DOI QR코드

DOI QR Code

Removal of Cd(II) and Cu(II) from Aqueous Solution by Agro Biomass: Equilibrium, Kinetic and Thermodynamic Studies

  • 투고 : 2012.02.06
  • 심사 : 2012.08.01
  • 발행 : 2012.09.30

초록

The removal of Cd(II) and Cu(II) from aqueous solution by an agricultural solid waste biomass prepared from Moringa oleifera bark (MOB) was investigated. The biosorbent was characterized by Fourier transform infrared spectroscopy and elemental analysis. Furthermore, the effect of initial pH, contact time, biosorbent dosage, initial metal ion concentration and temperature on the biosorption of Cd(II) and Cu(II) were studied using the batch sorption technique. Kinetic studies indicated that the biosorption process of the metal ions followed the pseudo-second order model. The biosorption data was analyzed by the Langmuir, Freundlich, Dubinin-Radushkevich, and Temkin isotherm models. Based on the Langmuir isotherm, the maximum biosorption capacities for Cd(II) and Cu(II) onto MOB were 39.41 and 36.59 mg/g at 323 K, respectively. The thermodynamic parameters, Gibbs free energy (${\Delta}G^o$), enthalpy (${\Delta}H^o$), and entropy (${\Delta}S^o$) changes, were also calculated, and the values indicated that the biosorption process was endothermic, spontaneous and feasible in the temperature range of 303-323 K. It was concluded that MOB powder can be used as an effective, low cost, and environmentally friendly biosorbent for the removal of Cd(II) and Cu(II) ions from aqueous solution.

