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Effect of annealing temperature on amorphous indium zinc oxide thin films prepared by a sol-gel spin-coating method

  • Lee, Sang-Hyun (Department of Inorganic Materials Engineering, Kyungpook National University) ;
  • Lee, Seung-Yup (Department of Inorganic Materials Engineering, Kyungpook National University) ;
  • Park, Byung-Ok (Department of Inorganic Materials Engineering, Kyungpook National University)
  • Received : 2011.10.21
  • Accepted : 2011.12.02
  • Published : 2012.02.29

Abstract

Transparent conductive indium zinc oxide thin films were prepared by spin-coating a sol-gel solution. Zinc acetate dihydrate [$Zn(CH_3COO)_2{\cdot}2H_2O$] and indium acetate [In$(CH_3COO)_3$] were used as starting precursors, and 2-methoxyethanol with 1-propanol as solvents. Upon annealing in a temperature range from 500 to $1000^{\circ}C$, the thin film crystallizes into polycrystalline $In_2O_3$(ZnO). The lowest electrical resistivity was obtained at an annealing temperature of $700^{\circ}C$ as $2{\Omega}{\cdot}cm$. Average optical transmittances were higher than 80% at all annealing temperatures. These experimental results confirm that the sol-gel spin-coating can be a good simplified practical method for forming transparent electrodes.

Keywords

References

  1. T. Moriga, D.D. Edwards and T.O. Mason, "Phase relationships and physical properties of homologous compounds in the zinc oxide-indium oxide system", J. Am. Ceram. Soc. 81(5) (1998) 1310. https://doi.org/10.1111/j.1151-2916.1998.tb02483.x
  2. K.Y. Son, D.H. Park, J.H. Lee, J.J. Kim and J.S. Lee, "Phase development procedure of $In_{2}O_{3}(ZnO)_{3}$ ceramics and its sintering behavior", Solid State Ion. 172 (2004) 425. https://doi.org/10.1016/j.ssi.2004.03.028
  3. L. Dupont, C. Maugy, N. Naghavi, C. Guery and J.M. Tarascon, "Structures and textures of transparent conducting pulsed laser deposited $In_{2}O_{3}-ZnO$ thin films revealed by transmission electron microscopy", J. Solid State Chem. 158 (2001) 119. https://doi.org/10.1006/jssc.2000.9059
  4. T. Moriga, M. Mikawa, Y. Sakakibara, Y. Misaki, K.I. Murai, I. Nakabayashi, K. Tominaga and J.B. Metson, "Effects of introduction of argon on structural and transparent conducting properties of $ZnO-In_{2}O_{3}$ thin films prepared by pulsed laser deposition", Thin Solid Films 486 (2005) 53. https://doi.org/10.1016/j.tsf.2004.11.241
  5. N. Naghavi, C. Marcel, L. Dupont, A. Rougier, J.B. Leriche and C. Guery, "Structural and physical characterization of transparent conducting pulsed laser deposited $In_{2}O_{3}-ZnO$ thin films", J. Mater. Chem. 10 (2000) 2315. https://doi.org/10.1039/b002094j
  6. G. Goncalves, P. Barquinha, L. Raniero, R. Martins and E. Fortunato, "Crystallization of amorphous indium zinc oxide thin films produced by radio-frequency magnetron sputtering", Thin Solid Films 516 (2008) 1374. https://doi.org/10.1016/j.tsf.2007.03.087
  7. Y.R. Park, E.K. Kim, D.G. Jung, T.S. Park and Y.S. Kim, "Growth of transparent conducting nano-structured In doped ZnO thin films by pulsed DC magnetron sputtering", Applied Surface Science 254 (2008) 2250. https://doi.org/10.1016/j.apsusc.2007.09.008
  8. K.J. Chen, F.Y. Hung, S.J. Chang and Z.S. Hu, "Microstructures, optical and electrical properties of In-doped ZnO thin films prepared by sol-gel method", Applied Surface Science 255 (2009) 6308. https://doi.org/10.1016/j.apsusc.2009.02.007
  9. S.Y. Lee and B.O. Park, "Electrical and optical properties of $In_{2}O_{3}-ZnO$ thin films prepared by sol-gel method", Thin Solid Films 484 (2005) 184. https://doi.org/10.1016/j.tsf.2005.03.007
  10. J.H. Lee, S.Y. Lee and B.O. Park, "Fabrication and characteristics of transparent conducting $In_{2}O_{3}-ZnO$ thin films by ultrasonic spray pyrolysis", Mater. Sci. Eng. B 127 (2006) 267. https://doi.org/10.1016/j.mseb.2005.10.008
  11. Z.Q. Xu, H. Deng, Y. Li, Q.H. Guo and Y.R. Li, "Characteristics of Al-doped c-axis orientation ZnO thin films prepared by the sol-gel method", Mater. Res. Bull. 41 (2006) 354. https://doi.org/10.1016/j.materresbull.2005.08.014
  12. G.S. Wang, D. Remiens and C. Soyer, "Combined annealing temperature and thickness effects on properties of $PbZr_{0.53}Ti_{0.47}O_{3}$ films on $LaNiO_{3}/Si$ substrate by sol-gel process", J. Cryst. Growth 293 (2006) 370. https://doi.org/10.1016/j.jcrysgro.2006.06.014
  13. G. Machado, D.N. Guerra, D. Leinen, J.R. Ramos-Barrado, R.E. Marotti and E.A. Dalchiele, "Indium doped zinc oxide thin films obtained by electrodeposition", Thin Solid Films 490 (2005) 124. https://doi.org/10.1016/j.tsf.2005.04.042
  14. N. Naghavi, L. Dupont, C. Marcel, C. Maugy, B. Laik, A. Rougier, C. Guery and J.M. Tarascon, "Systemic study and performance optimization of transparent conducting indium-zinc oxide thin films", Electrochim. Acta 46 (2001) 2007. https://doi.org/10.1016/S0013-4686(01)00417-0
  15. R. Ghosh, G.K. Paul and D. Basak, "Effect of thermal annealing treatment on structural, electrical and optical properties of transparent sol-gel ZnO thin films", Mater. Res. Bul. 40 (2005) 1905 https://doi.org/10.1016/j.materresbull.2005.06.010
  16. P.K. Ghosh, S. Jana, S. Nandy and K.K. Chattopadhyay, "Size-dependent optical and dielectric properties of nanocrystalline ZnS thin films synthesized via rf-magnetron sputtering technique", Mater. Res. Bul. 42 (2006) 505. https://doi.org/10.1016/j.materresbull.2006.06.019