Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
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Synthesis of Calcium Phosphate Minerals from Biowaste Clam Shells Using Microwave Heating

  • Bramhe, Sachin (Centre for New Functional Materials Metrology, KRISS) ;
  • Ryu, Jae-Kyung (Department of Dental Technology and Science, ShinHan University) ;
  • Chu, Min Cheol (Centre for New Functional Materials Metrology, KRISS) ;
  • Balakrishnan, Avinash (Nanosolar Division, Amrita Centre for Nanosciences and Molecular Medicine) ;
  • Kim, Taik Nam (Department of Material Science and Engineering, Pai Chai University)
  • Received : 2014.11.04
  • Accepted : 2014.12.02
  • Published : 2014.12.27
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Abstract

Calcium phosphate minerals are biologically important because of their application in the fields of orthopaedics and dentistry. Herein we have tried to synthesize calcium phosphate minerals from biowaste clam shells. A simple microwave method was used to synthesize a mixture of calcium phosphate minerals such as hydroxyapatite, tri-calcium phosphate, and monetite. The microwave induces vibration of the dipole ions in the reagent. The heating and rearrangement of ions and atoms occurs during the process. The phases obtained in the final powder were ascertained by X-ray diffraction; the morphology of each sample was checked using a scanning electron microscope. We were able to obtain a mixture of calcium phosphate minerals using the microwave method; the calcined powder showed a brick like morphology, which is different from the rod shape morphology of the hydroxyapatite obtained using the hydrothermal process.

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References

  1. C. P Yogan and, V. Selvarajan, Junshu Wu and Dongfeng Xue, Vacuum, 83, 319 (2009).
  2. S. H. Kwon, Y. K. Jun, S. H. Hong and H. E. Kim, J. Eur. Ceram. Soc., 23, 1039 (2003). https://doi.org/10.1016/S0955-2219(02)00263-7
  3. S. Joschek, B. Nies, R. Krotz and A. Gopferich, Biomaterials, 21, 1645 (2000). https://doi.org/10.1016/S0142-9612(00)00036-3
  4. K. P. Sanosh, M. C. Chu, A. Balakrishnan, T. N. Kim and S. J. Cho, Mater. Lett. 63, 2100 (2009). https://doi.org/10.1016/j.matlet.2009.06.062
  5. R. Murugan and K. P. Rao, Trends Biomater. Artif. Organs, 16, 43 (2002).
  6. J. H. G. Rocha, A. F. Lemos, S. Agathopoulos, P. Valerio, S. Kannan and F.N. Oktar, Bone, 37, 850 (2005). https://doi.org/10.1016/j.bone.2005.06.018
  7. M. Kurkcu, M. E. Benlidayi, B. Cam and Y. Sertdemir, J. Oral Implantol., 38, 519 (2012). https://doi.org/10.1563/AAID-JOI-D-11-00061
  8. A. Wassila, A. Leila, A. Lydia and A. Abdeltif, Food Technol Biotechnol., 51, 12 (2013).
  9. R. Kumar, K. H. Prakash, P. Cheang and K. A. Khor, Langmuir, 20, 5196 (2004). https://doi.org/10.1021/la049304f
  10. M. H. Fathi, and A. Hanifi, Mater. Lett., 61, 3978 (2007). https://doi.org/10.1016/j.matlet.2007.01.028
  11. Z. H. Zhou, P. L. Zhou, S. P Yang, X. B. Yu and L. Z. Yang, Mater. Res. Bull., 42, 1611 (2007). https://doi.org/10.1016/j.materresbull.2006.11.041
  12. S. Bramhe, T. N. Kim, A. Balakrishnan and M. C. Chu, Mater. Lett., 135, 195 (2014). https://doi.org/10.1016/j.matlet.2014.07.137
  13. S. H. Rhee, Biomaterials, 23, 1147 (2002). https://doi.org/10.1016/S0142-9612(01)00229-0
  14. X. Yang and Z. Wang, J. Mater. Chem., 8, 2233 (1998). https://doi.org/10.1039/a802067a
  15. J. C. Elliott, Structure and Chemistry of the Apatites and other Calcium Orthophosphates. Elsevier, Amsterdam, Netherlands, 1994.
  16. T. Kanazawa, Inorganic Phosphate Materials, Kondansha Ltd, Tokyo, Japan, 1989.
  17. Y. B. Khollam, A. S. Deshpande, A. J. Patil, H. S. Potdar, S. B. Deshpande and S. K. Date, Mater. Chem. Phys., 71, 304 (2001). https://doi.org/10.1016/S0254-0584(01)00286-3
  18. X. Xu, Y. Bao, C. Song, W. Yang, J. Lin and L. Lin, Micropor. Mesopor. Mater, 75, 173 (2004). https://doi.org/10.1016/j.micromeso.2004.07.019
  19. J. Liu, K. Li, H. Wang, M. Zhu and H. Yan, Chem. Phys. Lett., 396, 429 (2004). https://doi.org/10.1016/j.cplett.2004.08.094
  20. J. K. Han H.Y. Song, F. Saito and B.T Lee, Mater. Chem. Phys., 99, 235 (2006). https://doi.org/10.1016/j.matchemphys.2005.10.017

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  1. Facile Synthesis of Hydroxyapatite by Hydrothermal and Solvent Combustion Methods vol.25, pp.9, 2015, https://doi.org/10.3740/MRSK.2015.25.9.492