Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Preparation and Cyclic Performance of Li1.2(Fe0.16Mn0.32Ni0.32)O2 Layered Cathode Material by the Mixed Hydroxide Method

  • Karthikeyan, K. (Faculty of Applied Chemical Engineering, Chonnam National University) ;
  • Nam, K.W. (Chemistry Department, Brookhaven National Laboratory) ;
  • Hu, E.Y. (Chemistry Department, Brookhaven National Laboratory) ;
  • Yang, X.Q. (Chemistry Department, Brookhaven National Laboratory) ;
  • Lee, Y.S. (Faculty of Applied Chemical Engineering, Chonnam National University)
  • Received : 2013.01.29
  • Accepted : 2013.04.03
  • Published : 2013.07.20
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Abstract

Layered $Li_{1.2}(Fe_{0.16}Mn_{0.32}Ni_{0.32})O_2$ was prepared by the mixed hydroxide method at various temperatures. Xray diffraction (XRD) pattern shows that this material has a ${\alpha}-NaFeO_2$ layered structure with $R{\bar{3}}m$ space group and that cation mixing is reduced with increasing synthesis temperature. Scanning electron microscopy (SEM) reveals that nano-sized $Li_{1.2}(Fe_{0.16}Mn_{0.32}Ni_{0.32})O_2$ powder has uniform particle size distribution. X-ray absorption near edge structure (XANES) analysis is used to study the local electronic structure changes around the Mn, Fe, and Ni atoms in this material. The sample prepared at $700^{\circ}C$ delivers the highest discharge capacity of 207 $mAhg^{-1}$ between 2-4.5 V at 0.1 $mAcm^{-2}$ with good capacity retention of 80% after 20 cycles.

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References

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