DOI QR코드

DOI QR Code

Preparation and Characterization of Lightweight Fillers and Inorganic Flame Retardants are Added Polyurethane Composite Foam

경량 충진제 및 무기계 난연제 첨가 polyurethane 복합발포체 제조 및 특성

  • 강동락 (호서대학교 안전공학과)
  • Received : 2012.01.11
  • Accepted : 2012.03.08
  • Published : 2012.03.31

Abstract

In this study, pure Polyurethane and commonly used flame retardants $Al(OH)_3$ and $Mg(OH)_2$, the add-in sample and Cloisite Na+, Cloisite 15A added sample of flammability and mechanical properties are compared. Sodium silicate and a mixture of polyurethane that the lightweight filler Vermiculite, Perlite addition of flame retardant and mechanical properties of the sample was confirmed. As a result, the flame retardant additive in the Vermiculite and Perlite in a flame-retardant grade sample except sample were identified. Tensile strength is degrade accord to the filler amount. But, Sodium silicate in the case of the sample add-in, other than confirmed that the sample strength increases.

본 연구는 순수 Polyurethane과 일반적인 난연제인 $Al(OH)_3$$Mg(OH)_2$를 첨가한 sample과 Cloisite Na+, Cloisite 15A를 첨가한 sample의 난연성 및 기계적 특성을 비교하였다. 또한 Sodium silicate와 Polyurethane을 혼합한 것에 경량성 충진제인 Vermiculite, Perlite를 충진한 sample의 난연성 및 기계적 특성을 확인하였다. 그 결과, Cloisite Na+와 Cloisite 15A를 첨가한 sample과 Sodium silicate를 혼합한 sample에서 난연제를 첨가한 것과 같은 등급의 난연성을 확인하였다. 인장강도는 filler의 양이 증가함에 따라 저하 되었으나, sodium silicate를 첨가한 sample의 경우 다른 sample 보다 강도가 향상됨을 확인하였다.

Keywords

References

  1. P. Thomas, "Polyurethane technology & applications", Huntsman international, 2002.
  2. J. H. Saunders and K. C. Frisch, "Polyurethanes : Chemistry and Technology", Part I, Chemistry, 4th Ed, Wiley-Interscience, New York, 1979.
  3. M. Modesti, "Synergism between flame retardant and modified layered silicate on thermal stability and fire behaviour of polyurethane nanocomposite foams", Polymer Degradation and Stability, 93(12), 2008, pp.2166-2171 https://doi.org/10.1016/j.polymdegradstab.2008.08.005
  4. D. Klemper and K.C Frisch, "Handbook of polymeric Foams and Foam" New York, p.253 (1991)
  5. Louis O. Raether, "Flame retardant Markets, products, regulations, a historical perspective", Flame retardant 101 : Basic dynamics, Fire Retardant Chemical Association, pp, 4-9, 1996.
  6. M. Lewis, S. M. Altas and E. M. Pearce, "Flame-Retardant Polymer Materals", Plenum Press, New York(1975)
  7. K. Troev, A. Tsekova, R. Tsevi, "Chemical degradation of polyurethanes: Degradation of flexible polyester polyurethane foam by phosphonic acid dialkyl esters", Journal of Applied Polymer Science, Vol. 78, pp. 2565-2573, 2000. https://doi.org/10.1002/1097-4628(20001227)78:14<2565::AID-APP180>3.0.CO;2-H
  8. David Purser, "Toxicity of tire retaedamts in relation to life safety and environmental hazards", Fire retardant materials, pp. 69-74, CRC Press, 2001.
  9. Suprakas Sinharay et al, "Polymer/layered silicate nanocomposites : A review from preparation to processing", Progress in polymer science, 2003.