한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제49권6호
  • /
  • Pages.648-653
  • /
  • 2012
  • /
  • 1229-7801(pISSN)
  • /
  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
권호 표지
DOI QR코드

DOI QR Code

고에너지 밀링을 통한 Ni-BaCe0.9Y0.1O3-δ 서멧 멤브레인의 미세구조 균질성 향상

Improved Microstructural Homogeneity of Ni-BCY Cermets Membrane via High-Energy Milling

  • 김혜진 (한국과학기술연구원 고온에너지재료연구센터) ;
  • 안기용 (한국과학기술연구원 고온에너지재료연구센터) ;
  • 김보영 (한국과학기술연구원 고온에너지재료연구센터) ;
  • 이종흔 (고려대학교 신소재공학과) ;
  • 정용재 (한양대학교 신소재공학과) ;
  • 김혜령 (한국과학기술연구원 고온에너지재료연구센터) ;
  • 이종호 (한국과학기술연구원 고온에너지재료연구센터)
  • Kim, Hyejin (High-Temperature Energy Materials Research Center, Korea Institute of Science and Technology) ;
  • Ahn, Kiyong (High-Temperature Energy Materials Research Center, Korea Institute of Science and Technology) ;
  • Kim, Boyoung (High-Temperature Energy Materials Research Center, Korea Institute of Science and Technology) ;
  • Lee, Jongheun (Department of Materials Science and Engineering, Korea University) ;
  • Chung, Yong-Chae (Department of Materials Science and Engineering, Hanyang University) ;
  • Kim, Hae-Ryoung (High-Temperature Energy Materials Research Center, Korea Institute of Science and Technology) ;
  • Lee, Jong-Ho (High-Temperature Energy Materials Research Center, Korea Institute of Science and Technology)
  • 투고 : 2012.08.31
  • 심사 : 2012.10.08
  • 발행 : 2012.11.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Hybridization of dense ceramic membranes for hydrogen separation with an electronically conductive metallic phase is normally utilized to enhance the hydrogen permeation flux and thereby to increase the production efficiency of hydrogen. In this study, we developed a nickel and proton conducting oxide ($BaCe_{0.9}Y_{0.1}O_{3-{\delta}}$: BCY) based cermet (ceramic-metal composites) membrane. Focused on the general criteria in that the hydrogen permeation properties of a cermet membrane depend on its microstructural features, such as the grain size and the homogeneity of the mix, we tried to optimize the microstructure of Ni-BCY cermets by controlling the fabrication condition. The Ni-BCY composite powder was synthesized via a solid-state reaction using $2NiCO_3{\cdot}3Ni(OH)_2{\cdot}4H_2O$, $BaCeO_3$, $CeO_2$ and $Y_2O_3$ as a starting material. To optimize the mixing scale and homogeneity of the composite powder, we employed a high-energy milling process. With this high-energy milled composite powder, we could fabricate a fine-grained dense membrane with an excellent level of mixing homogeneity. This controlled Ni-BCY cermet membrane showed higher hydrogen permeability compared to uncontrolled Ni-BCY cermets created with a conventionally ball-milled composite powder.

