DOI QR코드

DOI QR Code

Monitoring of the Changes in Volatile Flavor Components in Oriental Melon Wine Using SPME

SPME를 이용한 참외와인의 휘발성 향기성분의 모니터링

  • Jo, Yong-Jun (Department of Food Science and Technology, Keimyung University) ;
  • Kim, Ok-Mi (Faculty of Hotel Culinary Arts, Taekyeung College) ;
  • Jeong, Yong-Jin (Department of Food Science and Technology, Keimyung University)
  • 조용준 (계명대학교 식품가공학과) ;
  • 김옥미 (대경대학교 호텔조리계열) ;
  • 정용진 (계명대학교 식품가공학과)
  • Received : 2013.01.11
  • Accepted : 2013.04.15
  • Published : 2013.04.30

Abstract

This study was conducted to investigate changes in the main volatile flavor components of oriental melon during the process of alcohol fermentation via SPME (solid phase micro extraction). The flavor components of oriental melon were shown to have mainly included melon and green flavors. The green flavor was identified to be nonanal, 1-butanol, 1-octen-2-ol and benzene, and its relative concentration was shown to be 16.66%. The nonanal concentration was shown to have been reduced among the green-flavor components, but no significant change in remaining components was observed. Mainly, sweet flavor tended to increase, and the relative concentration of benzene was particularly shown to have increase by 25.58%, accounting for the highest relative concentration. The amount of green-flavor components, except for 1-butanol, was shown to have significantly decrease after alcohol fermentation. Then, no component of green-flavor, which causes an offensive smell, was found during fermentation and aging. Meanwhile, the volatile flavor components, which are consist of acids, were shown to have been produced during alcohol fermentation. In particular, octanoic acid, which causes off-flavor, was shown to be 60.99%, a very high relative concentration during the aging stage. In addition, acetic acid with a pungent sour flavor tended to be produced. A further study on the improvement of flavor in the production of oriental melon wine is required.

본 연구에서는 SPME를 이용하여 참외 알코올 발효과정 중 주요 휘발성 향기성분의 변화를 조사하였다. 참외 원과의 향기성분은 주로 melon 및 풋내향이 주로 나타났으며 풋내성분은 nonanal, 1-butanol, 1-octen-3-ol 및 benzene으로 동정되었고 상대적 농도는 16.66%로 나타났다. 머스트에서는 풋내성분 중 nonanal은 농도는 감소하였으나 나머지 성분들은 큰 변화가 없었으며, 주로 sweet향이 증가하는 경향으로 나타났으며 특히 benzene의 상대적 함량이 25.58% 증가하여 가장 높은 함량을 차지하였다. 알코올 발효 후 1-butanol을 제외한 풋내유발 성분들의 함량이 매우 감소하였으며 숙성 중 모두 검출되지 않은 것으로 나타났다. 이취의 원인이 되는 풋내유발 물질들은 발효 및 숙성과정을 통해 모두 소멸되었으나 acid류의 휘발성 향기성분들은 알코올 발효과정에서 생성되었으며 특히 불쾌취를 유발하는 octanoic acid는 상대적 농도가 숙성과정 중 60.99%로 매우 높게 나타났으며 숙성 중에 자극적인 신냄새의 acetic acid가 생성되는 경향으로 나타나 향후 참외 와인 제조에 있어 향기 개선을 위한 연구가 요구된다.

