Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Salicylimine-Based Colorimetric and Fluorescent Chemosensor for Selective Detection of Cyanide in Aqueous Buffer

  • Noh, Jin Young (Department of Fine Chemistry, Seoul National University of Science and Technology) ;
  • Hwang, In Hong (Department of Fine Chemistry, Seoul National University of Science and Technology) ;
  • Kim, Hyun (Department of Fine Chemistry, Seoul National University of Science and Technology) ;
  • Song, Eun Joo (Department of Fine Chemistry, Seoul National University of Science and Technology) ;
  • Kim, Kyung Beom (Department of Fine Chemistry, Seoul National University of Science and Technology) ;
  • Kim, Cheal (Department of Fine Chemistry, Seoul National University of Science and Technology)
  • Received : 2013.03.20
  • Accepted : 2013.04.02
  • Published : 2013.07.20
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Abstract

A simple colorimetric and fluorescent anion sensor 1 based on salicylimine showed a high selectivity and sensitivity for detection of cyanide in aqueous solution. The receptor 1 showed high selectivity toward $CN^-$ ions in a 1:1 stoichiometric manner, which induces a fast color change from colorless to orange and a dramatic enhancement in fluorescence intensity selectively for cyanide anions over other anions. Such selectivity resulted from the nucleophilic addition of $CN^-$ to the carbon atom of an electron-deficient imine group. The sensitivity of the fluorescence-based assay (0.06 ${\mu}M$) is below the 1.9 ${\mu}M$ suggested by the World Health Organization (WHO) as the maximum allowable cyanide concentration in drinking water, capable of being a practical system for the monitoring of $CN^-$ concentrations in aqueous samples.

Keywords

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