키워드

참고문헌

  1. O'Connell DW, Birkinshaw C, O'Dwyer TF. Heavy metal adsorbents prepared from the modification of cellulose: a review. Bioresour. Technol. 2008;99:6709-6724. https://doi.org/10.1016/j.biortech.2008.01.036
  2. Khlifi R, Hamza-Chaffai A. Head and neck cancer due to heavy metal exposure via tobacco smoking and professional exposure: a review. Toxicol. Appl. Pharmacol. 2010;248:71-88. https://doi.org/10.1016/j.taap.2010.08.003
  3. Siboni MR, Samarghandi MR, Azizian S, Kim WG, Lee SM. The removal of hexavalent chromium from aqueous solutions using modified holly sawdust: equilibrium and kinetics studies. Environ. Eng. Res. 2011;16:55-60. https://doi.org/10.4491/eer.2011.16.2.55
  4. Lim J, Kang HM, Kim LH, Ko SO. Removal of heavy metals by sawdust adsorption: equilibrium and kinetic studies. Environ. Eng. Res. 2008;13:79-84. https://doi.org/10.4491/eer.2008.13.2.079
  5. Gorme JB, Maniquiz MC, Kim SS, Son YG, Kim YT, Kim LH. Characterization of bottom ash as an adsorbent of lead from aqueous solutions. Environ. Eng. Res. 2010;15:207-213. https://doi.org/10.4491/eer.2010.15.4.207
  6. Volesky B. Biosorption and me. Water Res. 2007;41:4017-4029. https://doi.org/10.1016/j.watres.2007.05.062
  7. Gadd GM. Biosorption: critical review of scientific rationale, environmental importance and significance for pollution treatment. J. Chem. Technol. Biotechnol. 2009;84:13-28. https://doi.org/10.1002/jctb.1999
  8. Bennett RN, Mellon FA, Foidl N, et al. Profiling glucosinolates and phenolics in vegetative and reproductive tissues of the multi-purpose trees Moringa oleifera L. (horseradish tree) and Moringa stenopetala L. J. Agric. Food Chem. 2003;51:3546-3553. https://doi.org/10.1021/jf0211480
  9. Reddy DH, Seshaiah K, Reddy AV, Rao MM, Wang MC. Biosorption of $Pb^{2+}$ from aqueous solutions by Moringa oleifera bark: equilibrium and kinetic studies. J. Hazard. Mater. 2010;174:831-838. https://doi.org/10.1016/j.jhazmat.2009.09.128
  10. Pascoal Neto C, Rocha J, Gil A, et al. 13C solid-state nuclear magnetic resonance and Fourier transform infrared studies of the thermal decomposition of cork. Solid State Nucl. Magn. Reson. 1995;4:143-151. https://doi.org/10.1016/0926-2040(94)00039-F
  11. Bayramoglu G, Yakup Arica M. Construction a hybrid biosorbent using Scenedesmus quadricauda and Ca-alginate for biosorption of Cu(II), Zn(II) and Ni(II): kinetics and equilibrium studies. Bioresour. Technol. 2009;100:186-193. https://doi.org/10.1016/j.biortech.2008.05.050
  12. Ozdemir S, Kilinc E, Poli A, Nicolaus B, Guven K. Biosorption of Cd, Cu, Ni, Mn and Zn from aqueous solutions by thermophilic bacteria, Geobacillus toebii sub.sp. decanicus and Geobacillus thermoleovorans sub.sp. stromboliensis: equilibrium, kinetic and thermodynamic studies. Chem. Eng. J. 2009;152:195-206. https://doi.org/10.1016/j.cej.2009.04.041
  13. Moreno-Castilla C, Lopez-Ramon MV, Carrasco-Marin F. Changes in surface chemistry of activated carbons by wet oxidation. Carbon 2000;38:1995-2001. https://doi.org/10.1016/S0008-6223(00)00048-8
  14. Zhu B, Fan T, Zhang D. Adsorption of copper ions from aqueous solution by citric acid modified soybean straw. J. Hazard. Mater. 2008;153:300-308. https://doi.org/10.1016/j.jhazmat.2007.08.050
  15. Lagergren S. About the theory of so-called adsorption of soluble substances. K. Sven. Vetensk. Akad. Handl. 1898;24:1-39.
  16. Ho YS, McKay G. Pseudo-second order model for sorption processes. Process Biochem. 1999;34:451-465. https://doi.org/10.1016/S0032-9592(98)00112-5
  17. Weber WJ, Morris JC. Kinetics of adsorption on carbon from solution. J. Sanit. Eng. Div. 1963;89:31-60.
  18. Al-Degs YS, El-Barghouthi MI, Issa AA, Khraisheh MA, Walker GM. Sorption of Zn(II), Pb(II), and Co(II) using natural sorbents: equilibrium and kinetic studies. Water Res. 2006;40:2645-2658. https://doi.org/10.1016/j.watres.2006.05.018
  19. Srividya K, Mohanty K. Biosorption of hexavalent chromium from aqueous solutions by Catla catla scales: equilibrium and kinetics studies. Chem. Eng. J. 2009;155:666-673. https://doi.org/10.1016/j.cej.2009.08.024
  20. Langmuir, I. The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc. 1918;40:1361- 1403. https://doi.org/10.1021/ja02242a004
  21. Singh KK, Talat M, Hasan SH. Removal of lead from aqueous solutions by agricultural waste maize bran. Bioresour. Technol. 2006;97:2124-2130. https://doi.org/10.1016/j.biortech.2005.09.016
  22. Freundlich HM. Uber die adsorption in losungen. Z. Phys. Chem. 1906;57: 385-470.
  23. Dubinin MM, Radushkevich LV. Equation of the characteristic curve of activated charcoal. Proc. Acad. Sci. USSR Phys. Chem. Sect. 1947;55:331-333.
  24. Temkin MI, Pyzhev V. Kinetics of ammonia synthesis on promoted iron catalysts. Acta Physicochim. USSR 1940;12:327-356.
  25. Kim Y, Kim C, Choi I, Rengaraj S, Yi J. Arsenic removal using mesoporous alumina prepared via a templating method. Environ. Sci. Technol. 2004;38:924-931. https://doi.org/10.1021/es0346431
  26. Aksu Z, Isoglu IA. Removal of copper(II) ions from aqueous solution by biosorption onto agricultural waste sugar beet pulp. Process Chem. 2005;40:3031-3044.

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