Environmental Engineering Research

  • 제17권4호
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  • Pages.185-190
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  • 2012
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  • 1226-1025(pISSN)
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  • 2005-968X(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
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Removal of Perchlorate Using Reverse Osmosis and Nanofiltration Membranes

  • Han, Jonghun (Department of Chemistry and Environmental Sciences, Korea Army Academy at Youngcheon) ;
  • Kong, Choongsik (Beautiful Environment Construction Co., Ltd.) ;
  • Heo, Jiyong (Department of Civil and Environmental Engineering, University of South Carolina) ;
  • Yoon, Yeomin (Department of Civil and Environmental Engineering, University of South Carolina) ;
  • Lee, Heebum (Department of Chemistry and Environmental Sciences, Korea Army Academy at Youngcheon) ;
  • Her, Namguk (Department of Chemistry and Environmental Sciences, Korea Army Academy at Youngcheon)
  • 투고 : 2012.06.28
  • 심사 : 2012.11.06
  • 발행 : 2012.09.30
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초록

Rejection characteristics of perchlorate ($ClO_4^-$) were examined for commercially available reverse osmosis (RO) and nanofiltration (NF) membranes. A bench-scale dead-end stirred-cell filtration system was employed to determine the toxic ion rejection and the membrane flux. Model water solutions were used to prepare $ClO_4^-$ solutions (approximately, $1,000{\mu}g/L$) in the presence of background salts (NaCl, $Na_2SO_4$, and $CaCl_2$) at various pH values (3.5, 7, and 9.5) and solution ionic strengths (0.001, 0.01, and 0.01 M NaCl) in the presence of natural organic matter (NOM). Rejection by the membranes increased with increasing solution pH owing to increasingly negative membrane charge. In addition, the rejection of the target ion by the membranes increased with increasing solution ionic strength. The rejection of $ClO_4^-$ was consistently higher for the RO membrane than for the NF membrane and $ClO_4^-$ rejection followed the order $CaCl_2$ < NaCl < $Na_2SO_4$ at conditions of constant pH and ionic strength for both the RO and NF membranes. The possible influence of NOM on $ClO_4^-$ rejection by the membranes was also explored.

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참고문헌

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