Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Synthesis of Monomers for Polyamide-type TPEs from Oleic Acid

천연 올레인산 기반 폴리아미드계 TPEs 단량체 합성

  • Koh, Moo-Hyun (Department of Chemical and Biological Engineering, Seoul National University) ;
  • Kim, Hyun Su (Department of Chemical and Biological Engineering, Seoul National University) ;
  • Kim, Hyeonjeong (Department of Chemical and Biological Engineering, Seoul National University) ;
  • Shin, Nara (Department of Chemical and Biological Engineering, Seoul National University) ;
  • Yoo, Dongwon (Department of Chemical and Biological Engineering, Seoul National University) ;
  • Kim, Young Gyu (Department of Chemical and Biological Engineering, Seoul National University)
  • 고무현 (서울대학교 화학생물공학부) ;
  • 김현수 (서울대학교 화학생물공학부) ;
  • 김현정 (서울대학교 화학생물공학부) ;
  • 신나라 (서울대학교 화학생물공학부) ;
  • 유동원 (서울대학교 화학생물공학부) ;
  • 김영규 (서울대학교 화학생물공학부)
  • Received : 2012.12.03
  • Accepted : 2012.12.18
  • Published : 2013.03.31
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Abstract

We have developed the synthetic processes for the monomers of polyamide-type TPEs (thermoplastic elastomers, TPAEs) obtained from vegetable oil. TPAEs have several superior physical properties to those of thermoplastic elastomers (TPEs). From the common starting material, oleic acid, which is commonly found in various vegetable oils, we have synthesized three ${\omega}$-amino acid monomers ($C_9$, $C_{10}$ and $C_{11}$ ${\omega}$-amino acid) and three ${\alpha}$, ${\omega}$-dicarboxylic acids($C_9$, $C_{10}$ and $C_{11}$ ${\alpha}$, ${\omega}$-dicarboxylic acid) for TPAEs in good yields.

식물성 오일로부터 추출한 물질을 기반으로 하여 열가소성 탄성체(thermoplastic elastomer, TPE) 중에서도 뛰어난 물성을 가진 것으로 잘 알려진 폴리아미드계 TPE(polyamide-type TPE, TPAE)의 단량체 합성공정을 개발하였다. 대다수의 식물성 오일에 함유되어 있는 불포화 지방산으로 잘 알려진 올레인산을 사용하여 TPAE의 단량체 6종($C_9$, $C_{10}$, $C_{11}$ ${\omega}$-amino acid 와 ${\alpha}$, ${\omega}$-dicarboxylic acid)을 좋은 수율로 합성하였다.

Keywords

References

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