DOI QR코드

DOI QR Code

Semiconductor-Type MEMS Gas Sensor for Real-Time Environmental Monitoring Applications

  • Moon, Seung Eon (Components & Materials Research Laboratory, ETRI) ;
  • Choi, Nak-Jin (Components & Materials Research Laboratory, ETRI) ;
  • Lee, Hyung-Kun (Components & Materials Research Laboratory, ETRI) ;
  • Lee, Jaewoo (Components & Materials Research Laboratory, ETRI) ;
  • Yang, Woo Seok (Components & Materials Research Laboratory, ETRI)
  • Received : 2012.11.26
  • Accepted : 2013.07.02
  • Published : 2013.08.01

Abstract

Low power consuming and highly responsive semiconductor-type microelectromechanical systems (MEMS) gas sensors are fabricated for real-time environmental monitoring applications. This subsystem is developed using a gas sensor module, a Bluetooth module, and a personal digital assistant (PDA) phone. The gas sensor module consists of a $NO_2$ or CO gas sensor and signal processing chips. The MEMS gas sensor is composed of a microheater, a sensing electrode, and sensing material. Metal oxide nanopowder is drop-coated onto a substrate using a microheater and integrated into the gas sensor module. The change in resistance of the metal oxide nanopowder from exposure to oxidizing or deoxidizing gases is utilized as the principle mechanism of this gas sensor operation. The variation detected in the gas sensor module is transferred to the PDA phone by way of the Bluetooth module.

Keywords

References

  1. M. Sharifi and M. Okhovvat "Scate: A Scalable Time and Energy Aware Actor Task Allocation Algorithm in Wireless Sensor and Actor Networks," ETRI J., vol. 34, no. 3, June 2012, pp. 330-340. https://doi.org/10.4218/etrij.12.0111.0366
  2. European Environment Agency, "Air Pollution," 2001 Report.
  3. J. Moon et al., "Semiconducting ZnO Nanofibers as Gas Sensors and Gas Response Improvement by $SnO_2$ Coating," ETRI J., vol. 31, no. 6, Dec. 2009, pp. 636-641. https://doi.org/10.4218/etrij.09.1209.0004
  4. C.S. Moon et al., "Highly Sensitive and Fast Responding CO Sensor Using $SnO_2$ Nanosheets," Sensors Actuators B, vol. 131, no. 2, 2008, pp. 556-564. https://doi.org/10.1016/j.snb.2007.12.040
  5. H.G. Byun, K.C. Persaud, and A.M. Pisanelli, "Wound-State Monitoring for Burn Patients Using E-Nose/SPME System," ETRI J., vol. 32, no. 3, June 2010, pp. 440-446. https://doi.org/10.4218/etrij.10.0109.0300
  6. J. Jun et al., "A Hydrogen Leakage Detection System Using Self-Powered Wireless Hydrogen Sensor Nodes," Solid-State Electron., vol. 51, no. 7, 2007, pp. 1018-1022. https://doi.org/10.1016/j.sse.2007.05.019
  7. A.D. DeHennis and K.D. Wise, "A Wireless Microsystem for the Remote Sensing of Pressure, Temperature, and Relative Humidity," J. Microelectromech. Syst., vol. 14, no. 1, Feb. 2005, pp. 12-22. https://doi.org/10.1109/JMEMS.2004.839650
  8. L. Zhao et al., "The Effect of Mutiwalled Carbon Nanotube Doping on the CO Gas Response of $SnO_2$-based Nanomaterials," Nanotechnol., vol. 18, no. 44, 2007, pp. 1-5.
  9. H.K. Lee et al., "Encapsulation of Semiconductor Gas Sensors with Gas Barrier Films for USN Application," ETRI J., vol. 34, no. 5, Oct. 2012, pp. 713-718. https://doi.org/10.4218/etrij.12.0112.0266
  10. N.J. Choi et al., "Fast Response Formaldehyde Gas Sensor for USN Application," Sensors Actuator B, vol. 175, 2012, pp. 132-136. https://doi.org/10.1016/j.snb.2012.01.004
  11. S.-J. Kim et al., "Enhanced $C_2H_5OH$ Sensing Characteristics of Nano-porous $In_2O_3$ Hollow Spheres Prepared by Sucrose-Mediated Hydrothermal Reaction," Sensors Actuators B, vol. 155, no. 2, 2011, pp. 512-518. https://doi.org/10.1016/j.snb.2010.12.055
  12. D.-S. Lee et al., "Micro Gas Sensor Array with Neural Network for Recognizing Combustible Leakage Gases," IEEE Sensors J., vol. 5, no. 3, 2005, pp. 530-536. https://doi.org/10.1109/JSEN.2005.845186
  13. J. Kong et al., "Nanotube Molecular Wires as Chemical Sensors," Sci., vol. 287, no. 5453, 2000, pp. 622-625. https://doi.org/10.1126/science.287.5453.622
  14. D. Zhang et al., "Detection of $NO_2$ Down to ppb Levels Using Individual and Multiple $In_2O_3$ Nanowire Devices," Nano Lett., vol. 4, no. 10, 2004, pp. 1919-1924. https://doi.org/10.1021/nl0489283
  15. N. Yamazoe and K. Shimanoe, "Theory of Power Laws for Semiconductor Gas Sensors," Sensors Actuators B, vol. 128, no. 2, 2008, pp. 566-573. https://doi.org/10.1016/j.snb.2007.07.036
  16. J.K. Prades et al., "Ultralow Power Consumption Gas Sensors Based on Self-Heated Individual Nanowires," Appl. Phys. Lett., vol. 93, no. 12, 2008, pp. 123110-1-123110-3. https://doi.org/10.1063/1.2988265
  17. Q. Wan et al., "Fabrication and Ethanol Sensing Characteristics of ZnO Nanowire Gas Sensors," Appl. Phys. Lett., vol. 84, no. 18, 2004, pp. 3654-3656. https://doi.org/10.1063/1.1738932
  18. M. Graf et al., "CMOS Microhotplate Sensor System for Operating Temperature up to $500^{\circ}C$," Sensors Actuator B, vol. 117, no. 2, 2006, pp. 346-352. https://doi.org/10.1016/j.snb.2005.11.012
  19. C. Hagleitner et al., "Smart Single-Chip Gas Sensor Microsystem," Nature, vol. 414, 2001, pp. 293-296.
  20. S.Z. Ali et al., "High Temperature SOI CMOS Tungsten Micro-Heaters," Proc. IEEE Conf. Sensors, 2006, pp. 847-850.
  21. S.E. Moon et al., "Low-Power-Consumption and High-Sensitivity $NO_2$ Micro Gas Sensor Based on a Co-Planar Micro-Heater Fabricated by Using a CMOS-MEMS Process," J. Korean Phys. Soc., vol. 56, no. 1, 2010, pp. 434-438. https://doi.org/10.3938/jkps.56.434
  22. F. Udrea et al., "Three Technologies for a Smart Miniaturized Gas-Sensor: SOI CMOS, Micromachining and CNTs - Challenges and Performance," Proc. 2007 IEEE Int. Electron Dev. Mtg. Tech. Dig., Washington, DC, Dec. 2007, pp. 831-834.
  23. S.E. Moon et al., " High-Response and Low-Power-Consumption CO Micro Gas Sensor Based on Nano-powders and a Micro-heater," J. Korean Phys. Soc., vol. 60, no. 2, 2012, pp. 235-239. https://doi.org/10.3938/jkps.60.235
  24. Korean Ministry of Environment, "Air Pollution," 2010 Report.
  25. N. Barsan, M. Schweizer-Berberich, and W. Gopel, "Fundamental and Practical Aspects in the Design of Nanoscaled $SnO_2$ Gas Sensors: A Status Report," J. Annal. Chem., vol. 365, 1999, pp. 287-304. https://doi.org/10.1007/s002160051490
  26. J. Gardner and P.N. Bartlett, Electronic Nose: Principles and Applications, New York: Oxford University Press, 1999.
  27. N. Barsan and U. Weimar, "Conduction Model of Metal Oxide Gas Sensors," J. Electroceram., vol. 7, 2001, pp. 143-167. https://doi.org/10.1023/A:1014405811371
  28. A. Kolmakov et al., "Detection of CO and $O_2$ Using Tin Oxide NanaoWire Sensors," Adv. Mater., vol. 15, 2003, pp. 997-1000. https://doi.org/10.1002/adma.200304889

