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Coloration Characteristics of Copper Red Glaze

진사 유약의 발색 특성 연구

  • Eo, Hye-Jin (Department of Material Science & Engineering, Myongji University) ;
  • Lee, Byung-Ha (Department of Material Science & Engineering, Myongji University)
  • 어혜진 (명지대학교 신소재공학과) ;
  • 이병하 (명지대학교 신소재공학과)
  • Received : 2013.03.26
  • Accepted : 2013.07.23
  • Published : 2013.07.27

Abstract

The purpose of this study is to investigate the coloration characteristics by identifying the factor affecting red coloration of copper red glaze in traditional Korean ceramics. This study analyzed the characteristics of the reduction-fired copper red glaze by using XRD, Raman spectroscopy, EDX and UV-vis spectroscopy. As a result of XRD analysis, the glaze completely melted and amorphous glass appeared overall, and the characteristic peak of metal Cu was shown together. In addition, as a result of Raman analysis, the characteristic bands of CuO and $Cu_2O$ were shown together. The distribution of component elements was observed by EDX. As a result, copper(Cu) were distributed throughout the glaze. Thus, it was shown that copper red glaze appeared the best red coloration because metal Cu, CuO and $Cu_2O$ evenly existed throughout glaze in particle colloidal state. The chroma value of the copper red glaze was CIE $L^*$ 30.07, $a^*$ 13.65, $b^*$ 3.72. Wine-Red Solution was shown by Dark Graish Red coloration.

Keywords

References

  1. Journal of the Research center for Ceramic Arts., Ewha women's university, 4, 4 (1982).
  2. M. Wakamatsu, S. Ishida, 'Effect of heating and cooling atmospheres on colors of glaze and glass containing copper'. Journal of non-crystalline solids 80, 412 (1986). https://doi.org/10.1016/0022-3093(86)90425-4
  3. M. Wakamatsu, N. Takeuchi, H. Nagai, 'Chemical States of Copper and Tin in Copper Glazes Fired under various Atmospheres', J. Am. Ceram. Soc., 72(1), 16 (1989). https://doi.org/10.1111/j.1151-2916.1989.tb05946.x
  4. J. Zhang. J. Liu, Q. Peng, X. Wang, T. Li, "Nearly Monodisperse $Cu_2O$ and CuO Nanospheres : Preparation and Applications for Sensitive Gas Sensors", Chem. Mater., 18, 867 (2006). https://doi.org/10.1021/cm052256f
  5. M. S. Yeh, Y. S. Yang, Y. P. Lee, H. F. Lee, Y. H. Yeh, C. S. Yeh, "Formation and characteristics of Cu colloids from CuO powder by laser irradiation in 2-propanol", J. Phys. Chem. B., 103, 6851 (1999).
  6. S. F. Brown, F. H. Norton, 'constitution of copper-red Glazes', J. Am. Ceram. Soc., 42(11), 499 (1959). https://doi.org/10.1111/j.1151-2916.1959.tb13566.x
  7. J. A. Creighton, D. G. Eadon, "Ultraviolet-visible absorption spectra of the colloidal metallic elements", J. Chem. Soc., Faraday Trans., 87, 3881 (1991). https://doi.org/10.1039/ft9918703881
  8. J. H. Lee, D. K. Kim, W. Y. Kang, "Preparation of Cu Nanoparticles from Cu Powder Dispersed in 2-Propanol by Laser Ablation", Bull. Korean Chem. Soc. 11(27), 1869 (2006).
  9. P. He, X. Shen, H. Gao, "Size-controlled prearation of $Cu_2O$ octahedron nanocrystals and studies on their optical absorption", J. Collod Interface Sci. 284, 510 (2005). https://doi.org/10.1016/j.jcis.2004.10.060
  10. K. Borgohain, N. Murase, S. Mahamuni, "Synthesis and properties of $Cu_2O$ quantum particles", J. Appl. Phys., 92, 1292 (2002). https://doi.org/10.1063/1.1491020

Cited by

  1. Analysis of the Coloration Characteristics of Copper Red Glaze Using Raman Microscope vol.50, pp.6, 2013, https://doi.org/10.4191/kcers.2013.50.6.518
  2. Chromatic Characteristics of Copper Glaze as a Function of Copper Oxide Addition and Sintering Atmosphere vol.54, pp.1, 2017, https://doi.org/10.4191/kcers.2017.54.1.04