Keywords

References

  1. Lee JG, Kwon YJ, Chang HJ, Kwag JJ, Kim OC, Choi YH (1997) Volatile components of green tea(Camellia sinesis L. var. Yabukita) by purge and trap headspace sampler. J Korean Soc Food Sci Nutr, 10, 25-30
  2. Seo JH, Park NY, Jeong YJ (2001) Volatile components in perimmon vinegars by solid-phase microextraction. Korean J Food Sci Technol, 33, 153-156
  3. Noh BS (2005) Analysis of volatile compounds using electronic nose and its application in food industry. Korean J Food Sci Technol, 37, 1048-1064
  4. Arthur CL, Pawliszyn J (1990) Solid-phase microextraction with thermal desorption using fused silica optical fibers. Anal Chem, 62, 2145-2148 https://doi.org/10.1021/ac00218a019
  5. Arthur C, Killam LM, Buchholz KD, Pawliszyn J (1992) Automation and optimization of solid-phase microextraction. Anal Chem, 64, 1960-1966 https://doi.org/10.1021/ac00041a034
  6. Zhang Z, Pawliszyn J (1993) Headspace solid-phase microextraction. Anal Chem, 65, 1843-1852 https://doi.org/10.1021/ac00062a008
  7. Yang X, Peppard T (1994) Solid-Phase microextraction for flavor analysis. J Agric Food Chem, 42, 1925-1930 https://doi.org/10.1021/jf00045a018
  8. Penton, Z (1996) Flavor volatiles in a fruit beverage with automated SPME. Food Test Anal, 2, 16-18
  9. Field JA, Nickerson G, James DD, Heider C (1996) Determination of essential oils in hops by headspace solid-phase microextraction. J Agric Food Chem, 44, 1768-1772 https://doi.org/10.1021/jf950663d
  10. Ibanez E, Bernhard RA (1996) Solid-phase microextraction (SPME) of pyrazines in model reaction systems. J Sci Food Agric, 72, 91-96 https://doi.org/10.1002/(SICI)1097-0010(199609)72:1<91::AID-JSFA627>3.0.CO;2-T
  11. Ng LK, Hupe M, Harnois J, Moccia D (1996) Characterization of commercial vodkas by solid-phase microextraction and gas chromatography/mass spectrometry analysis. J Sci Food Agric, 70, 380-388 https://doi.org/10.1002/(SICI)1097-0010(199603)70:3<380::AID-JSFA517>3.0.CO;2-M
  12. Jung GT, Ju IO, Ryu J, Choi JS, Choi YG (2003) Studies on manufacture of wine using apricot. Korean J Food Preserv, 10, 493-497
  13. Lee JM, Kim SK, Lee GD (2003) Monitoring on alcohol fermentation characteristics of strawberry. J Korean Soc Food Sci Nutr, 32, 679-683 https://doi.org/10.3746/jkfn.2003.32.5.679
  14. Cho KM, Lee JB, Kahng GG, Seo WT (2006) A study on the making of sweet persimmon (Diospyros kaki, T) wine. Korean J Food Sci Technol, 38, 785-792
  15. Jeong MR, Cha JD, Yun SI, Han JH, Lee YE (2005) Manufacturing of wine with korean figs(Ficus carica L.) and quality improvement by adding fig leaves. J East Asian Soc Dietary Life 15, 112-118
  16. Kim YS, Jeong DY, Shin DH (2008) Optimum fermentation conditions and fermentation characteristics of mulberry (Morus alba) wine. Korean J Food Sci Technol, 40, 63-69
  17. Jo YJ, Jang SY, Kim OM, Park CW, Jeong YJ (2010) Effects of sugar addition in alcohol fermentation of oriental melon. J Korean Soc Food Sci Nutr, 39, 1359-1365 https://doi.org/10.3746/jkfn.2010.39.9.1359
  18. Jo YJ, Park CW, Jang SY, Kim OM, Jeong YJ (2011) Characteristics of alcohol fermentation in oriental melon by yeast kind. Korean J Food Preserv, 18, 779-785 https://doi.org/10.11002/kjfp.2011.18.5.779
  19. Kwon YJ, Lee JG, Deng KY, Lee GH, Oh MJ (1999) The odor discriminents analysis and the comparison of flavor components in korean and chinese sesame oils. Korean J Postharvest Sci Technol, 6, 200-205
  20. Choi HS, Kang EJ, Kim KH (2006) Analyses of essential oil and headspace compositions of Capsella bursa-pastoris medicus by SDE and SPME methods. Korean J Food Preserv, 13, 108-114
  21. Cho MG, Kim H, Chae YA (2003) Analysis of volatile compounds in leaves and fruits of Zanthoxylum schinifolium siebold et zucc. & Zanthoxylum piperitum DC. by headspace SPME. Korean J Medicinal Crop Sci, 11, 40-45
  22. Park ER, Choi JH, Kim KS (2002) Volatile flavor components from traditional cultivars of pear(Pyrus pyrifolia N.). Korean J Food Sci Technol, 34, 180-185
  23. Suwanagul A, Richardson DG (1998) Identification of headspace volatile compounds from different pear(Pyrus communis L.) varieties. Acta Horticulture, 475, 605-623
  24. Schreiber P, Ofner S, Grosch W (1990) Evaluation of potent odorants in cucumbers(Cucumis sativus) and muskmelon(Cucumis melo) by aroma extract dilution analysis. J Food Sci, 55, 193-195 https://doi.org/10.1111/j.1365-2621.1990.tb06050.x
  25. Schreiber P (1982) Chromatographic studies of biogenesis of plant volatiles. Huethig Verlag, Heidelberg. p 149-158
  26. Kim KS, Lee HJ, Kim SM (1999) Volatile flavor components in watermelon (Citrullus vulgaris S.) and oriental melon (Cucumis melo L.). J Korean Food Sci Technol, 31, 322-328
  27. Buttery RG, Seifert RM, Ling LC, Soderstrom EL, Ogawa JM, Tumbaugh JG (1982) Additional aroma components of honeydew melon. J Agric Food Chem, 30, 1208-1211 https://doi.org/10.1021/jf00114a051
  28. Robert PA (1995) Identification of essential oil components by gas chromatography/mass spectroscopy. Allured Publishing Co., p121-129
  29. Park NY (2000) Dynamic changes in flavor-related components of polygonatum odoratum root as affected by steaming and roasting. Ph D. thesis. Kyungpook National University, Daegu, Korea.
  30. Yuda J (1976) Volatile compounds from beer fermentation. J Soc Brew Japan, 71, 818-830
  31. Chung MS, Lee MS (1998) Analysis of volatile flavor components of Pleurospermum kamtschaticum. Korean J Soc Food Sci, 14, 541-546

Cited by

  1. Physicochemical characteristics and volatile flavor compounds of produced mixture wine with kiwi and permission fruits using wild yeast, Saccharomyces cerevisiae Y28 vol.52, pp.1, 2016, https://doi.org/10.7845/kjm.2016.5072
  2. Change in Flavor Components of Black-fermented Garlic Wine according to the Type of Chips during the Manufacturing Process vol.29, pp.1, 2014, https://doi.org/10.13103/JFHS.2014.29.1.073
  3. 감나무 수령과 감꽃 기관에 따른 휘발성 향기성분 분석 vol.23, pp.4, 2014, https://doi.org/10.12791/ksbec.2014.23.4.321
  4. 발효 과일식초의 대사체 분석 및 향기 특성 vol.46, pp.4, 2013, https://doi.org/10.4014/mbl.1806.06012
  5. 숙성에 의한 옥수수 식초의 향기 성분 변화 vol.48, pp.1, 2013, https://doi.org/10.4014/mbl.1902.02002