Chan, T. Tou and B. Teo, "Thickness Dependence of the Structural and Electrical Properties of Copper Films Deposited by DC Magnetron Sputtering Technique," Microelectron. J., 37 608-12 (2006). https://doi.org/10.1016/j.mejo.2005.09.016
  16. K. Navaneetha Pandiyaraj, V. Selvarajan, M. Pavese, P. Falaras, and D. Tsoukleris, "Investigation on Surface Properties of $TiO_2$ Films Modified by DC Glow Discharge Plasma," Curr. Appl. Phys., 9 1032-37 (2009). https://doi.org/10.1016/j.cap.2008.11.005
  17. K. O. Awitor, A. Rivaton, J. L. Gardette, A. J. Down, and M. B. Johnson, "Photo-protection and Photo-catalytic Activity of Crystalline Anatase Titanium Dioxide Sputter-coated on Polymer Films," Thin Solid Films, 516 2286-91 (2008). https://doi.org/10.1016/j.tsf.2007.08.005
  18. J. Guillot, F. Fabreguette, L. Imhoff, O. Heintz, M. C. Marco de Lucas, M. Sacilotti, B. Domenichini, and S. Bourgeois, "Amorphous $TiO_2$ in LP-OMCVD $TiN_xO_y$ Thin Films Revealed by XPS," Appl. Surf. Sci., 177 268-72 (2001). https://doi.org/10.1016/S0169-4332(01)00220-3
  19. J. Jun, J. H. Shin, and M. Dhayal, "Surface State of $TiO_2$ Treated with Low Ion Energy Plasma," Appl. Surf. Sci., 252 3871-77 (2006). https://doi.org/10.1016/j.apsusc.2005.06.004
  20. P. Madhu Kumar, S. Badrinarayanan, and M. Sasty, "Nanoc-Rystalline $TiO_2$ Studied by Optical, FTIR and X-ray Photoelectron Spectroscopy: Correlation to Presence of Surface States," Thin Solid Films, 358 122-30 (2000). https://doi.org/10.1016/S0040-6090(99)00722-1
  21. S. Chao and F. Dogan, "Processing and Dielectric Properties of $TiO_2$ Thick Films for High-energy Density Capacitor Applications," Int. J. Ceram. Technol., 8 [6] 1363-73 (2011). https://doi.org/10.1111/j.1744-7402.2010.02592.x
  22. V. M. Ferreira, J. L. Baptista, S. Kamba, and J. Petzelt, "Dielectric Spectroscopy of $MgTiO_3$-based Ceramics in the $10^9-10^{14}Hz$ Region," J. Mater. Sci., 28 5894-900 (1993). https://doi.org/10.1007/BF00365198
  23. C. L. Huang and Y. B Chen, "Structure and Electrical Characteristics of RF Magnetron Sputtered $MgTiO_3$," Surf. Coat. Technol., 200 3319-25 (2006). https://doi.org/10.1016/j.surfcoat.2005.07.045

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