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Removal of natural organic matter and trihalomethane formation potential by four different coagulants during coagulation-microfiltration processes

응집과 막여과 공정에서 응집제에 따른 유기물 및 THMFP제거

  • 박근영 (건국대학교 공과대학 환경공학과) ;
  • 최양훈 (한국수자원공사 상하수도연구소) ;
  • 진용철 (성현INB기술연구소) ;
  • 강선구 (건국대학교 공과대학 환경공학과) ;
  • 권지향 (건국대학교 공과대학 환경공학과)
  • Received : 2012.12.24
  • Accepted : 2013.02.08
  • Published : 2013.02.15

Abstract

Integrated process with coagulation and microfiltration as an advanced water treatment has been expanded its application in recent years due to its superb removal of particles and natural organic matter. In usual, effectiveness of coagulation sometimes determines performance of the whole system. Several new polymeric coagulants introduced to water utilities for better efficiency were studied in this paper. Three polymeric coagulants (i.e., PACl, PACs, and PAHCs) along with alum were evaluated for removal of natural organic matter, especially for reduction of trihalomethane formation potential, for which regulation has become stringent. Turbidity removal was closely related to pH variation showing the reduced turbidity removal by PACs due to the decreases in the pH of supernants at high doses. The four coagulants showed different organic matter removal during coagulation and affected the removal in microfiltration. For instance, DOC concentration was not reduced by microfiltration when PAHCs were used however 10 % of DOC removal was observed by microfiltration with alum coagulation. Coagulation pretreatment also impacted the THM removals, i.e., approximately 30 % of THMs and 13 % of DOC was removed by microfiltration only, but 40 to 67 % of THMs and 30 % of DOC was removed by the integrated process. Strategies on selection of coagulants are needed depending on characteristics of target pollutants in raw waters.

Keywords

References

  1. EPA, Basic information about disinfection byproducts in drinking water: Total trihalomethanes, Haloacetic acid, bromate, and chlorite. Cited 2012, March. http://water.epa.gov/drink/contaminants/basicinformation/disinfectionbyproducts.cfm
  2. Fan, L., Harris, J.L. and Roddick, F.A. (2001) Influence of the of the characteristics of natural organic matter on the fouling of microfiltration membranes, Water Research, 35(18), pp.4455-4463 https://doi.org/10.1016/S0043-1354(01)00183-X
  3. Jin, Y. C., Choi, Y.H. and Kweon, J.H. (2011) Impact of characteristics of polymeric Al coagulants PACl and Alum on membrane flux and fouling of microfiltration, Journal of the Korean society of water and wastewater, 25(2), pp. 231-246
  4. Jung, C.W., Shim, H.S. and Sohn, I.S. (2007) Effect of metal salt coagulant on membrane fouling during coagulation-UF membrane process, Korean Chem. Eng. Res, 45(5), pp.523-528
  5. Kalscheur K.N., Gerwe C.E., Kweon J.H., Speitel J.G.E. and Lawler D.F. (2006) Enhanced softening: Effects of source water quality on NOM removal and DBP formation, AWWA, 98(11), pp. 93-106
  6. Kim, H.C., Yu, M.J. and Lee, S.H. (2005) Influence of different mixing types on the removal of natural organic matter in water treatment, Journal of the Korean society of water and wastewater, 19(3), pp. 370-377
  7. Kim, J.H., Lee, C.H., Sohn, J.S. and Yoon, J.Y. (2004) The correlation between the polymeric aluminum species of inorganic coagulant and its coagulation efficiency, Journal of the Korean society of water and wastewater, 18(3), pp. 331-336
  8. Kim, J.K. (2006) Speciation of THMs, HAAs, Korean society of environmental engineers, 28(11), pp. 1135-1140
  9. Korea Ministry of Government Legislation, Standard for drinking water quality in korea. Cited 2011, Dec. http://law.go.kr/1sInfoP.DO?1siSeq=120260#AJAX
  10. Nikola ou A.D., Lekkas T.D. and Golfinopoulos S.K., (2004) Kinetics of the formation and decomposition of chlorination by-products in surface water, chemical engineering, 100(1-3) pp. 139-148 https://doi.org/10.1016/j.cej.2004.01.033
  11. Park, S.H., Hong, J,H., Yu, M.J. and Koo, J.Y. (2010) A study on the fouling characteristics of low-pressure membranes and NOM with coagulation pretreatment, Journal of the Korean society of water and wastewater, 24(2), pp. 237-24
  12. Schafer A.I., Schwicker U., Fischer M.M., Fane A.G. and Waite T.D. (2000) Microfiltration of colloids and natural organic matter, Journal of membrane science, 171(2), pp.151-172 https://doi.org/10.1016/S0376-7388(99)00286-0
  13. Sharp E.L., Parsons S.A. and Jefferson B. (2006) Seasonal variations in natural organic matter and its impact on coagulation in water treatment, Science of the Total Environment, 363(1-3), pp. 183-194 https://doi.org/10.1016/j.scitotenv.2005.05.032
  14. Taimur Khan, M.M., Lewandowski, Z., Takizawa, S., Yamada, K., Katayama, H., Yamamoto K. and Ohgaki S. (2009) Continuous and efficient removal of THMs from river water using MF membrane combined with high dose of PAC, Desalination, 249(2), pp. 713-720 https://doi.org/10.1016/j.desal.2008.09.009
  15. Son, H.J., Jeong, C.W. and Kang, L.S. (2004) The relationship between disinfection byproduct formation and characteristics of natural organic matter in the raw water for drinking water, Korean society of environmental engineers, 26(4), pp. 457-466
  16. Wang, S., Liu, C. and Li, Q. (2011) Fouling of microfiltration membranes by organic polymer coagulants and flocculants: Controlling factors and mechanisms, water research, 45(1), pp. 357-365 https://doi.org/10.1016/j.watres.2010.08.009
  17. Xie, Y. F. (2003) Disinfection byproducts in drinking water formation, analysis, and control, Lewis publishers
  18. Yeom, C.M., Byun, S.J., Cho, S.H. and Yoon, J.Y. (2003) Disinfection by-products formation potential as the characteristics of natural organic matter in raw water, Journal of the Korean society of water and wastewater, 17(1), pp. 72-78
  19. Yoon, Y.S., Lee, H.D. and Kim, S.D. (2009) The analysis and design of the disinfection process, Donghwa technology publishing

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