DOI QR코드

DOI QR Code

Volume Optimization of a Combined System of LNT and SCR Catalysts Considering Economic Feasibility and De-NOx Performance

  • Seo, Choong-Kil (Department of Automative & Mechanical Engineering, Howon University) ;
  • Choi, Byung-Chul (School of Mechanical System Engineering, Chonnam National University) ;
  • Kim, Young-Kwon (Gwangju Center, Korea Automotive Technology Institute)
  • Received : 2012.08.14
  • Accepted : 2012.12.20
  • Published : 2013.02.28

Abstract

The purpose of the study is carried out volume optimization of a combined system consisting of an LNT and SCR catalysts from the standpoint of its economic feasibility and de-NOx performance. Under the rich air-fuel ratio conditions for 5s (${\Phi}$=1.1), CO, $H_2$ and THC were generated at levels of 4%, 1.2% and $110ppmC_1$, respectively. The NOx conversion of the 1+1 combination was 5% lower than that of the 1.5+0.5 combination, however the reduced volume of the LNT catalyst decreased the total cost by about 6%. Therefore, the optimal volume ratio of the LNT and SCR catalysts was found to be the 1+1 catalyst combination, which has the highest total score in the terms of an economic feasibility and the NOx performance.

Keywords

References

  1. C. K. Seo, H. N. Kim, B. C. Choi, M. T. Lim, C. H. Lee and C. B. Lee, 2011, "De-NOx characteristics of a combined system of LNT and SCR catalysts according to hydrothermal aging and sulfur poisoning", Catalysis Today. Vol. 164. pp. 507-514. https://doi.org/10.1016/j.cattod.2010.10.010
  2. C. K. Seo, H. N. Kim and B. C. Choi, 2010, "Characteristics of Adsorption, Desorption of Exhaust Gases and Deactivation of LNT and SCR Catalysts for Diesel Vehicles", Journal of the Korea Society For Power System, Vol 14. pp. 13-19.
  3. Official Journal of the European Union, Regulation (EC) No 595/2009. July 18.
  4. R. Snow, D. Dobson, R. Hammerle and S. Katare, "Robustness of a LNT-SCR System to Aging Protocol", SAE Papers No. 2007-01-0469.
  5. J. Wang, Y. JI, Z. He, M. Crocker, M. Dearth and R. McCabe, "A non-$NH_3$ pathway for NOx conversion in coupled LNT-SCR system", SAE Papers No, 2010-01-0305.
  6. P. Forzatti and L. Lietti, 2010, "The reduction of NOx stored on LNT and combined LNT-SCR systems, Catalysis Today. Vol. 155. pp. 131-139. https://doi.org/10.1016/j.cattod.2008.11.023
  7. C. K. Seo, H. N. Kim, B. C. Choi and M. T. Lim, 2011, "The optimal volume of a combined system of LNT and SCR catalysts", J. Ing. Eng. Chem. Vol. 17, pp. 382-385. https://doi.org/10.1016/j.jiec.2010.10.033
  8. S. Y. Park, H. N. Kim and B. C. Choi, 2010, "Effective parameters for DME steam reforming catalysts for the formation of $H_2$ and CO", J. Ing. Eng. Chem. Vol. 16. pp. 734-740. https://doi.org/10.1016/j.jiec.2010.07.010
  9. L. Xu, R. McCabe, M. Dearth and W. Ruona, "Laboratory and vehicle demonstration of "2nd-generation" LNT+in-situ SCR diesel NOx emission control systems", SAE Papers No, 2010-01-0305.
  10. C. Chimmer, "Transient on-road emission reduction of an LNT+SCR after-treatment system", SAE Papers No. 2008-01-2641.
  11. C. K. Seo, B. C. Choi, H. N. Kim, C. H. Lee and C. B. Lee, 2012, "Effect of $ZrO_2$ addition on de-NOx performance of Cu-ZSM-5 for SCR catalyst", Chem. Eng. J., Vol. 191, pp. 331-340. https://doi.org/10.1016/j.cej.2012.03.027
  12. C. K. Seo, 2012, "Optimization of an LNT-SCR combined system to de-NOx the diesel engine exhasut gas". dissertation for the degree of the Ph. D., Chonnam National University, pp. 54-55.
  13. B. West, S. Huff, J. Parks, S. Lewis, J. S. Choi W. Partride and J. Story, "Assessing reductant chemistry during in-cylinder regeneration of diesel lean NOx traps, SAE Papers No. 2004-01-3023.
  14. J. Parks and V. Prikhodko, "Ammonia production and utilization in a hybrid LNT+SCR system, SAE Papers No. 2009-01-2739.
  15. M. F. Hsieh and J. Wang, 2011, "Sliding-mode observer for urea-selective catalytic reduction (SCR) mid-catalyst ammonia concentration estimation" Int. J. Automo. Tech. Vol. 12. pp. 351-358. https://doi.org/10.1007/s12239-011-0041-9
  16. B. C. Choi, 2001, "Technologies for emission after-treatment", Baro Press Co., p. 51.
  17. http://www.dieselnet.com.

Cited by

  1. Physicochemical Characteristics Based on Hydrothermal Aging of Prepared DOC vol.17, pp.5, 2013, https://doi.org/10.9726/kspse.2013.17.5.013