키워드

참고문헌

  1. International Atomic Energy Agency (IAEA), "Hydrogen as an Energy Carrier and its Production by Nuclear Power", Reported by IAEA-TECDOC-1085, (1999).
  2. US Department of Energy (US DOE) and US Department of Transpotation (US DOT), "Hydrogen Posture Plan", Reported by DOE and DOT (2006).
  3. D. Jack, D. Anderson, C. Evenson, and D. Waters, "Hydrogen Separation Membrane Application", Eltron Research & Development (2009).
  4. International Energy Agency (IEA), "Prospects for Hydrogen and Fuel Cells", Reported by the Secretariat of IEA (2005).
  5. J. W. Phair, and S. P. S. Badwal, "Review of Proton Conductors for Hydrogen Separation", Ionics, 12 [2] 103-15 (2006). https://doi.org/10.1007/s11581-006-0016-4
  6. S. J. Song, E. D. Wachsman, J. Rhodes, S. E. Dorris, and U. Balachandran, "Hydrogen Permeability of $SrCe_{1x}M_xO_{3-{\delta}}$ (x = 0.05, M = Eu, Sm)," Solid State Ionics, 167 [1-2] 99-105 (2004). https://doi.org/10.1016/j.ssi.2003.12.010
  7. S. J. Song, E. D. Wachsman, J. Rhodes, H. S. Yoon, G. Zhang, K. H. Lee, S. E. Dorris, and U. Balachandran, "Hydrogen Permeability and Effect of Microstructure on Mixed Protonic-Electronic Conducting Eu-doped Strontium Cerate," J. Mater. Sci., 40 4061-66 (2005). https://doi.org/10.1007/s10853-005-2841-7
  8. J. Guan, S. E. Dorris, U. Balachandran, and M. Liu, "Transport Properties of $SrCe_{0.95}Y_{0.05}O_{3-{\delta}$ and its Application for Hydrogen Separation", Solid State Ionics, 110 [3-4] 303-10 (1998). https://doi.org/10.1016/S0167-2738(98)00148-9
  9. T. Hibino, K Mizutani, T. Yajima, and H. Iwahara "Evaluation of Proton Conductivity in $SrCeO_3$, $BaCeO_3$, $CaZrO_3$ and $SrZrO_3$ by Temperature Programmed Desorption Method", Solid State Ionics, 57 [3-4] 303-6 (1992). https://doi.org/10.1016/0167-2738(92)90162-I
  10. S. J. Song, T.H. Lee, E.D. Wachsman, L. Chen, S.E. Dorris, and U. Balachandran, "Defect Structure and Transport Properties of Ni-$SrCeO_{3-{\delta}}$ Cermet for Hydrogen Separation Membrane", J. Electrochem. Soc., 152 [11] J 125 (2005). https://doi.org/10.1149/1.2060690
  11. C. Zuo, T.H. Lee, S.-J. Song, L. Chen, S.E. Dorris, U. Balachandran, and M. Liu, "Hydrogen Permeation and Chemical Stability of Cermet [Ni-$Ba(Zr_{0.8-x}Ce_xY_{0.2})O_3$] Membranes", Electrochem. Solid State Lett., 8 [12] J 35 (2005). https://doi.org/10.1149/1.2081807
  12. S. J. Song, E. D. Wachsman, J. Rhodes, H. S. Yoon, K. H. Lee, G. Zhang, S.E. Dorris, U. BalachandranS. J. Song, E. D. Wachsman, S. E. Dorris, and U. Balachandran, "Defect Chemistry Modeling of High-Temperature Proton-Conducting Cerates," Solid State Ionics, 149 [1-2] 1-10 (2002). https://doi.org/10.1016/S0167-2738(02)00147-9
  13. S. J. Song, E. D. Wachsman, S. E. Dorris, and U. Balachandran, "Electrical Properties of p-type Electronic Defects in the Protonic Conductor $SrCe_{0.95}Eu_{0.05}O_{3-{\delta}$," J. Electrochem. Soc., 150 A790-A795 (2003). https://doi.org/10.1149/1.1574031
  14. H. Iwahara, "Hydrogen Pumps using Proton-conducting Ceramics and their Applications," Solid State Ionics, 125 271-78 (1999). https://doi.org/10.1016/S0167-2738(99)00185-X
  15. C. Suryanarayana, "Mechanical Alloying and Milling", Progress in Materials Science, 46 1-184 (2001) https://doi.org/10.1016/S0079-6425(99)00010-9
  16. T.A.G. Restivo, S.R.H. de Mello-Castanho, "Nickel-zirconia Cermet Processing by Mechanical Alloying for Solid Oxide Fuel Cell Anodes," J. Power Sources, 185 1262-66 (2008). https://doi.org/10.1016/j.jpowsour.2008.08.082