Structural and electrical characteristics of IZO thin films deposited under hydrogen atmosphere on flexible substrate

수소 분위기에서 유연 기판 위에 증착된 IZO 박막의 구조적 및 전기적 특성

  • Jo, D.B. (Dept. of Materials Engineering, Korea University of Technology and Education) ;
  • Lee, K.M. (Dept. of Materials Engineering, Korea University of Technology and Education)
  • 조담비 (한국기술교육대학교 신소재공학과) ;
  • 이규만 (한국기술교육대학교 신소재공학과)
  • Received : 2012.02.14
  • Accepted : 2012.03.15
  • Published : 2012.03.31

Abstract

In this study, we have investigated the structural and electrical characteristics of IZO thin films deposited under hydrogen atmosphere on flexible substrate for the OLED (organic light emitting diodes) devices. For this purpose, PES was used for flexible substrate and IZO thin films were deposited by RF magnetron sputtering under hydrogen ambient gases (Ar, $Ar+H^2$) at room temperature. In order to investigate the influences of the hydrogen, the flow rate of hydrogen in argon mixing gas has been changed from 0.1sccm to 0.5sccm. All the samples show amorphous structure regardless of flow rate. The electrical resistivity of IZO films increased with increasing flow rate of $H^2$ under $Ar+H^2$. All the films showed the average transmittance over 85% in the visible range. The OLED device was fabricated with different IZO electrodes made by configuration of IZO/$\acute{a}$-NPD/DPVB/$Alq_3$/LiF/Al to elucidate the performance of IZO substrate. OLED devices with the amorphous-IZO (a-IZO) anode film show good current density-voltage-luminance characteristics. This suggests that flat surface roughness and low electrical resistivity of a-IZO anode film lead to more efficient anode material in OLED devices.

Keywords

References

  1. K. Ishibashi, K. Hirata, and N. Hosokawa, "Mass spectrometric ion analysis in the sputtering of oxide targets," J.Vac. Sci. Technol. A, 10, pp.1718-1722, 1992. https://doi.org/10.1116/1.577776
  2. K. Tominaga, T. Ueda, T. Ao, M. Kataoka, and I. Mori, "ITO films prepared by facing target sputtering system," Thin Solid Films, 281-282, pp. 194-197, 1996. https://doi.org/10.1016/0040-6090(96)08611-7
  3. Y. Hoshi, H. Kato, and K. Funatsu, "ITO films deposited by facing target sputtering," J. mat. sci., 18, pp. 359-362, 2003.
  4. N. Taga, M. Maekawa, Y. Shigesato, I. Yasui, M. Kamei and T. E. Haynes, "Deposition of Heteroepitaxial $In_2O_3$ Thin Films by Molecular Beam Epitaxy", Jpn. J. Appl.Phys., 37, pp.6524-6529, 1998. https://doi.org/10.1143/JJAP.37.6524
  5. D. C. Paine, B. Yaglioglu, "Amorphous IZO-based transparent thin film transistors," Thin solid films, 516, pp.5894-5898, 2007.
  6. H.-K. Kim, D.-G. Kim, K.-S. Lee, M. S. Huh, S. H. Jeong, and K. I. Kim, "The Application of Anode Material (ITAZO) and Hole Transportation Material (NiO) in Organic Solar Cell," Photonics and Optoelectronics 2009, pp.1-4, 2005.
  7. 노경현, 최문구, 박승환, 주홍렬, 정창오, 정규하, 박장우, "비정질 투명전도막 $In_2O_3:Zn$ 의 전기적 광학적 특성," 한국광학회지, 13, pp.455-459, 2002.
  8. C. Nunes de Carvalho, A. M. Botelho do Rego, A. Amaral, P. Brogueira and G. Lavareda, "Effect of substrate temperature on the surface structure, composition and morphology of indium-tin oxide films," Surface and Coatings Technology, 124, pp. 70-75, 2000. https://doi.org/10.1016/S0257-8972(99)00619-2
  9. 박영란, 김용성, "In 도핑된 ZnO 박막의 투명 전극과 유기 발광 다이오드 특성," 한국세라믹학회지, 44, pp. 303-307, 2007.
  10. 조한나, 리유에롱, 민수련, 정지원, "Indium Zinc Oxide 박막 특성에 대한 $O_2$ 농도와 열처리 온도의 영향," 한국공업화학학회지, 17, pp. 644-647, 2006.
  11. K. Zhang, F. Zhu, C. H. A. Huan, A. T. S. Wee, "Effect of hydrogen partial pressure on optoelectronic properties of indium tin oxide thin films deposited by radio frequency magnetron sputtering method," J. Appl. Phys., 86, pp. 974-980, 1999. https://doi.org/10.1063/1.370834