청정기술 (Clean Technology)

  • 제19권2호
  • /
  • Pages.128-133
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  • 2013
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  • 1598-9712(pISSN)
  • /
  • 2288-0690(eISSN)
한국청정기술학회 (The Korean Society of Clean Technology)
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다양한 방법으로 제조된 CuO/CeO2 촉매에서의 벤젠의 연소반응

Complete Combustion of Benzene over CuO/CeO2 Catalysts Prepared by Various Methods

  • Jung, Won Young (Department of Chemical Engineering, Pukyong National University) ;
  • Song, Young In (Department of Chemical Engineering, Pukyong National University) ;
  • Hong, Seong-Soo (Department of Chemical Engineering, Pukyong National University)
  • 투고 : 2013.04.30
  • 심사 : 2013.05.28
  • 발행 : 2013.06.28
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초록

$CeO_2$에 담지된 구리산화물에서 벤젠의 촉매연소 반응에 대해 연구하였다. 담지된 구리산화물 촉매들은 볼밀법과 함침법으로 제조하였고, XRD, FT-IR, TEM 및 TPR에 의해 특성분석을 하였다. 볼밀법으로 제조된 CuO/$CeO_2$ 촉매는 높은 담지량에서도 잘 분산된 CuO를 얻었다. 볼밀법으로 제조된 CuO/$CeO_2$ 촉매는 함침법으로 제조된 촉매에 비해 높은 활성을 보여주었다. CuO의 담지량이 증가할수록 촉매 활성이 증가하였으며, 10 wt%로 담지된 촉매에서 가장 높은 활성을 나타내었다. 또한, 10 wt% CuO/$CeO_2$ 촉매에 소량의 $Fe_2O_3$와 CoO의 조촉매 첨가는 CuO의 분산도를 높여 반응활성을 증가시켰다.

Catalytic combustion of benzene over $CeO_2$-supported copper oxides has been investigated. The supported copper oxides catalysts were prepared using ball mill method and characterized by XRD, FT-IR, TEM and TPR. In the CuO/$CeO_2$ catalysts prepared using ball mill method, highly dispersed copper oxide species were shown at high loading ratio. The CuO/$CeO_2$ prepared using ball mill method showed the higher activity than those prepared using impregnation method. The catalytic activity increased with an increase in the CuO loading ratio, 10 wt% loaded CuO/$CeO_2$ catalyst giving the highest activity. In addition, the promoting of 10 wt% loaded CuO/$CeO_2$ catalyst with $Fe_2O_3$ and CoO enhanced the dispersion of CuO and then increased the catalytic activity.

키워드

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피인용 문헌

  1. Plasma-assisted Catalysis for the Abatement of Isopropyl Alcohol over Metal Oxides vol.20, pp.4, 2014, https://doi.org/10.7464/ksct.2014.20.4.375
  2. Catalytic Combustion of Benzene over CuO-CeO2Mixed Oxides Prepared by Co-precipitation Method vol.25, pp.3, 2014, https://doi.org/10.14478/ace.2014.1036