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Analysis of Geographical Origin of Red Ginseng Extract Using Mass Spectrometer-based Electronic Nose

홍삼 농축액의 원산지 판별을 위한 전자코 분석

  • Kim, Ki Hwa (Department of Food Science and Technology, Seoul Women's University) ;
  • Dong, Hyemin (Department of Food Science and Technology, Seoul Women's University) ;
  • Han, Hyun Jung (Department of Food Science and Technology, Seoul Women's University) ;
  • Lee, Young Hyun (Department of Food Science and Technology, Seoul Women's University) ;
  • Moon, Ji Young (Department of Food Science and Technology, Seoul Women's University) ;
  • Bang, Kyong-Hwan (Ginseng Research Division, National Institute of Horticultural and Herbal Science, Rural Development Administration) ;
  • Noh, Bong Soo (Department of Food Science and Technology, Seoul Women's University)
  • 김기화 (서울여자대학교 식품공학과) ;
  • 동혜민 (서울여자대학교 식품공학과) ;
  • 한현정 (서울여자대학교 식품공학과) ;
  • 이영현 (서울여자대학교 식품공학과) ;
  • 문지영 (서울여자대학교 식품공학과) ;
  • 방경환 (농촌진흥청 국립원예특작과학원 인삼특작부) ;
  • 노봉수 (서울여자대학교 식품공학과)
  • Received : 2013.07.04
  • Accepted : 2013.10.04
  • Published : 2013.10.31

Abstract

The geographical origin of red ginseng extract (RGE) was studied using a mass spectrometry based electronic nose. Imported RGE and domestic RGE were diluted to 12oBx. The treated RGE was analyzed, and discriminant function analysis (DFA) was used for discriminating of geographical origins. The DFA plots indicated a significant separation of imported RGE and domestic RGE. The F-value of discriminant function first score (DF1) was much higher than that of discriminant function second score (DF2), indicating that discrimination was mainly affected by DF1. Based on DF1, the concentration of domestic RGE to imported RGE shifted to the left side of DFA plot, and the mixing ratio highly correlated to DF1 value. Unknown sample (#2) was closely located to the sample of mixed imported : domestic (6:4) RGE. In the bar graph, the DF1 value correlated to the mixing ratio. Unknown samples (#2) were thought to be mixed with the imported RGE. This technique could be used to efficiently differentiate the geographical origin of RGE.

수입산과 국내산 홍삼농축액이 혼합비율에 따른 차이에 따른 원산지 판별가능성을 알아보기 위하여 MS-전자코를 이용하여 분석해 보았다. 수입산 홍삼 농축액과 국내산 홍삼농축액의 원산지 판별이 가능하였고 수입산과 국내산 홍삼농축액의 혼합비율에 따라 DF1값이 일정하게 감소하는 경향을 보였다. 관계식으로 볼때, 상관계수가 0.9951와 0.9656로 나타나 정확한 관계식을 토대로 원산지 판별에 적용 가능함을 보여주었다. 이러한 관계식을 토대로 미지의 시료와 함께 판별함수 분석할 경우 수입산과 국내산이 혼합된 제품의 원산지 및 혼합비율을 알아보는 것이 가능함을 알 수 있었다.

