Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
권호 표지
DOI QR코드

DOI QR Code

Photoinitiator-free Photo-reactive Coloration of Wool Fabrics Using C.I. Reactive Black 5

  • Dong, Yuanyuan (Department of Nano-Bio Textile Engineering, Kumoh National Institute of Technology) ;
  • Jang, Jin-Ho (Department of Nano-Bio Textile Engineering, Kumoh National Institute of Technology)
  • Received : 2012.06.05
  • Accepted : 2012.06.19
  • Published : 2012.06.27
Download PDF
⟨ Previous Next ⟩

Abstract

Compared with conventional adsorption-based coloration, the photoreactions of dyes such as photo-copolymerization and photo-crosslinking under UV irradiation can be employed for the coloration of textiles, which can be carried out without salt addition at room temperature. C.I. Reactive Black 5, a homo-bifunctional reactive dye containing two sulfatoethylsulfone groups, is used as a photo-reactive dye for wool fibers. Upon UV irradiation, the photo-reactive dye was grafted onto wool fabrics without photoinitiators. Since the disulfide bonds in the cystine residues of wool can be easily photodecomposed to active thiyl radicals which initiate the polymerization, the dye can be polymerized to an oligomeric dye of a degree of polymerization of 12 or more. The grafted fabrics reached a grafting yield of 2.3% o.w.f. and a color yield (K/S) of 18.2 by the photografting of an aqueous dye concentration of 9% using a UV energy of 25J/$cm^2$. Furthermore, the photochemically dyed wool fabric showed higher colorfastness properties to light, laundering and rubbing comparable to conventional reactive dyeing.

