Journal of Korean Society on Water Environment (한국물환경학회지)

Korean Society on Water Environment (한국물환경학회)
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Feature of the Change of the Arsenic Ionic State and Prediction of Toxicity in Aqueous Environment depending on Temperature Condition

온도 조건에 따른 비소 이온의 수중 상태 변화 특성 및 독성 예측

  • Won, Yu-Ra (Department of Environmental Science and Engineering, Ewha Womans University) ;
  • Kim, Dong-Su (Department of Environmental Science and Engineering, Ewha Womans University)
  • 원유라 (이화여자대학교 환경학과) ;
  • 김동수 (이화여자대학교 환경학과)
  • Published : 2013.03.30
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Abstract

The variation of the stable region of arsenic compounds in aqueous environment with temperature has been investigated by constructing the Pourbaix diagram of arsenic at different temperatures. The standard potential corresponding to the boundary between arsenic compounds with different charge valence was estimated to be decreased with temperature, which means the stability of arsenic compound with +5 charge valence increases. The distribution diagram of the most highly oxidized arsenic compound showed that arsenic acid is formed at higher pH and arsenate is generated at lower pH as temperature rises. The aquatic toxicity due to arsenic compounds was considered to be decreased with temperature in the neutral pH condition based on the $LD_T$ value defined in this study.

Keywords

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