DOI QR코드

DOI QR Code

Prediction of Autoignition Temperature of n-Propanol and n-Octane Mixture

n-Propanol과 n-Octane 혼합물의 최소자연발화온도의 예측

  • Ha, Dong-Myeong (Dept. of Occupational Health and Safety Engineering, Semyung University)
  • 하동명 (세명대학교 보건안전공학과)
  • Received : 2013.03.08
  • Accepted : 2013.04.01
  • Published : 2013.04.30

Abstract

The lowest values of the AITs(Autoignition temperatures) in the literature were normally used fire and explosion protection. In this study, the AITs of n-Propanol+n-Octane system were measured from ignition delay time(time lag) by using ASTM E659 apparatus. The AITs of n-Propanol and n-Octane which constituted binary systems were $435^{\circ}C$ and $218^{\circ}C$, respectively. The experimental ignition delay time of n-Propanol+n-Octane system were a good agreement with the calculated ignition delay time by the proposed equations with a few A.A.D.(average absolute deviation).

화재 및 폭발 방호를 위해서 문헌에서의 최소자연발화온도 값을 사용하는 것이 일반적이다. 본 연구에서, n-Propanol+n-Octane 계의 최소자연발화온도는 ASTM E659 장치를 이용하여 발화지연시간으로부터 측정하였다. 2성분계를 구성하는 n-Propanol과 n-Octane의 측정된 최소자연발화온도는 각 각 $435^{\circ}C$$218^{\circ}C$ 였다. 그리고 두 개의 2성분계에서 측정된 발화지연시간은 제시된 식에 의한 예측된 발화지연시간과 적은 평균절대오차에서 일치하였다.

Keywords

References

  1. Crowl, D.A. and J. F. Louvar, Chemical Process Safety Fundamentals with Application, 2nd ed., Pearson Education Inc., (2002)
  2. Cullis, C.F. and C.D. Foster, "Studies of the Spontaneous Ignition in the Air of Binary Hydrocarbon Mixtures", Combustion and Flame, 23, 347-356, (1974) https://doi.org/10.1016/0010-2180(74)90117-5
  3. Ha, D.M. and S.J. Lee, "Measurement of Autoignition Temperature of o-Xylene+n-Pentanol System", J. of the Korean Society of Safety, 21(4), 66-72, (2006)
  4. Ha, D.M., "Investigation of Combustible Properties of Binary Systems for Risk Assessment of Equipment of Hazard Materials Storage", Semyung Univ. 2011-2-170, Semyung Univ., (2011)
  5. Goldfrab, I. and A. Zinoviev, "A Study of Delay Spontaneous Insulation Fires", Physics Letter, 311, 491-500, (2003) https://doi.org/10.1016/S0375-9601(03)00506-1
  6. Box, G.E.P. and N.R. Draper, Empirical Model-Building and Response Surface, John Wiley and Sons, Inc., (1987)
  7. Drysdale, D., An Introduction to Fire Dynamics, 2nd ed., Jone Wiley & Sons, (1998)
  8. Semenov, N.N., Some Problems in Chemical Kinetics and Reactivity, Vol. 2, Princeton University
  9. NFPA, Fire Hazard Properties of Flammable Liquid, Gases, and Volatile Solids, NFPA 325M, NFPA, (1991)
  10. Lenga, R.E. and K.L. Votoupal, The Sigma Aldrich Library of Regulatory and Safety Data, Volume I-III, Sigma Chemical Company and Aldrich Chemical Company Inc., (1993)
  11. Kanury, A.M., SFPE Handbook of Fire Protection Engineering ; Ignition of Liquid Fuels, 2nd ed., SFPE, (1995)
  12. Babrauskas, V., Ignition Handbook, Fire Science Publishers, SFPE (2003)
  13. Lewis, R.J., SAX's Dangerous Properties of Industrial Materials, 11th ed., John Wiley & Son, Inc., N.J., (2004)
  14. Jackson, J.L., "Spontaneous Ignition Temperature -Commercial Fluids and Pure Hydrocarbons-", Industrial and Engineering Chemistry, 43(12), 2869-2870, (1951) https://doi.org/10.1021/ie50504a058
  15. Hilado, C.J. and S.W. Clark, "Autoignition Temperature of Organic Chemicals", Chemical Engineering, 4, 75-80, (1972)
  16. Scott, G.S., G.W. Jones and F.E. Scott, "Determination of Ignition Temperature of Combustible Liquids and Gases", Analytical Chemistry, 20(3), 238-241, (1948) https://doi.org/10.1021/ac60015a015
  17. Zabetakis, M.G., A.L. Furno and G.W. Jones, "Minimum Spontaneous Ignition Temperature of Combustibles in Air", Industrial and Engineering Chemistry, 46(10), 2173-2178, (1954) https://doi.org/10.1021/ie50538a047
  18. Dean, J.A., Lange's Handbook of Chemistry, 14th ed., McGraw Hill, (1992)
  19. Lide, D. R., Handbook Chemistry and Physics, 76th ed., CRC Press, (1996)

Cited by

  1. Measurement of Autoignition Temperature of Propionic Acid and 3-Hexanone System vol.28, pp.4, 2014, https://doi.org/10.7731/KIFSE.2014.28.4.044
  2. Measurement and Prediction of Autoignition Temperature of n-Propanol+n-Decane Mixture vol.29, pp.6, 2014, https://doi.org/10.14346/JKOSOS.2014.29.6.055
  3. Measurement and Prediction of Autoignition Temperature(AIT) of n-Decane+Ethylbenzene System vol.19, pp.5, 2015, https://doi.org/10.7842/kigas.2015.19.5.54
  4. Measurement and Prediction of the Combustible Properties of n-Butyl methacrylate(n-BMA) vol.31, pp.4, 2016, https://doi.org/10.14346/JKOSOS.2016.31.4.42
  5. Measurement and Prediction of Autoignition Temperature of n-Hexanol+p-Xylene Mixture vol.25, pp.1, 2016, https://doi.org/10.5855/ENERGY.2015.25.1.048
  6. Measurement of Autoignition Temperature of n-Propanol and Formic acid System vol.27, pp.5, 2013, https://doi.org/10.7731/KIFSE.2013.27.5.64
  7. Prediction and Measurement of Autoignition Temperature of Toluene and 2-Butanol System vol.30, pp.4, 2015, https://doi.org/10.14346/JKOSOS.2015.30.4.73