Interfacial Microstructure and Electrical Properties of $Al_2O_3/Si$ Interface of Mono-crystalline Silicon Solar Cells

단결정 실리콘 태양전지에서 후열처리에 따른 $Al_2O_3/Si$ 계면조직의 특성 변화

  • Paek, Sin Hye (KCC Central Research Inst.) ;
  • Kim, In Seob (School of Materials Sci. & Engr. of University of Ulsan) ;
  • Cheon, Joo Yong (School of Materials Sci. & Engr. of University of Ulsan) ;
  • Chun, Hui Gon (School of Materials Sci. & Engr. of University of Ulsan)
  • 백신혜 (KCC 중앙연구소) ;
  • 김인섭 (울산대학교 첨단소재공학부) ;
  • 천주용 (울산대학교 첨단소재공학부) ;
  • 천희곤 (울산대학교 첨단소재공학부)
  • Received : 2013.08.30
  • Accepted : 2013.09.23
  • Published : 2013.09.30

Abstract

Efficient and inexpensive solar cells are necessary for photo-voltaic to be widely adopted for mainstream electricity generation. For this to occur, the recombination losses of charge carriers (i.e. electrons or holes) must be minimized using a surface passivation technique suitable for manufacturing. Recently it has been shown that aluminum oxide thin films are negatively charged dielectrics that provide excellent surface passivation of silicon solar cells to attract positive-charged holes. Especially aluminum oxide thin film is a quite suitable passivation on the rear side of p-type silicon solar cells. This paper, it demonstrate the interfacial microstructure and electrical properties of mono-crystalline silicon surface passivated by $Al_2O_3$ films during firing process as applied for screen-printed solar cells. The first task is a comparison of the interfacial microstructure and chemical bonds of PECVD $Al_2O_3$ and of PEALD $Al_2O_3$ films for the surface passivation of silicon. The second is to study electrical properties of double-stacked layers of PEALD $Al_2O_3$/PECVD SiN films after firing process in the temperature range of $650{\sim}950^{\circ}C$.

Keywords

References

  1. E.V. Kerschaver, "Back-contact Solar Cells: A review", Prog. Photovolt, Vol.14, p. 107-123, 2006 https://doi.org/10.1002/pip.657
  2. W. Shockley, and W.T. Read, "Statistics of the Recombinations of Holes and Electrons", Physics. Review. 87 (1952), p.835-842 https://doi.org/10.1103/PhysRev.87.835
  3. Aberle AG, "Crystalline Silicon Solar Cells - Advanced surface passivation and analysis", Centre for photovoltaic engineering, University of NSW: Australia, 1999
  4. R. Hezel and K. Jaeger, "Low-Temperature Surface Passivation of Silicon for Solar Cells" Journal of the Electrochemical Society, vol.136, no.2, p.518-523, 1989 https://doi.org/10.1149/1.2096673
  5. B. Hoex, S.B.S. Heil, E. Langereis, M.C.M. van de Sanden, and W.M.M. Kessels, "Ultralow surface recombination of c-Si substrates passivated by plasma-assisted atomic layer deposited $Al_2O_3$", Appl. Phys. Lett. 89, 042112, 2006 https://doi.org/10.1063/1.2240736
  6. K.J. Hubbard and D. G. Schlom, "Thermodynamic stability of binary oxides in contact with silicon", Journal of Materials Research, vol. 11, p. 2757, 1996 https://doi.org/10.1557/JMR.1996.0350
  7. Y. Min, "Atomic Layer Deposition of $Al_2O_3$ Thin Films from a 1-Methoxy-2-methyl-2-propoxide Complex of Aluminum and Water", Chemistry of Materials, vol. 17, p. 626, 2005 https://doi.org/10.1021/cm048649g