Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis, Crystal Structures and Properties of Two 3D CdII and ZnII Complexes with a 3-Fold Interpenetrating Feature

  • Lin, Hongyan (Department of Chemistry, Bohai University) ;
  • Sui, Fangfang (Department of Chemistry, Bohai University) ;
  • Liu, Peng (Department of Chemistry, Bohai University) ;
  • Wang, Xiuli (Department of Chemistry, Bohai University) ;
  • Liu, Guocheng (Department of Chemistry, Bohai University)
  • Received : 2013.03.28
  • Accepted : 2013.04.22
  • Published : 2013.07.20
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Abstract

Two new 3D coordination complexes [Cd(3-bpcd)(pht)] (1) and [Zn(3-bpcd)(pht)] (2) [3-bpcd = N,N'-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide, $H_2pht$ = phthalic acid] have been hydrothermally synthesized. X-ray diffraction analysis reveals that the complexes 1 and 2 represent a 4-connected diamondoid topology with a 3-fold interpenetrating feature. Moreover, the fluorescent properties of complexes 1 and 2 are studied.

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References

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