Keywords

References

  1. R. M. Christie, R. R. Mather and R. H. Wardman, "The Chemistry of Colour Application", Blakwell, USA, pp.98-108, 2000.
  2. D. M. Lewis, "Wool Dyeing", Society of Dyers and Colourists, UK, pp.176-253, 1992.
  3. R. M. Christie, "Environmental Aspects of Textile Dyeing", The Textile Institute and Woodhead, England, pp.83-138, 2007.
  4. P. Suwanruji, H. S. Freeman and D. Zhao, Studies toward a Universal Dye for Textile Fibres, Color. Technol., 120, 220(2004). https://doi.org/10.1111/j.1478-4408.2004.tb00121.x
  5. D. M. Lewis, Coloration in the Next Century, Rev. Prog. Coloration, 29, 23(1999).
  6. C. W. Kan, K. Chan, C. W. M. Yuen and M. H. Miao, The Effect of Low-temperature Plasma on the Chrome Dyeing of Wool Fibre, J. Materials Processing Technol., 82, 122(1998). https://doi.org/10.1016/S0924-0136(98)00030-2
  7. C. W. Kan, K. Chan, C. W. M. Yuen and M. H. Miao, Surface Properties of Low-temperature Plasma Treated Wool Fabrics, J. Materials Processing Technol., 83, 180(1998). https://doi.org/10.1016/S0924-0136(98)00060-0
  8. D. Fakin, A. Ojstrsek and S. Benkovic, The Impact of Corona Modified Fibers' Chemical Changes on Wool Dyeing, J. Materials Processing Technol., 209, 584(2009). https://doi.org/10.1016/j.jmatprotec.2008.02.034
  9. M. N. Micheal and N. A. El-Zaher, Efficiency of Ultraviolet/Ozone Treatments in the Improvement of the Dyeability and Light Fastness of Wool, J. Appl. Polym. Sci., 90, 3668(2003). https://doi.org/10.1002/app.12941
  10. R. Atav and A. Yurdakul, Effect of the Ozonation Process on the Dyeability of Mohair Fibres, Color. Technol., 127, 159(2011). https://doi.org/10.1111/j.1478-4408.2011.00293.x
  11. A. Bhattacharya and B. N. Misra, Grafting: A Versatile Means to Modify Polymers Techniques, Factors and Applications, Prog. Polym. Sci., 29, 767(2004). https://doi.org/10.1016/j.progpolymsci.2004.05.002
  12. A. M. Naggar, M. M. Marie, E. H. Gendy and A. A. Miligy, Dyeing, Moisture Regain and Mechanical Properties of Wool Fabric Grafted with PMMA by Chemical and Radiation-grafted Methods, Radiat. Phys. Chem., 47, 623(1996). https://doi.org/10.1016/0969-806X(95)00106-8
  13. Y. Y. Dong, W. S. Lyoo and J. H. Jang, Union Dyeing of the Photografted PET/Wool Blend Fabrics with Dimethylaminopropyl Methacrylamide, Fiber Polym., 11, 213(2010). https://doi.org/10.1007/s12221-010-0213-7
  14. E. Partouche, D. Waysbort and S. Margel, Surface Modification of Crosslinked Poly(Styrene-divinyl benzene) Micrometer-sized Particles of Narrow Size Distribution by Ozonolysis, J. Colloid Interface Sci., 294, 69(2006). https://doi.org/10.1016/j.jcis.2005.07.007
  15. Z. Xu, Y. Huang, C. Zhang, L. Liu, Y. Zhang and L. Wang, Effect of $\gamma$-ray Irradiation Grafting on the Carbon Fibers and Interfacial Adhesion of Epoxy Composites, Composites Sci. Technol., 67, 3261(2007). https://doi.org/10.1016/j.compscitech.2007.03.038
  16. A. Vahdat, H. Bahrami, N. Ansari and F. Ziaie, Radiation Grafting of Styrene onto Polypropylene Fibres by a 10 MeV Electron Beam, Radiat. Phys. Chem., 76, 787(2007). https://doi.org/10.1016/j.radphyschem.2006.05.009
  17. M. Okubo, M. Tahara, N. Saeki and T. Yamamoto, Surface Modification of Fluorocarbon Polymer Film for Improved Adhesion using Atmospheric-pressure Nonthermal Plasma Graft-polymerization, Thin Solid Films, 516, 6592(2008). https://doi.org/10.1016/j.tsf.2007.11.033
  18. J. Lei, M. Shi and J. Zhang, Surface Graft Copolymerization of Hydrogen Silicone Fluid onto Fabric Through Corona Discharge and Water Repellency of Grafted Fabric, Eur. Polym. J., 36, 1277(2000). https://doi.org/10.1016/S0014-3057(99)00169-X
  19. F. C. Loh, K. L. Tan, E. T. Kang, K. G. Neoh and M. Y. Pun, Near-UV Radiation Induced Surface Graft Copolymerization of Some $O_3$-pretreated Conventional Polymer Films, Eur. Polym. J., 31, 481(1995). https://doi.org/10.1016/0014-3057(94)00203-7
  20. J. Jang and Y. Jeong, Flame-retardant Finish of Cotton Fabrics Using UV-curable Phosphorous-containing Monomers, Textile Coloration and Finishing(J. Korean Soc. Dyers & Finishers), 20, 8(2008).
  21. K. H. Hong, N. Liu and G. Sun, UV-induced Graft Polymerizaiton of Acrylamide on Cellulose by using Immobilized Benzophenone as Photo-initiator, Eur. Polym. J., 45, 1443(2009).
  22. A. M. Shanmugharaj, J. K. Kim and S. H. Ryu, Modificaiton of Rubber Surface by UV Surface Grafting, Appl. Surf. Sci., 252, 5714(2006). https://doi.org/10.1016/j.apsusc.2005.07.069
  23. S. Hu, X. Ren, M. Bachman, C. E. Sims, G. P. Li and N. Allbritton, Surface Modification of Poly (dimethylsiloxane) Microfluidic Devices by Ultraviolet Polymer Grafting, Anal. Chem., 74, 4117(2002). https://doi.org/10.1021/ac025700w
  24. Y. Y. Dong and J. Jang, Novel Coloration of Cotton Fabrics by UV-induced Photografting of Reactive Black 5 and Acrylic Acid, Textile Coloration and Finishing(J. Korean Soc. Dyers & Finishers), 23, 11(2011). https://doi.org/10.5764/TCF.2011.23.1.011
  25. J. Xue, L. Chen and H. Wang, Degradation Mechanism of Alizarin Red in Hybrid Gas-Liquid Phase Dielectric Barrier Discharge Plasmas: Experimental and Theoretical Examination, Chem. Eng. J., 138, 120(2008). https://doi.org/10.1016/j.cej.2007.05.055
  26. D. Meadows and J. Gervay-Hague, Vinyl Sulfones: Synthetic Preparations and Medicinal Chemistry Applications, Med. Res. Rev., 26, 793(2006). https://doi.org/10.1002/med.20074
  27. E. A. Bekturov, V. A. Frolova and G. K. Mamytbekov, Swelling of Poly(2-methyl-5-vinylpyridine) Gel in Linear Sodium Poly(vinylsulfonate) Solution, Macromol. Chem. Phys., 199, 1071(1998). https://doi.org/10.1002/(SICI)1521-3935(19980601)199:6<1071::AID-MACP1071>3.0.CO;2-4
  28. H. S. Choe, J. Giaccai, M. Alamgir and K. M. Abraham, Preparation and Characterization of Poly (vinyl sulfone) and Poly(vinylidene fluoride)-Based Electrolytes, Electrochim. Acta, 40, 2289(1995). https://doi.org/10.1016/0013-4686(95)00180-M
  29. J. Chen, H. Luo and W. Cao, Interaction of Diazoresins and Sulfonate Containing Polyelectrolytes, Polym. Int., 49, 382(2000). https://doi.org/10.1002/(SICI)1097-0126(200004)49:4<382::AID-PI385>3.0.CO;2-0
  30. N. Inagaki, S. Tasaka and Y. Goto, Surface Modification of Poly(tetrafluoroethylene) Film by Plasma Graft Polymerization of Sodium Vinylsulfonate, J. Appl. Polym. Sci., 66, 77(1997). https://doi.org/10.1002/(SICI)1097-4628(19971003)66:1<77::AID-APP9>3.0.CO;2-L
  31. D. M. Lewis, "Colour and Textile Chemistry", AATCC, pp.1-31, 2008.
  32. X. Bingshe, N. Mei, W. Liqiao, H. Wensheng and L. Xuguang, The Structural Analysis of Biomacro-molecule Wool Fiber with Ag-loading $SiO_2$ Nano-antibacterial Agent by UV Radiation, J. Photochem. Photobiol. A: Chem., 188, 98(2007). https://doi.org/10.1016/j.jphotochem.2006.11.025

Cited by

  1. UV-grafting coloration of cotton and wool fabrics using bismethacrylated quinizarin dye vol.17, pp.10, 2016, https://doi.org/10.1007/s12221-016-6481-0
  2. LED-UV grafting of vinylsulfone dyes onto photo-oxidized wool fabrics vol.18, pp.7, 2017, https://doi.org/10.1007/s12221-017-7287-4
  3. Environmentally friendly coloration of cotton by the UV-induced photografting of α-bromoacrylamido dyes vol.130, pp.4, 2014, https://doi.org/10.1111/cote.12094