Bulletin of the Korean Chemical Society

  • 제34권2호
  • /
  • Pages.421-425
  • /
  • 2013
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  • 0253-2964(pISSN)
  • /
  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Effect of Different Pretreatments on Indium-Tin Oxide Electrodes

  • Choi, Moonjeong (Department of Chemistry and Chemistry Institute of Functional Materials, Pusan National University) ;
  • Jo, Kyungmin (Department of Chemistry and Chemistry Institute of Functional Materials, Pusan National University) ;
  • Yang, Haesik (Department of Chemistry and Chemistry Institute of Functional Materials, Pusan National University)
  • 투고 : 2012.10.25
  • 심사 : 2012.11.12
  • 발행 : 2013.02.20
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초록

The effect of pretreatment on indium-tin oxide (ITO) electrodes has been rarely studied, although that on metal and carbon electrodes has been enormously done. The electrochemical and surface properties of ITO electrodes are investigated after 6 different pretreatments. The electrochemical behaviors for oxygen reduction, $Ru(NH_3){_6}^{3+}$ reduction, $Fe(CN){_6}^{3-}$ reduction, and p-hydroquinone oxidation are compared, and the surface roughness, hydrophilicity, and surface chemical composition are also compared. Oxygen reduction, $Fe(CN){_6}^{3-}$ reduction, and p-hydroquinone oxidation are highly affected by the type of the pretreatment, whereas $Ru(NH_3){_6}^{3+}$ reduction is almost independent of it. Interestingly, oxygen reduction is significantly suppressed by the treatment in an HCl solution. The changes in surface roughness and composition are not high after each pretreatment, but the change in contact angle is substantial in some pretreatments.

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