DOI QR코드

DOI QR Code

A Study on the Usability of Red Mud as Activator of Alkali-Activated Cementless Binder

알칼리활성화 무시멘트 결합재의 촉진제로서 레드머드 활용에 관한 연구

  • 강석표 (우석대학교 건축.인테리어디자인학과)
  • Received : 2012.08.30
  • Published : 2012.11.25

Abstract

The enormous quantity of 'red mud' discharged by industries producing alumina from bauxite represents an environmental and economical problem. As it is mainly composed of $Fe_2O_3$, $Al_2O_3$, $SiO_2$, CaO and $Na_2O$, it is thought that using red mud as a construction material is an effective way to consume such a large quantity of alkaline waste. Therefore, the purpose of this study is to investigate usability of red mud as an solid composite alkali activator into cementless binder mixture system instead of the liquid water glass or caustic soda. As a results, it were found that the alkali-activated cementless blended binder paste based blast furnace slag using red mud had almost integrated and very compacted structure, which was believed to be the physical reasons for its high strength similar to that of ordinary portland cement. But the cementless binders, added to the red mud as activator into only the blast furnace slag or fly ash, are no use as cementitious materials due to the unstable hydration strength. to improve this defect was introduced to the red mud mixes together with extra addition of activators such as portlandite and gypsum.

Keywords

Acknowledgement

Supported by : 우석대학교, 한국연구재단

References

  1. 문경주, 산업폐기물을 이용한 비소성 시멘트 및 콘크리트의 특성, 전북대학교 박사학위 논문, 2003. 9.
  2. 송진규 외, 고로슬래그와 나트륨계열 활성화제를 이용한 무시멘트 모르타르의 특성, 대한건축학회논문집 구조계, 제26권, 제6호, pp.61-68, 2010. 6
  3. 전창섭 외, 고로슬래그의 지오폴리머 축중합반응에 미치는 양생온도의 영향, 한국세라믹학회지, 제48권, 제6호, pp.610-616, 2011.
  4. Pan Zhihua et al., Properties and microstructure of the hardened alkali-activated red mud-slag cementitious material, Cement and Concrete Research 33, pp.1437-1441, 2003 https://doi.org/10.1016/S0008-8846(03)00093-0
  5. Pan Zhihua et al., Hydration products of alkali-activated slag-red mud-slag cementitious material, Cement and Concrete Research 32, pp.357-362, 2002 https://doi.org/10.1016/S0008-8846(01)00683-4
  6. 김해종, 레드머드의 화학적 특성과 적용에 관한 연구, 전남대학교 석사학위논문, pp.23-28, 2007. 8
  7. Ikeda, K., Utilization of red mud as a new type of cement, Proc. Beijing Inter. Symp. Chem. Cem. Concr., pp.595-607, 1985.
  8. 박성권, 레드머드와 플라이애시를 첨가한 흙 포장재의 일축 압축강도, 안동대학교 석사학위논문, 2008. 2
  9. 정동영 외, 산업폐기물 레드머드를 사용한 친환경 칼라콘크리트 개발에 관한 실험적 연구, 한국환경과학회지, 제16권, 제8호, pp.929-939, 2007.
  10. 최은수 외, 콘크리트 표면처리용 시멘트 액체방수제의 품질관리에 관한 연구, 한국콘크리트학회 봄 학술발표대회 논문집, pp.181-188, 2000. 5