Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis, Structures, and Catalytic Properties of Ionic Metallacyclodimeric Palladium(II) Complexes

  • Kim, Sung Min (Department of Chemistry, Pusan National University) ;
  • Park, Kyung Hwan (Department of Chemistry, Pusan National University) ;
  • Lee, Haeri (Department of Chemistry, Pusan National University) ;
  • Moon, So Yun (Department of Chemistry, Pusan National University) ;
  • Jung, Ok-Sang (Department of Chemistry, Pusan National University)
  • Received : 2012.08.25
  • Accepted : 2012.09.19
  • Published : 2012.12.20
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Abstract

Metallacyclodimeric complexes of $[(Me_4en)Pd(L)]_2(ClO_4)_4$ ($Me_4en$ = N,N,N',N'-tetramethylethylenediamine; L = dimethylbis(4-pyridyl)silane (dmps), methylvinylbis(4-pyridyl)silane (mvps)) have been synthesized, and their structures have been characterized by X-ray single crystallography. The skeletal structures consist of one 20-membered metallamacrocycle, two 5-membered metallacycles, and four pyridyl groups. The local geometry around the palladium(II) ion approximates to a typical square planar arrangement with four nitrogen donors. Delicate difference in catalytic effects on hydrogenation was investigated based on the structure of catalyst and substrates.

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References

  1. Swiegers, G. F.; Malefetse, T. J. Coord. Chem. Rev. 2002, 225, 91. https://doi.org/10.1016/S0010-8545(01)00407-6
  2. Cotton, F. A.; Lin, C.; Murillo, C. A. Acc. Chem. Res. 2001, 34, 759. https://doi.org/10.1021/ar010062+
  3. Leinigner, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 853. https://doi.org/10.1021/cr9601324
  4. Jude, H.; Disteldorf, H.; Fischer, S.; Wedge, T.; Hawkridge, A. M.; Arif, A. M.; Hawthorne, M. F.; Muddiman, D. C.; Stang, P. J. J. Am. Chem. Soc. 2005, 127, 12131. https://doi.org/10.1021/ja053050i
  5. Wang, P.; Moorefield, C. N.; Newkome, G. R. Angew. Chem., Int. Ed. 2005, 44, 1679. https://doi.org/10.1002/anie.200462379
  6. Grote, Z.; Scopelliti, R.; Severin, K. J. Am. Chem. Soc. 2004, 126, 16959. https://doi.org/10.1021/ja044874n
  7. Benkstein, K. D.; Hupp, J. T.; Stern, C. L. J. Am. Chem. Soc. 1998, 120, 12982. https://doi.org/10.1021/ja982363t
  8. Jung, O.-S.; Lee, Y.-A.; Kim, Y. J.; Hong, J. Cryst. Growth Des. 2002, 2, 497. https://doi.org/10.1021/cg025555f
  9. Uehara, K.; Kasai, K.; Mizuno, N. Inorg. Chem. 2007, 46, 2563. https://doi.org/10.1021/ic062156r
  10. Zhang, Z.; Cai, R.; Chen, Z.; Zhou, X. Inorg. Chem. 2007, 46, 321. https://doi.org/10.1021/ic061722f
  11. Yao, Q.; Kinney, E. P.; Zheng, C. Org. Lett. 2004, 6, 2997. https://doi.org/10.1021/ol0486977
  12. Fujita, M.; Ibukuro, F.; Hagihara, H.; Ogura, K. Nature 1994, 367, 720. https://doi.org/10.1038/367720a0
  13. Chun, I. S.; Lee, K. S.; Do, J.; Hong, Y.; Jung, O.-S. Chem. Lett. 2007, 36, 548. https://doi.org/10.1246/cl.2007.548
  14. Chun, I. S.; Kwon, J. A.; Yoon, H. J.; Bae, M. N.; Hong, J.; Jung, O.-S. Angew. Chem., Int. Ed. 2007, 46, 4960. https://doi.org/10.1002/anie.200701152
  15. Seidel, S. R.; Stang, P. J. Acc. Chem. Res. 2002, 35, 972. https://doi.org/10.1021/ar010142d
  16. Jung, O.-S.; Kim, Y. J.; Kim, K. M.; Lee, Y.-A. J. Am. Chem. Soc. 2002, 124, 7906. https://doi.org/10.1021/ja026774s
  17. Jung, O.-S.; Lee, Y.-A.; Kim, Y. J. Chem. Lett. 2002, 31, 1906.
  18. Jung, O.-S.; Kim, Y. J.; Lee, Y.-A.; Kang, S. W.; Choi, S. N. Cryst. Growth Des. 2004, 4, 23. https://doi.org/10.1021/cg0341048
  19. Lee, J. W.; Kim, E. A.; Kim, Y. J.; Lee, Y.-A.; Pak, Y.; Jung, O.-S. Inorg. Chem. 2005, 44, 3151. https://doi.org/10.1021/ic048537r
  20. Schmitz, M.; Leninger, S.; Fan, J.; Arif, A. M.; Stang, P. J. Organometallics 1999, 18, 4817. https://doi.org/10.1021/om990567s
  21. Phan, N. T. S.; Van der Sluys, M.; Jones, C. W. Adv. Synth. Catal. 2006, 348, 609. https://doi.org/10.1002/adsc.200505473
  22. Wang, H.; Zhong, R.; Guo, X.-Q.; Feng, X.-Y.; Hou, X.-F. Eur. J. Inorg. Chem. 2010, 174.
  23. Weng, Z.; Teo, S.; Koh, L. L.; Hor, T. S. A. Organometallics 2004, 23, 3603. https://doi.org/10.1021/om049911y
  24. Jain, V. K.; Jain, L. Coord. Chem. Rev. 2005, 249, 3075. https://doi.org/10.1016/j.ccr.2005.06.020
  25. Sheldrick, G. M.; SHELXS-97: A Program for Structure Determination, University of Gottingen, Germany (1997); G. M. Sheldrick, SHELXL-97: A Program for Structure Refinement, University of Gottingen, Germany (1997).
  26. Ryu, Y. K.; Kim, C. W.; Noh, T. H.; Yoo, K. H.; Jung, O.-S. J. Coord. Chem. 2010, 63, 3888. https://doi.org/10.1080/00958972.2010.523825
  27. Evrard, D.; Groison, K.; Mugnier, Y.; Harvey, P. D. Inorg. Chem. 2004, 43, 790. https://doi.org/10.1021/ic0347992
  28. Islam, S. M.; Mondal, P.; Tuhina, K.; Roy, A. S. J. Chem. Technol. Biotechnol. 2010, 85, 999. https://doi.org/10.1002/jctb.2401

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