Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Preparation of Nano-sized Zirconia Powders by the Impregnation Method

함침법에 의한 지르코니아 나노 분말의 합성

  • Han, Cheong-Hwa (Department of Advanced Materials & Chemical Engineering, Halla University) ;
  • Kim, Soo-Jong (Department of Advanced Materials & Chemical Engineering, Halla University)
  • 한정화 (한라대학교 신소재화학공학과) ;
  • 김수종 (한라대학교 신소재화학공학과)
  • Received : 2012.08.15
  • Accepted : 2012.10.02
  • Published : 2012.09.30
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Abstract

The nano-sized zirconia powders were synthesized in an impregnation method using pulp and $ZrOCl_2{\cdot}8H_2O$ as an initial material. The synthesized powders were characterized by XRD and FE-SEM. The particle size of the powder was controlled by preparation conditions, such as drying temperature and time. As a result of the various drying and calcination conditions, 30~50 nm sized homogeneous zirconia particles were obtained at $800^{\circ}C$ for 1 h. Crystallization and the rapid growth of particles were accelerated with increasing calcination temperature and time. Tetragonal phase generated below $800^{\circ}C$ were transferred to monoclinic phase with increasing calcination temperature and time. Moreover, above $800^{\circ}C$, heat treatment time had very large influence on the particle growth, and the change of drying condition also had large influence on the growth of a crystal.

Keywords

References

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