Cited by

  1. Microdevice for Separation of Circulating Tumor Cells Using Embedded Magnetophoresis with V-shaped Ni-Co Nanowires and Immuno-nanomagnetic Beads vol.37, pp.2, 2013, https://doi.org/10.4218/etrij.15.0114.0572
  2. Surface Micromachined Pressure Sensor with Internal Substrate Vacuum Cavity vol.38, pp.4, 2013, https://doi.org/10.4218/etrij.16.0015.0025
  3. Transformation of CuO from Cu-MOF Templates and Their Enhanced Sensing Performance for HCHO : Transformation of CuOs from Cu-MOF Templates vol.37, pp.2, 2013, https://doi.org/10.1002/bkcs.10638
  4. Observation of convection phenomenon by high-performance transparent heater based on Pt-decorated Ni micromesh vol.7, pp.2, 2013, https://doi.org/10.1063/1.4977021
  5. Design and fabrication of a MEMS-based gas sensor containing WO3 sensitive layer for detection of NO2 vol.16, pp.1, 2017, https://doi.org/10.1117/1.jmm.16.1.015002
  6. Degree of indoor nitrogen oxides concentration and a method using an analytical chip with combination between porous glass and salzman's reagent vol.21, pp.2, 2013, https://doi.org/10.7879/siej.21.121
  7. p-p Heterojunction Sensors of p-Cu3Mo2O9 Micro/Nanorods Vertically Grown on p-CuO Layers for Room-Temperature Ultrasensitive and Fast Recoverable Detection of NO vol.12, pp.7, 2013, https://doi.org/10.1021/acsami.9b19971
  8. NO2 gas sensing properties of Pd/WO3 films prepared by glancing angle deposition vol.31, pp.8, 2020, https://doi.org/10.1007/s10854-019-02585-2
  9. Selective Ultrasonic Gravimetric Sensors Based on Capacitive Micromachined Ultrasound Transducer Structure—A Review vol.20, pp.12, 2013, https://doi.org/10.3390/s20123554
  10. Generic Approach to Boost the Sensitivity of Metal Oxide Sensors by Decoupling the Surface Charge Exchange and Resistance Reading Process vol.12, pp.33, 2013, https://doi.org/10.1021/acsami.0c07626
  11. A review on metal-oxide based p-n and n-n heterostructured nano-materials for gas sensing applications vol.2, pp.None, 2021, https://doi.org/10.1016/j.sintl.2021.100085
  12. Identification of Mint Scents Using a QCM Based E-Nose vol.9, pp.2, 2013, https://doi.org/10.3390/chemosensors9020031
  13. Surface Activity-Tuned Metal Oxide Chemiresistor: Toward Direct and Quantitative Halitosis Diagnosis vol.15, pp.9, 2021, https://doi.org/10.1021/acsnano.1c01350