DOI QR코드

DOI QR Code

The Effect of Nucleating Agent on Zn2SiO4 Crystal Glaze

Zn2SiO4 결정유약에 미치는 핵 형성제의 영향

  • Lee, Hyun-Soo (Department of Materials Science & Engineering, Myongji University)
  • 이현수 (명지대학교 공과대학 신소재공학과)
  • Received : 2012.12.26
  • Accepted : 2013.03.06
  • Published : 2013.03.31

Abstract

Zinc crystal glaze has its limits in practical use of commercial glaze due to the controlling crystal. In order to overcome this limit, and to heighten the practical usage, this study is aimed to develop artificially controlling willemite ($Zn_2SiO_4$) zinc crystalline glaze. For this purpose, it has experimented with the effect of anatase form and rutile form using $TiO_2$ known as nucleating agent. In zinc glaze, adding $TiO_2$ resulted with anatase form becoming more effective at nucleating formation and growth of willemite than the rutile form. Furthermore, it turned out that using the $TiO_2$ - anatase form, with synthetic seeds (zinc silicate), the numbers and positions of crystals can be controlled artificially.

Keywords

References

  1. F. H. Norton, "The Control of Crystalline Glazes", J. Ceram. Soc. Jpn., 20 217-24 (1937). https://doi.org/10.1111/j.1151-2916.1937.tb19892.x
  2. C. W. Parmelee, "Ceramic Glaze", 3rd Edi., Cahners Publishing Co. Inc., York, PA, USA, 1973.
  3. E. Kato and H. Takashima, "Study on the Structure of Zinc Opaque Glazes", J. Ceram. Soc. Jpn., 15 [2] 69-75 (1965).
  4. B. Karasu and S. Turan, "Effect of Cobalt Oxide and Copper Oxide Additions to Zinc-Containing Soft Porcelain Glazes", J. Eur. Ceram. Soc., 22 1447-55 (2002). https://doi.org/10.1016/S0955-2219(01)00456-3
  5. P. W. Mcmillan, "Glass Ceramics", p. 76, 2nd Ed., Academic Press, London, 1979.
  6. C. Y. Lee and B. H. Lee, "A Study of Nucleation and Growth in Zinc Crystal Glaze by Firing Conditions (in korean)," J. Kor. Ceram.Soc., 46 [3] 253-62 (2009). https://doi.org/10.4191/KCERS.2009.46.3.253
  7. V.A. Krapivin and G.A. Demidova, "Crystalline Glaze for Thin Stoneware", Glass Ceram., 26 [10] 35-6 (1969).
  8. C. C. Lee, P. Shen, and H. Y. Lu, "Formation of Willemite from Powder Mixture with $TiO_2$ Addition," J. Mater. Sci., 24 [9] 3300-04 (1989). https://doi.org/10.1007/BF01139057
  9. A. W. A. El-Shennawi and A.A.Omar, "The Roll of Titania and Titania Mixtures in the Nucleation and Crystallization of Spodumene-Willemite-Diopside Glass," Thermochim. Acta., 58 [2] 125-53 (1982). https://doi.org/10.1016/0040-6031(82)87077-9
  10. T. Santhaveesuk, D. Wongratanaphisan, N. Mangkorntong, and S. Choopun, "$Zn_2TiO_4$ Nanostructures Prepared by Thermal Oxidation Method," Adv. Mat. Res., 55-57 641-44 (2008). https://doi.org/10.4028/www.scientific.net/AMR.55-57.641
  11. L. Hou, Y. Hou, M. Zhu, J. Tang, J. Liu, H. Wang, and H. Yan, "Formation and Transformation of $ZnTiO_3$ Prepared by Sol-Gel Process," Mater. Lett., 59 [2-3] 197-200 (2005). https://doi.org/10.1016/j.matlet.2004.07.046
  12. T. A. Sidorov, "Raman Spectra and Molecular Structure of Silicates," Russ. J. Inorg. Chem., 52 [10] 1586-94 (2003).
  13. W. P. Griffith, "Raman Studies on Rock-Forming Minerals. Part I. Orthosilicates and Cyclosilicates," J. Chem. Soc. A., 1372-77 (1969). https://doi.org/10.1039/j19690001372
  14. Y. V. Kolen'ko, K. A. Kovnir, A. I. Gavrilov, A. V. Garshev, P. E. Meskin, B. R. Churagulov, M. Bouchard, C. Colbeau- Justin, O. I. Lebedev, G. Van Tendeloo, and M. Yoshimura, "Structural, Textural, and Electronic Properties of a Nanosized Mesoporous $Zn_xTi_{1-x}O_{2-x}$ Solid Solution Prepared by a Supercritical Drying Route," J. Phys. Chem. B, 109 [43] 20303-09 (2005) https://doi.org/10.1021/jp0535341
  15. R. Casasola, J. M. Rincon and M. Romero, "Glass-Ceramics Glazes for Ceramic Tiles-A Review," J. Mater. Sci., 47 553- 82 (2012).
  16. S. Sedpho, D. Wongratanaphisan, P. Mangkorntong, N. Mangkorntong, and S. Choopun, "Preparation and Characterization of Zinc Titanate Nanostructures by Oxidation Reaction Technique," J. Nat. Sci., 7 [1] 99-104 (2008).

Cited by

  1. on willemite crystalline glaze vol.24, pp.2, 2014, https://doi.org/10.6111/JKCGCT.2014.24.2.070
  2. Effects of Nucleating Seeds on Coloring of Zn2SiO4 Crystal Glazes vol.52, pp.3, 2015, https://doi.org/10.4191/kcers.2015.52.3.197
  3. 아연 결정유약 전처리 공정을 통한 결정생성 및 성장의 mechanism vol.27, pp.1, 2013, https://doi.org/10.6111/jkcgct.2017.27.1.034
  4. 아연결정유약의 결정 생성 및 제어를 위한 Zn2TiO4 활용 연구 vol.27, pp.4, 2013, https://doi.org/10.6111/jkcgct.2017.27.4.154