Keywords

References

  1. Moon JS, Lee JK, Kim WS, Woo HD. Report of Strategies of functional health food industry. Korea Health Industry Development Institute. Cheongwon, Korea, pp. 5-7 (2011)
  2. Yun TK. Experimental and epidemiological evidence on nonorgan specific cancer preventive effect of Korean ginseng and identification of active compounds. Mutat. Res. 523-524: 63-74 (2003) https://doi.org/10.1016/S0027-5107(02)00322-6
  3. Sotaniemi EA, Haapakoski E, Rautio A. Ginseng therapy in noninsulin-dependent diabetic patients. Diabetes Care 18: 1373-1375 (1995) https://doi.org/10.2337/diacare.18.10.1373
  4. Kwon BM, Kim MK, Baek NI, Kim DS, Park JD, Kim YK, Lee HK, Kim SI. Acyl-CoA: Cholesterol acyltransferase inhibitory activity of ginseng sapogenins, produced from the ginseng saponins. Bioorg. Med. Chem. Lett. 9: 1375-1378 (1999) https://doi.org/10.1016/S0960-894X(99)00208-5
  5. YTN. Cheat '100% domesticred ginseng extract' by the imported one. Available from: http://search.ytn.co.kr/ytn/view.php?s_mcd= 0103&key=200703301151167892&q=%C8%AB%BB%EF+%BF %F8%BB%EA%C1%F6. Accessed May 28, 2013.
  6. Choi JY, Bang KH, Han KY, Noh BS. Discrimination analysis of the geographical origin of food. Korean J. Food Sci. Technol. 44: 503-525 (2012) https://doi.org/10.9721/KJFST.2012.44.5.503
  7. Woo YA, Kim HJ, Cho JH, Chung H. Discrimination of herbal medicines according to geographical origin with near infrared reflectance spectroscopy and pattern recognition techniques. J. Pharmaceut. Biomed. 21: 407-413 (1999) https://doi.org/10.1016/S0731-7085(99)00145-4
  8. Mannas D, Altug T. SPME/GC/MS and sensory flavor profile analysis for estimation of authenticity of thyme honey. Int. J. Food Sci. Tech. 42: 133-138 (2007) https://doi.org/10.1111/j.1365-2621.2006.01157.x
  9. Cho IH, Lee HJ, Kim YS. Difference in the volatile compositions of ginseng species. J. Agr. Food Chem. 60: 7616-7622 (2012) https://doi.org/10.1021/jf301835v
  10. Chan TW, But PP, Cheng SW, Kwok IM, Lau FW, Xu HX. Differentiation and authentication of Panax ginseng, Panax quinquefolius, and ginseng products by using HPLC/MS. Anal. Chem. 72: 1281-1287 (2000) https://doi.org/10.1021/ac990819z
  11. Kim KH, Park SJ, Noh BS. Comparison of volatile compounds from vegetable oils under light emitting diode irradiation using MS-based electronic nose. Food Sci. Biotechnol. 21: 1055-1063 (2012) https://doi.org/10.1007/s10068-012-0137-7
  12. Hong EJ, Kim KH, Park IS, Park SY, Kim SG, Yang HD, Noh BS. Analysis of flavor pattern from different categories of cheeses using electronic nose. Korean J. Food Sci. An. 32: 669-677 (2012) https://doi.org/10.5851/kosfa.2012.32.5.669
  13. Son HJ, Kang JH, Hong EJ, Lim CL, Choi JY, Noh BS. Authentication of sesame oil with addition of perilla oil using electronic nose based on mass spectrometry. Korean J. Food Sci. Technol. 41: 609-614 (2009)
  14. Li S, Li XR, Wang GL, Nie LX, Yang YJ, Wu HZ, Wei F, Zhang J, Tian JG, Lin RC. Rapid discrimination of Chinese red ginseng and Korean ginseng using an electronic nose coupled with chemometrics. J. Pharmaceut. Biomed. 70: 605-608 (2012) https://doi.org/10.1016/j.jpba.2012.06.009
  15. Noh BS, Ko JW, Kim SG. Use of conducting polymer sensor and metal oxide sensor of electronic nose on discrimination of the habitat for Ginseng. J. Nat. Sci. Inst. Seoul Women's Univ. 9: 81-84 (1977)
  16. Hong EJ, Park SJ, Choi JY, Noh BS. Discrimination of palm olein oil and palm sterarin oil mixtures using a mass spectrometry based electronic nose. Food Sci. Biotechnol. 20: 809-816 (2011) https://doi.org/10.1007/s10068-011-0112-8
  17. Noh BS, Youn AR, Lee NY. Application of MS-based electronic nose for discrimination of Angelicae gigantis Radix. Food Sci. Biotechnol. 14: 537-539 (2005)

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