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Reactive Sputtering Process for $CuIn_{1-x}Ga_xSe_2$ Thin Film Solar Cells

  • Park, Nae-Man (Convergence Components & Materials Research Laboratory, ETRI) ;
  • Lee, Ho Sub (Convergence Components & Materials Research Laboratory, ETRI) ;
  • Kim, Jeha (Convergence Components & Materials Research Laboratory, ETRI, Research Institute of Photovoltaics, Cheongju University)
  • 투고 : 2012.02.09
  • 심사 : 2012.07.09
  • 발행 : 2012.10.31

초록

$CuIn_{1-x}Ga_xSe_2$ (CIGS) thin films are grown on Mo/soda lime glass using a reactive sputtering process in which a Se cracker is used to deliver reactive Se molecules. The Cu and $(In_{0.7}Ga_{0.3})_2Se_3$ targets are simultaneously sputtered under the delivery of reactive Se. The effects of Se flux on film composition are investigated. The Cu/(In+Ga) composition ratio increases as the Se flux increases at a plasma power of less than 30 W for the Cu target. The (112) crystal orientation becomes dominant, and crystal grain size is larger with Se flux. The power conversion efficiency of a solar cell fabricated using an 800-nm CIGS film is 8.5%.

키워드

참고문헌

  1. M. Green, "Thin-Film Solar Cells: Review of Materials, Technologies and Commercial Status", J. Mater. Sci., vol. 18, 2007, pp. 15-19.
  2. F. Krebs, "Fabrication and Processing of Polymer Solar Cells: A Review of Printing and Coating Techniques," Sol. Energy Mater. Sol. Cells, vol. 93, 2009, pp. 394-412. https://doi.org/10.1016/j.solmat.2008.10.004
  3. M. Kemell, M. Ritala, and M. Leskela, "Thin Film Deposition Methods for CuInSe2 Solar Cells," Crit. Rev. Solid State Mat. Sci., vol. 30, 2005, pp. 1-31. https://doi.org/10.1080/10408430590918341
  4. T. Todorov and D. Mitzi, "Direct Liquid Coating of Chalcopyrite Light-Absorbing Layers for Photovoltaic Devices," Eur. J. Inorg. Chem., 2010, pp. 17-28. https://doi.org/10.1002/ejic.200900837
  5. N.-M. Park et al., "Effect of Se flux on CuIn1-xGaxSe2 Film in Reactive Sputtering Process," Prog. Photovolt: Res. Appl., DOI: 10.1002/pip.1202.
  6. S. Niki et al., "CIGS Absorbers and Processes," Prog. Photovolt: Res. Appl., vol. 18, 2010, pp. 453-466. https://doi.org/10.1002/pip.969
  7. N. Dhere, "GW/Year of CIGS Production within the Next Decade," Sol. Energy Mater. Sol. Cells, vol. 91, 2007, pp. 1376-1382. https://doi.org/10.1016/j.solmat.2007.04.003
  8. K. Ramanathan et al., "Processing and Properties of Sub-micron CIGS Solar Cells," Proc. 4th World Conf. Photovoltaic Solar Energy Conversion, 2006, pp. 380-383.
  9. Z. Jehl et al., "Thinning of CIGS Solar Cells: Part II: Cell Characterizations," Thin Solid Films, vol. 519, 2011, pp. 7212-7215. https://doi.org/10.1016/j.tsf.2010.12.224
  10. S. Chaisitsak, A. Yamada, and M. Konagai, "Preferred Orientation Control of Cu(In1-xGax)Se2 (x =0.28) Thin Films and Its Influence on Solar Cell Characteristics," Jpn. J. Appl. Phys., vol. 41, 2002, pp. 507-513. https://doi.org/10.1143/JJAP.41.507
  11. G. Hanna et al., "Influence of the Selenium Flux on the Growth of Cu(In,Ga)Se2 Thin Films," Thin Solid Films, vol. 431-432, 2003, pp. 31-36. https://doi.org/10.1016/S0040-6090(03)00242-6
  12. A. Bolcavage et al., "Phase Equilibria of the cu-in System I: Experimental Investigation," J. Phase Equilibria, vol. 14, 1993, pp. 14-21. https://doi.org/10.1007/BF02652157
  13. R. Murray and R. Heyding, "The Copper-Selenium System at Temperatures to 850 K and Pressures to 50 kbar," Can. J. Chem., vol. 53, 1975, pp. 878-887. https://doi.org/10.1139/v75-122
  14. W. Honle, G. Huhn, and U. Boehnke, "Crystal Structures of Two Quenched CuInSe Phases," Cryst. Res. Technol, vol. 23, 1988, pp. 1347-1354. https://doi.org/10.1002/crat.2170231027
  15. T. Schlenker et al., "Substrate Influence on Cu(In,Ga)Se2 Film Texture," Thin Solid Films, vol. 480-481, 2005, pp. 29-32. https://doi.org/10.1016/j.tsf.2004.11.034
  16. Y.-D. Chung et al., "Incorporation of Cu in Cu(In,Ga)Se2-Based Thin-Film Solar Cells," J. Kor. Phys. Soc., vol. 57, 2010, pp. 1826-1830. https://doi.org/10.3938/jkps.57.1826

피인용 문헌

  1. Thin Metal Electrodes for Semitransparent Organic Photovoltaics vol.35, pp.4, 2012, https://doi.org/10.4218/etrij.13.1912.0025
  2. Growth and structural properties of reactively co-sputtered CIGS films and their solar cell applications vol.64, pp.3, 2012, https://doi.org/10.3938/jkps.64.465
  3. Na-Dependent Ultrafast Carrier Dynamics of CdS/Cu(In,Ga)Se2 Measured by Optical Pump-Terahertz Probe Spectroscopy vol.119, pp.35, 2012, https://doi.org/10.1021/acs.jpcc.5b02282
  4. Flower like Buffer Layer to Improve Efficiency of Submicron-Thick CuIn1-xGaxSe2 Solar Cells vol.37, pp.6, 2012, https://doi.org/10.4218/etrij.15.0115.0114