Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Separation of Two Amino Acids by Microemulsion Bulk Liquid Membrane

  • Received : 2012.04.26
  • Accepted : 2012.07.20
  • Published : 2012.10.20
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Abstract

In this research work the potentialities of microemulsion bulk liquid membrane for the selective transport of L-tryptophan (L-Trp) and L-tyrosine (L-Tyr) are investigated at 298.15 K. Reversed micelle formed by sodium bis(2-ethylhexyl)sulfosuccinate (AOT) in dichloroethane, was used as mobile carrier to transport amino acids between a source and a receiving aqueous phase. The effects of pH, surfactant concentration and initial amino acid concentration on the extraction efficiency and transfer rate of the amino acids were studied. It is verified that for a mixture of two amino acids, L-Trp can be extracted selectively by using this type of the bulk liquid membrane with optimized condition.

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References

  1. Muthiac, L.; Mutihac, R. J. Inclusion Phenom. Macrocycl Chem. 2007, 59, 177. https://doi.org/10.1007/s10847-007-9310-7
  2. Tondre, C.; Hebrant, M. J. Mol. Liq. 1997, 72, 279. https://doi.org/10.1016/S0167-7322(97)00042-1
  3. Mohagheghi, E.; Alemzadeh, I.; Vossoughi, M. Sep. Sci. Technology 2008, 43, 3075. https://doi.org/10.1080/01496390802219612
  4. Bringas, E.; San Roman, M. F.; Irabien, J. A.; Ortiz, I. J. Chem. Technol. Biotechnol. 2009, 84, 1583. https://doi.org/10.1002/jctb.2231
  5. Oshima, T.; Inoue, K.; Furusaki, S.; Goto, M. J. Membr. Sci. 2003, 217, 87. https://doi.org/10.1016/S0376-7388(03)00078-4
  6. Bucci, R.; Canepari, S.; Cardarelli E.; Girelli, A. M.; Pietrodangelo, A.; Valiente, M. Sep. Sci. Technology 2004, 39, 3821. https://doi.org/10.1081/SS-200041143
  7. Araki, T.; Tsukube, H. Liquid Membranes: Chemical Applications; CRC Press: Boca Raton, FL, 1990.
  8. Hebrant, M.; Tondre, C. Anal. Sci. 1998, 14, 109. https://doi.org/10.2116/analsci.14.109
  9. Paul, B. K.; Moulik, S. P. Curr. Sci. 2001, 80, 990.
  10. Kaur, A.; Vohra, D. K. Indian J. Chem. Technol. 2010, 17, 133.
  11. Stobbe, H.; Yunguang, X.; Zihao, W.; Jufu, F. Biotechnol. Bioeng. 1997, 53, 267. https://doi.org/10.1002/(SICI)1097-0290(19970205)53:3<267::AID-BIT4>3.0.CO;2-G
  12. Verkuijl, B. J. V.; Minnaard, A. J.; de Vries, J. G.; Feringa, B. L. J. Org. Chem. 2009, 74, 6526. https://doi.org/10.1021/jo901002d
  13. Poliwoda, A.; Ilczuk, N.; Wieczorek, P. P. Sep. Purif. Technol. 2007, 57, 444. https://doi.org/10.1016/j.seppur.2006.05.015
  14. Joshi, P.; Joshi, N.; Sharma, U. Indian J. Biochem. Biophys. 2006, 43, 323.
  15. Leodidis, E. B.; Bommarius, A. S.; Hatton, T. A. J. Phys. Chem. 1991, 95, 5943. https://doi.org/10.1021/j100168a043
  16. Leodidis, E. B.; Hatton, T. A. J. Phys. Chem. 1990, 94, 6411. https://doi.org/10.1021/j100379a047
  17. Leodidis, E. B.; Hatton, T. A. J. Phys. Chem. 1990, 94, 6400. https://doi.org/10.1021/j100379a046
  18. Xun, F.; Junling, L.; Ying, M.; Li, Z.; Debao, W.; Zhengshui, H. Colloids Surf. A: Physicochem. Eng. Aspects 2001, 179, 1. https://doi.org/10.1016/S0927-7757(00)00719-6

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