Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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A Study on Synthesis of Polyurethane/Functionalized Graphene Nanocomposites by In-situ Intercalation Method

In-situ 법에 의한 폴리우레탄/기능화 된 그래핀 나노복합체의 합성에 관한 연구

  • Hwang, Soo-Ok (School of Energy.Materials.Chemical Engineering, Korea University of Technology and Education) ;
  • Lee, Byung-Hwan (School of Energy.Materials.Chemical Engineering, Korea University of Technology and Education) ;
  • Cho, Ur-Ryong (School of Energy.Materials.Chemical Engineering, Korea University of Technology and Education)
  • 황수옥 (한국기술교육대학교 에너지.신소재.화학공학부) ;
  • 이병환 (한국기술교육대학교 에너지.신소재.화학공학부) ;
  • 조을룡 (한국기술교육대학교 에너지.신소재.화학공학부)
  • Received : 2012.07.11
  • Accepted : 2012.07.23
  • Published : 2012.09.30
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Abstract

Graphene oxide was synthesized from natural graphite, and its surface was modified using diisocyanatodicyclohexylmethane( $H_{12}MDI$). Isocyanate-graphene sheet(i-RGO) was obtained by reduction of surface modified GO. To select nanofiller having good dispersion with polyurethane, GO, i-RGO, natural graphite and thermal reduced graphite were analyzed, and then i-RGO was selected as a suitable nanofiller. PU/i-RGO nanocomposite was synthesized with various i-RGO contents to estimate effect of reinforcement on nanocomposite. Thermal stability, hardness, contact angle were increased with i-RGO contents due to i-RGO characteristic and crosslink bridge effect. But, tensile strength and elongation were decreased at i-RGO contents more than the 4 wt%. This phenomenon was interpreted by the excess formation of crosslink bridge.

천연 흑연으로부터 Graphene oxide(GO)를 합성한 후 diisocyanatodicyclohexylmethane($H_{12}MDI$)를 이용하여 GO의 표면을 기능화하였고, hydrazine monohydrate에 의한 환원을 통해 isocyanate-graphene sheet(i-RGO)를 얻었다. 폴리우레탄과 적합한 나노복합체를 형성하기 위하여 GO, i-RGO, 천연흑연 및 열적환원된 graphene을 서로 비교분석하였으며, i-RGO가 가장 적합한 나노충전제로 선정되었다. 선정된 i-RGO의 함량에 따른 폴리우레탄의 물성 향상을 확인하기 위하여 충전제의 함량을 다르게 하여 PU/i-RGO 나노복합체를 합성하였다. 물성 평가에서, i-RGO의 함량이 증가할수록 열적 안정성, 경도 및 접촉각(발수력)이 향상되었는데, 이는 i-RGO의 물성 특성 및 가교점 작용에 기인한 것으로 판단되었다. 다만, 인장강도와 신장률의 경우 함량이 4 wt%를 넘어갈 경우 오히려 물성이 감소하는 것을 확인할 수 있었는데, 이는 과량의 가교점 형성이 원인인 것으로 해석되었다.

Keywords

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