DOI QR코드

DOI QR Code

Influence of Blended Activators on the Physical Properties of Alkali-activated Slag Mortar

알칼리 활성화 슬래그 모르타르의 특성에 미치는 혼합 활성화제의 영향

  • Received : 2012.06.22
  • Accepted : 2012.08.13
  • Published : 2012.11.30

Abstract

This paper reported on the effect of blended activator on the physical properties of alkali-activated slag mortar. Five different activators(caustic alkalis) were used: sodium hydroxide(NaOH, A Case), calsium hydroxide($Ca(OH)_2$, B Case), magnesium hydroxide($Mg(OH)_2$, C Case), aluminum hydroxide($Al(OH)_3$, D Case), and potassium hydroxide(KOH, E Case). We blended five caustic alkalis with sodium carbonate($Na_2CO_3$). The dosage of five caustic alkalis was 3M and sodium carbonate was 1M, 2M and 3M. The result of flow and setting time was decrease as the dosage of sodium carbonate increase. But the compressive strength was increase as the dosage of sodium carbonate increase. It was shown that there is a good effect of blended caustic alkalis with sodium carbonate in alkali-activated slag mortar.

본 연구는 알칼리 활성화 슬래그에서 혼합 활성화제에 관한 것이다. 본 연구에서는 수산화나트륨(NaOH, A Case), 수산화칼슘($Ca(OH)_2$, B Case), 수산화마그네슘($Mg(OH)_2$, C Case), 수산화알루미늄($Al(OH)_3$, D Case), 그리고 수산화칼륨(KOH, E Case)의 5가지 수산화계열 활성화제를 사용했다. 이 5가지 수산화계열 활성화제와 탄산나트륨($Na_2CO_3$)를 혼합하였다. 5가지 수산화계열 활성화제의 농도는 3M로 하고, 탄산나트륨은 1M, 2M, 3M로 하였다. 플로우와 응결 특성은 탄산나트륨의 혼합에 따라 감소하는 결과가 나타났다. 그러나 압축응력은 탄산나트륨의 혼합 농도에 따라 증가하는 결과를 나타내었다. 이것은 수산화계열 활성화제와 탄산나트륨의 혼합은 알칼리 활성화 슬래그 모르타르의 특성에 효과적인 것으로 판단된다.

Keywords

References

  1. Byung-Wan Jo, Seung-Kook Park and Byung-Yoon Kwon, "Alkali-Activated Caol Ash(FLy Ash, Bottom Ash) Artificial Lightweight Aggregate and Its Application of Concrete", Journal of the Korea Concrete Institute, vol. 16, No. 6, 2004, pp.751-757. https://doi.org/10.4334/JKCI.2004.16.6.751
  2. Caijun Shi, A. Fernandez Jimenez, Angel Palomo, "New cements for the 21st century: The pursuit of an alternative to Portland cement", Cement and Concrete Research, vol. 41, 2011, pp.750-763. https://doi.org/10.1016/j.cemconres.2011.03.016
  3. Cengiz Duran Atis, Cahit Bilim, Ozlem Celik, Okan Karahan, "Influence of activator on the strength and drying shrinkage of alkali-activated slag mortar", Construction and Building Materials, vol. 23, 2009, pp.548-555. https://doi.org/10.1016/j.conbuildmat.2007.10.011
  4. F. Collins, J. G. Sanjayan, "Early age strength and workability of slag pastes activated by NaOH and $Na_{2}CO_{3}$", Cement and Concrete Research, vol. 28, 1998, pp.655-664. https://doi.org/10.1016/S0008-8846(98)00025-8
  5. F. Collins, J. G. Sanjayan, "Early age strength and workability of slag pastes activated by NaOH and $Na_{2}CO_{3}$", Cement and Concrete Research, vol. 28, 1998, pp.655-664. https://doi.org/10.1016/S0008-8846(98)00025-8
  6. Geon-Woo Kim, Byeong-Jo Kim, Keun-Hyeok Yang and Jin-Kyu Song, "Strength Development of Blended SOdium Alkali-Activated Ground Granulated Blast-Furnace Slag(GGBS) Mortar", Journal of the Korea Concrete Institute, vol. 24, No. 2, 2012, pp.137-145. https://doi.org/10.4334/JKCI.2012.24.2.137
  7. Han, Sang-Ho, Park, Sang-Sook, Kang, Hwa-Young, "Compressive Strength and Optimal Mixing Ratio of Alkali Activated Cement Concrete Containing Fly Ash", Journal of the Korea Institute for Structural Maintenance and Inspection, vol. 11, No. 4, 2007, pp.152-158.
  8. Keun-Hyeok Yang, Jin-Gyu Song, "The Properties and Applications of Alkali-Activated Concrete with No Cement", Magazine of the Korea Concrete Institute, vol. 19, No. 2, 2007, pp.42-28.
  9. Kim, Tae Wan, Hahm, Hyung Gil, "Mechanical Properties of Gypsum on the Alkali-Activated Slag Mortar", vol. 16, No. 3, 2012, pp.109-116.
  10. Lee, Chan-Taek, "A study on properties of non-cement mortar with alkali activators", Chonnam National University, 2010.
  11. Li Yongde, Sun Yao, "Preliminary study on combinedalkali- slag paste materials", Cement and Concrete Research, vol. 30, 2000, pp.963-966. https://doi.org/10.1016/S0008-8846(00)00269-6
  12. Moon, Han-Young, Shin, Dong-Gu, "Effect of Alkali Activators on Early Compressive Strength of Blast-Furnace Slag Mortar", Magazine of the Korea Institute for Structural Maintenance and Inspection, vol. 9, No. 3, 2005, pp.120-128.
  13. Palomo. A, Grutzeck, M. W., Blanco, M. T., "Alkali Activated Fly Ashes: A Cement for the Future", Cement and Concrete Research, vol. 29, 1999, pp.1323-1329. https://doi.org/10.1016/S0008-8846(98)00243-9
  14. Roy, D. M., "Alkali-activated Cements : Opportunities and Challenges", Cement and Concrete Research, vol. 29, 1999, pp.249-254. https://doi.org/10.1016/S0008-8846(98)00093-3
  15. Wang S., Pu, X. C., Scrivener, K. L, Pratt, P. L., "Alklai-Activated Slag Cement and Concrete; a Review of Properties and Problems", Advances in Cement Research, vol. 7, 1995, pp.93-102. https://doi.org/10.1680/adcr.1995.7.27.93

Cited by

  1. The Fundamental Study of Strength and Drying Shrinkage on Alkali-activated Slag Cement Mortar with Different Entering Point of Fine Aggregate vol.18, pp.2, 2014, https://doi.org/10.11112/jksmi.2014.18.2.117
  2. A Study on the Improvement of Early-age Compressive Strength of Smart BFS Powder Added Cement Mortar vol.17, pp.2, 2013, https://doi.org/10.11112/jksmi.2013.17.2.135
  3. The Fundamental Properties of Alkali-Activated Slag Cement (AASC) Mortar with Different Water-Binder Ratios and Fine Aggregate-Binder Ratios vol.17, pp.5, 2013, https://doi.org/10.11112/jksmi.2013.17.5.077